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Johnson, Mark A.

Publications and source records attributed to Johnson, Mark A..

Demonstration of Capture, Cooling, Tagging, and Spectroscopic Characterization of UV Photoproduct Ions in a Cryogenic Ion Trap: Application to 266 nm Photofragment Ions from Rhodamine 6G

We demonstrate a method to determine the structures of the primary photodissociation products from a cryogenically cooled parent ion. In this approach, a target ion is cooled by a pulse of buffer gas and tagged in a 20 K Paul trap. The cold ion is then photodissociated by pulsed (~5 ns) UV laser excitation, and the ionic products are trapped, cooled, and tagged by introduction of a second buffer gas pulse in the same trap. The tagged fragments are then ejected into a triple focusing, UV/vis/IR time-of-flight photofragmentation mass spectrometer which yields vibrational and electronic spectra of the mass-selected photofragments. Furthermore, these methods are demonstrated by application to the 266 nm photodissociation of the Rhodamine 6G cation to yield the R575 fragment ion based on loss of ethene as well as to a weaker secondary fragment arising from loss of m/z 43.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

InSight Aerothermal Environment Assessment

The Mars Interior Exploration using Seismic Investigations, Geodesy and Heat Transport (InSight) spacecraft, which successfully touched down on the planet surface on November 26, 2018, was proposed as a near build-to-print copy of the Mars Phoenix vehicle to reduce the overall cost and risk of the mission. Since the lander payload and the atmospheric entry trajectory were similar enough to those of the Phoenix mission, it was expected that the Phoenix thermal protection material thickness would be sufficient to withstand the entry heat load. However, allowances were made for increasing the heatshield thickness because the planned spacecraft arrival date coincided with the Mars dust storm season. The aftbody Thermal Protection System (TPS) components were not expected to change. In a first for a US Mars mission, the aerothermal environments for InSight included estimates of radiative heat flux to the aftbody from the wake. The combined convective and radiative heat fluxes were used to determine if the as-flown Phoenix thermal protection system (TPS) design would be sufficient for InSight. Although the radiative heat fluxes on the aftbody were predicted to be comparable to, or even higher than the local convective heat fluxes, all analyses of the aftbody TPS showed that the design would still be adequate. Aerothermal environments were computed for the vehicle from post-flight reconstruction of the atmosphere and trajectory and compared with the design environments. These comparisons showed that the predicted as-flown conditions were less severe than the design conditions.

Beck, Robin A. S.↗

The influence of the Alaskan Gyre on the coastal circulation in the Gulf of Alaska

The circulation of the northeast Pacific Ocean and the Gulf of Alaska is simulated by means of a reduced-gravity wind-driven model to study seasonal and interannual flow variability. The circulation in the NE Pacific is discussed emphasizing its ramifications for the physical domain, equations, and boundary conditions of the numerical model. The pseudostress fields used to drive the model are based on 20 years of data from the Comprehensive Ocean-Atmosphere Data Set and are analyzed with empirical orthogonal function analysis. The monthly stresses from 1986-89 are used to drive the model, and regional oceanographic features are reproduced including the Alaskan Gyre, Coastal Current, the Sitka eddy, and a severe cyclonic eddy. Comparisons with experimental data show that the high-resolution baroclinic model is valid and demonstrates the applicability of reduced-gravity models.

Heim, Paul K., II↗

Observation of mesoscale ocean features in the northeast Pacific using Geosat radar altimetry data

Mesoscale circulation in the Gulf of Alaska is studied by means of processed Geosat radar altimetry results with comparisons to observations of mesoscale eddies and surface circulation. The first set of Geosat data is treated by sea-surface height (SSH) binning in 1-deg latitude x 2-deg longitude boxes and analyzed by complex empirical orthogonal functions and 2D spectral analysis. The second set is taken from ascending Geosat tracks and analyzed as a time series. The Geosat data are compared to observational data including mesoscale eddies and fluctuations in mean surface circulation as well as sea-surface signals generated by numerical models. The data demonstrate the feasibility of a westward propagation of sea-level anomalies, and the Geosat SSH data are found to agree well with model solutions of seasonal variations in sea level in the northeast Pacific.

Matthews, Paul E.↗