Engineering topics

Jackman, Charles H.

Publications and source records attributed to Jackman, Charles H..

At least 73 records · Page 4

NASA NTRS1995

The middle atmospheric response to short and long term solar UV variations: analysis of observations and 2D model results

We have investigated the middle atmospheric response to the 27-day and 11-yr solar UV flux variations at low to middle latitudes using a two-dimensional photochemical model. The model reproduced most features of the observed 27-day sensitivity and phase lag of the profile ozone response in the upper stratosphere and lower mesosphere, with a maximum sensitivity of +0.51% per 1% change in 205 nm flux. The model also reproduced the observed transition to a negative phase lag above 2 mb, reflecting the increasing importance with height of the solar modulated HO(x) chemistry on the ozone response above 45 km. The model revealed the general anti-correlation of ozone and solar UV at 65-75 km, and simulated strong UV responses of water vapor and HO(x) species in the mesosphere. Consistent with previous 1D model studies, the observed upper mesospheric positive ozone response averaged over +/- 40 was simulated only when the model water vapor concentrations above 75 km were significantly reduced relative to current observations. In agreement with observations, the model computed a low to middle latitude total ozone phase lag of +3 days and a sensitivity of +0.077% per 1% change in 205 nm flux for the 27-day solar variation, and a total ozone sensitivity of +0.27% for the 11-yr solar cycle. This factor of 3 sensitivity difference is indicative of the photochemical time constant for ozone in the lower stratosphere which is comparable to the 27-day solar rotation period but is much shorter than the 11-yr solar cycle.

Fleming, Eric L.↗

NASA NTRS1995

Sensitivity of two-dimensional model predictions of ozone response to stratospheric aircraft: An update

The Goddard Space Flight Center (GSFC) two-dimensional model of stratospheric photochemistry and dynamics has been used to calculate the O3 response to stratospheric aircraft (high-speed civil transport (HSCT)) emissions. The sensitivity of the model O3 response was examined for systematic variations of five parameters and two reaction rates over a wide range, expanding on calculations by various modeling groups for the NASA High Speed Research Program and the World Meteorological Organization. In all, 448 model runs were required to test the effects of variations in the latitude, altitude, and magnetitude of the aircraft emissions perturbation, the background chlorine levels, the background sulfate aerosol surface area densities, and the rates of two key reactions. No deviation from previous conclusions concerning the response of O3 to HSCTs was found in this more exhaustive exploration of parameter space. Maximum O3 depletions occur for high-altitude, low altitude HSCT perturbations. Small increases in global total O3 can occur for low-altitude, high-altitude injections. Decreasing aerosol surface area densities and background chlorine levels increases the sensitivity of model O3 to the HSCT perturbations. The location of the aircraft emissions is the most important determinant of the model response. Response to the location of the HSCT emissions is not changed qualitatively by changes in background chlorine and aerosol loading. The response is also not very sensitive to changes in the rates of the reactions NO + HO2 yields NO2 + OH and HO2 + O3 yields OH + 2O2 over the limits of their respective uncertainties. Finally, levels of lower stratospheric HO(sub x) generally decrease when the HSCT perturbation is included, even though there are large increases in H2O due to the perturbation.

Considine, David B.↗

NASA NTRS1994

Effects of a polar stratosphere cloud parameterization on ozone depletion due to stratospheric aircraft in a two-dimensional model

A parameterization of Type 1 and 2 polar stratospheric cloud (PSC) formation is presented which is appropriate for use in two-dimensional (2-D) photochemical models of the stratosphere. The calculations of PSC frequency of occurrence and surface area density uses climatological temperature probability distributions obtained from National Meteorological Center data to avoid using zonal mean temperatures, which are not good predictors of PSC behavior. The parameterization does not attempt to model the microphysics of PSCs. The parameterization predicts changes in PSC formation and heterogeneous processing due to perturbations of stratospheric trace constituents. It is therefore useful in assessing the potential effects of a fleet of stratospheric aircraft (high speed civil transports, or HSCTs) on stratospheric composition. the model calculated frequency of PSC occurrence agrees well with a climatology based on stratospheric aerosol measurement (SAM) 2 observations. PSCs are predicted to occur in the tropics. Their vertical range is narrow, however, and their impact on model O3 fields is small. When PSC and sulfate aerosol heterogeneous processes are included in the model calculations, the O3 change for 1980 - 1990 is in substantially better agreement with the total ozone mapping spectrometer (TOMS)-derived O3 trend than otherwise. The overall changes in model O3 response to standard HSCT perturbation scenarios produced by the parameterization are small and tend to decrease the model sensitivity to the HSCT perturbation. However, in the southern hemisphere spring a significant increase in O3 sensitivity to HSCT perturbations is found. At this location and time, increased PSC formation leads to increased levels of active chlorine, which produce the O3 decreases.

Considine, David B.↗

NASA NTRS1994

The impact of emissions from space transport systems on the state of the atmosphere

The exhaust products of space transport systems contain many substances, some of which can lead to ozone destruction. Significant changes in atmospheric constituents were calculated in a local area within a few kilometers of the exhaust trail of rockets (i.e., over 80% decreases in local ozone), although these effects are simulated to last only a few hours. Relatively small changes in atmospheric constituents are computed for regional areas within 1000 km of the exhaust trail (i.e. less than 10% decreases in column ozone), and even smaller changes are computed on a global scale (i.e., less than 0.03% decreases in total global ozone depletion).

Jackman, Charles H.↗

NASA NTRS1994

Three dimensional model calculations of the global dispersion of high speed aircraft exhaust and implications for stratospheric ozone loss

Two-dimensional (zonally averaged) photochemical models are commonly used for calculations of ozone changes due to various perturbations. These include calculating the ozone change expected as a result of change in the lower stratospheric composition due to the exhaust of a fleet of supersonic aircraft flying in the lower stratosphere. However, zonal asymmetries are anticipated to be important to this sort of calculation. The aircraft are expected to be restricted from flying over land at supersonic speed due to sonic booms, thus the pollutant source will not be zonally symmetric. There is loss of pollutant through stratosphere/troposphere exchange, but these processes are spatially and temporally inhomogeneous. Asymmetry in the pollutant distribution contributes to the uncertainty in the ozone changes calculated with two dimensional models. Pollutant distributions for integrations of at least 1 year of continuous pollutant emissions along flight corridors are calculated using a three dimensional chemistry and transport model. These distributions indicate the importance of asymmetry in the pollutant distributions to evaluation of the impact of stratospheric aircraft on ozone. The implications of such pollutant asymmetries to assessment calculations are discussed, considering both homogeneous and heterogeneous reactions.

Douglass, Anne R.↗

NASA NTRS1993

The effects of the October 1989 solar proton events on the stratosphere as computed using a three-dimensional model

In an effort to better characterize the interhemispheric difference in the ozone depletion observed as a result of the very large solar proton events (SPEs) of October 19-27, 1989, NASA-Goddard's 3D chemistry and transport model has been used to simulate the distribution of NO(x) and ozone after the SPEs. Differences in the constituent behavior of the two hemispheres are seen as due to substantial mixing of perturbed air in the Southern Hemisphere from the polar region with unperturbed lower latitude air during the final November warming, in conjunction with confinement of the photochemically perturbed air in the Northern Hemisphere in the wintertime polar vortex.

Jackman, Charles H.↗

NASA NTRS1993

Chlorine catalyzed destruction of ozone - Implications for ozone variability in the upper stratosphere

The annual mean and the annual amplitude of ozone have been derived from ozone measurements from the SBUV and SBUV/2 spectrometers on board the Nimbus-7 and NOAA-11 satellites. These values differ significantly from values calculated using a two-dimensional model of stratospheric photochemistry and dynamics with standard chemistry. We have found that the differences between the calculated and data-derived values are considerably improved by changing the partitioning in the Cly family to create a larger reservoir of HCl and reducing ClO. This is accomplished by including a channel for the products HCl + O2 from the reaction ClO + OH in addition to the products Cl + HO2. This partitioning also improves the agreement between the calculated and measured values of ClO/HCl ratio.

Chandra, Sushil↗

NASA NTRS1992

A simulation of the effects of the National Aerospace Plane testing on the stratosphere using a two-dimensional model

A 2D photochemical model has been utilized to investigate the influence of testing of the NASP on the stratosphere. Effluents of H2, H2O, NO, NO2, OH, H, and O from the experimental vehicles are predicted to slightly disturb the stratosphere. The European Sanger spacecraft possible influence on the stratosphere has been simulated and is predicted to also be minor.

Jackman, Charles H.↗

NASA NTRS1992

Ozone depletion in the upper stratosphere estimated from satellite and Space Shuttle data

Shuttle Solar Backscatter Ultraviolet (SSBUV) spectrometer observations of ozone concentrations in the upper stratosphere made in October 1989 are combined here with measurements made in October 1980 by the similar SBUV instruments on NASA's Nimbus-7 satellite. It is shown that the ozone concentration near 45 km has decreased during this period by about 7 +/- 2 percent. The trend is consistent with predictions of a 2D photochemical model.

Hilsenrath, Ernest↗

NASA NTRS1992

Previous model comparisons

The first model comparison workshop examined 14 mathematical models. Issues discussed included: transport methodologies; transport of nuclear test debris; transport algorithms; source gases; NO(y), Cl(x), HO(x), and O3; photolysis rates; diurnal averaging; and rainout. The second model comparison meeting examined 16 models. More real model-model intercomparisons were undertaken and several topics were addressed including: photochemistry and radiation; transport; current atmosphere 1980; and assessment runs. The models computed different values for photolysis rates even when O3 and O2 were fixed, thus more time should be spent at future model comparison meeting on radiation codes.

Jackman, Charles H.↗

NASA NTRS1992

Model capabilities, 2-D

Two dimensional (2-D) atmospheric models provide results for altitude versus latitude as a function of time and are developed primarily for two reasons: to help understand atmospheric occurrences and to give assessments and/or make predictions of future changes in the atmosphere. Historically, the formulation of transport in 2-D models has been a difficult problem. Most current 2-D models have a transport that is either an Eulerian mean circulation with large stratospheric eddy diffusion or a residual (diabatic or Lagragian) mean circulation which typically is accompanied with small stratospheric eddy diffusion. Because of the assumption of zonal averaging, 2-D models are primarily useful in making predictions of atmospheric changes of time scales longer than a season. Although decadel atmospheric changes may be reasonably well represented with a 2-D model, the year to year changes which result from interannual transport differences, stratospheric warmings, semiannual oscillations, or quasi-biennial oscillations may not be well represented in the stratosphere and troposphere.

Jackman, Charles H.↗

NASA NTRS1992

Natural Cycles, Gases

The major gaseous components of the exhaust of stratospheric aircraft are expected to be the products of combustion (CO2 and H2O), odd nitrogen (NO, NO2 HNO3), and products indicating combustion inefficiencies (CO and total unburned hydrocarbons). The species distributions are produced by a balance of photochemical and transport processes. A necessary element in evaluating the impact of aircraft exhaust on the lower stratospheric composition is to place the aircraft emissions in perspective within the natural cycles of stratospheric species. Following are a description of mass transport in the lower stratosphere and a discussion of the natural behavior of the major gaseous components of the stratospheric aircraft exhaust.

Douglass, Anne R.↗

NASA NTRS1992

Ozone Response to Aircraft Emissions: Sensitivity Studies with Two-dimensional Models

Our first intercomparison/assessment of the effects of a proposed high-speed civil transport (HSCT) fleet on the stratosphere is presented. These model calculations should be considered more as sensitivity studies, primarily designed to serve the following purposes: (1) to allow for intercomparison of model predictions; (2) to focus on the range of fleet operations and engine specifications giving minimal environmental impact; and (3) to provide the basis for future assessment studies. The basic scenarios were chosen to be as realistic as possible, using the information available on anticipated developments in technology. They are not to be interpreted as a commitment or goal for environmental acceptability.

Ko, Malcolm K. W.↗

NASA NTRS1991

The influence of dynamics on two-dimensional model results - Simulations of C-14 and stratospheric aircraft NO(x) injections

The influence of dynamics on model results is investigated via a 2D photochemical model. Three representations of atmospheric transport are tested in order to simulate total ozone and C-14 amounts after nuclear tests in the early 1960s. Three scenarios of NO(x) injections from a proposed fleet of stratospheric aircraft and their effects on ozone are simulated. The three dynamical formulations used are Dynamics A, a base dynamics used in previous work with this model; Dynamics B, a strong circulation dynamics discussed by Jackman et al. (1989); and Dynamics C, the dynamics used by Shia et al. (1989). The advective component of the stratosphere to the troposphere mass exchange rate is largest for Dynamics B (5.8 x 10 exp 17 kg/yr) and smallest for Dynamics C (1.4 x 10 exp 17 kg/yr), with the advective strat/trop exchange rate for Dynamics A (2.4 x 10 exp 17 kg/yr) being these two extremes. Ozone depletion from NO(x) injections of stratospheric aircraft showed a strong sensitivity to dynamics.

Jackman, Charles H.↗

NASA NTRS1991

Two-dimensional model calculation of fluorine-containing reservoir species in the stratosphere

Two-dimensional model calculations have been carried out of the distributions of the fluorine-containing reservoir species HF, CF2O, and CFClO. HF constitutes the largest fluorine reservoir in the stratosphere, but CF2O also makes an important contribution to the inorganic fluorine budget. CFClO amounts are most important in the tropical lower stratosphere. HF amounts increase with altitude throughout the stratosphere, while those of CF2O and CFClO fall off above their mixing ratio peaks due to photolysis. The model is in good qualitative agreement with observed vertical profiles of HF and CF2O but tends to underestimate the total column of HF. The calculated CFClO distribution is in good agreement with the very limited data. The disagreement in the HF columns is likely due to small inaccuracies in the model's treatment of lower stratospheric photolysis of chlorofluorocarbons. The model results support the suggestion that CF2O may be heterogeneously converted to HF on the surface of polar stratospheric cloud particles. The model results also suggest that the quantum yield for photolysis of CF2O is near unity.

Kaye, Jack A.↗

NASA NTRS1991

Impact of interannual variability (1979-1986) of transport and temperature on ozone as computed using a two-dimensional photochemical model

Values of the monthly mean heating rates and the residual circulation characteristics were calculated using NMC data for temperature and the solar backscattered UV ozone for the period between 1979 and 1986. The results were used in a two-dimensional photochemical model in order to examine the effects of temperature and residual circulation on the interannual variability of ozone. It was found that the calculated total ozone was more sensitive to variations in interannual residual circulation than in the interannual temperature. The magnitude of the modeled ozone variability was found to be similar to the observed variability, but the observed and modeled year-to-year deviations were, for the most part, uncorrelated, due to the fact that the model did not account for most of the QBO forcing and for some of the observed tropospheric changes.

Jackman, Charles H.↗

NASA NTRS1991

Predicted rocket and shuttle effects on stratospheric ozone

The major chemical effluents of either solid- or liquid-fueled rockets that can potentially perturb stratospheric ozone include chlorine compounds (HCl), nitrogen compounds (NO(x)), and hydrogen compounds (H2 and H2O). Radicals (Cl, ClO, H, OH, HO2, NO, and NO2) formed directly or indirectly from rocket exhaust can cause the catalytic destruction of ozone. Other exhaust compounds that could presumably lead to ozone destruction either by direct reaction with ozone or by providing a surface for heterogeneous processes include the particulates Al2O3, ice, and soot. These topics are discussed in terms of the possible effects of rocket exhausts on stratospheric ozone.

Harwood, Robert S.↗

NASA NTRS1990

The Space Shuttle's impact on the stratosphere

Launch of spacecraft using solid rocket motors leads to release of gaseous and particular matter in the stratosphere. Concern over these emissions, particularly chlorine, goes back to the Climatic Impact Assessment Program. The buildup of these exhaust products and their perturbation to stratospheric ozone are followed with two- and three-dimensional atmospheric chemical transport models. Chlorine enhancements due to the current rate of shuttle launches is small, on average less than 0.6 percent above the current background. Other gases emitted from the solid rockets appear to have even smaller global effects, although the impact of particulate alumina remains uncertain.

Prather, Michael J.↗