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Hwang, I. H.

Publications and source records attributed to Hwang, I. H..

12 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Trace level of atomic copper in N-doped graphene quantum dots switching the selectivity from C 1 to C 2 products in CO electroreduction

To unravel the relationship between trace Cu on the metal-free catalysts toward CO/CO 2 reduction reaction (CO/CO 2 RR), we investigated the effect of trace Cu loading in N-doped graphene quantum dots (NGQDs) on CO/CO 2 RR. A general trend is that increasing the Cu loading in NGQDs switches the selectivity from C 1 (CH 4 ) to C 2 products in CORR. When 2.5 μg/cm 2 Cu with the atomic size is loaded on NGQDs, the selectivity shifts from 62% Faradaic efficiency (FE) of CH 4 to 52% FE of C 2 products in CORR. Further increasing the atomic Cu loading to 3.8 μg/cm 2 promotes the FE of C 2 products to 78%. CO 2 RR requires one order of magnitude higher Cu loading than CORR to switch the selectivity from C 1 to C 2 products due to the low partial pressure of CO. Finally, this study clarifies the distinct impact of trace (ppm level) Cu on the activity/selectivity between CORR and CO 2 RR.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2016

Injection Seeded Laser for Formaldehyde Differential Fluorescence Lidar

We describe the design and development of an injection seeded Nd:YVO4 laser for use in a differential fluorescence lidar for measuring atmospheric formaldehyde profiles. A high repetition rate Q-switched laser is modified to accept injection seed input to spectrally narrow and tune the output. The third harmonic output is used to excite formaldehyde (HCHO) fluorescence when tuned to a HCHO absorption line. Spectral confirmation is made with the use of a photoacoustic cell and grating spectrometer.

formaldehyde (HCHO) fluorescence↗
NASA NTRS2001

Full-Time, Eye-Safe Cloud and Aerosol Lidar Observation at Atmospheric Radiation Measurement Program Sites: Instruments and Data Analysis

Atmospheric radiative forcing, surface radiation budget, and top of the atmosphere radiance interpretation involves a knowledge of the vertical height structure of overlying cloud and aerosol layers. During the last decade, the U.S. Department of Energy through I the Atmospheric Radiation Measurement (ARM) program has constructed four long- term atmospheric observing sites in strategic climate regimes (north central Oklahoma, In Barrow. Alaska, and Nauru and Manus Islands in the tropical western Pacific). Micro Pulse Lidar (MPL) systems provide continuous, autonomous observation of all significant atmospheric cloud and aerosol at each of the central ARM facilities. Systems are compact and transmitted pulses are eye-safe. Eye-safety is achieved by expanding relatively low-powered outgoing Pulse energy through a shared, coaxial transmit/receive telescope. ARM NIPL system specifications, and specific unit optical designs are discussed. Data normalization and calibration techniques are presented. A multiple cloud boundary detection algorithm is also described. These techniques in tandem represent an operational value added processing package used to produce normalized data products for Cloud and aerosol research and the historical ARM data archive.

Campbell, James R.↗
NASA NTRS1994

Spaceborne Photonics Institute

This report describes in chronological detail the development of the Spaceborne Photonics Institute as a sustained research effort at Hampton University in the area of optical physics. This provided the research expertise to initiate a PhD program in Physics. Research was carried out in the areas of: (1) modelling of spaceborne solid state laser systems; (2) amplified spontaneous emission in solar pumped iodine lasers; (3) closely simulated AM0 CW solar pumped iodine laser and repeatedly short pulsed iodine laser oscillator; (4) a materials spectroscopy and growth program; and (5) laser induced fluorescence and atomic and molecular spectroscopy.

Venable, D. D.↗
NASA NTRS1990

Analytical and experimental studies on creep behavior of polymeric matrix composites

The creep behavior of graphite/epoxy composites is studied both analytically and experimentally. In the analytical study, a special finite element procedure was developed for the accurate and efficient analysis of creep response in anisotropic materials. This procedure was used to study the stress and strain distributions and histories in composite laminates containing circular holes. In the experimental study, creep tests were performed to investigate the time-dependent response of graphite/epoxy composites at elevated temperature. The moire interferometry technique was employed to determine the deformation histories in notched composites. The experimental results were compared with the analytical predictions and good agreement was observed.

Lin, K. Y.↗
NASA NTRS1989

Thermo-viscoelastic analysis of composite materials

The thermo-viscoelastic boundary value problem for anisotropic materials is formulated and a numerical procedure is developed for the efficient analysis of stress and deformation histories in composites. The procedure is based on the finite element method and therefore it is applicable to composite laminates containing geometric discontinuities and complicated boundary conditions. Using the present formulation, the time-dependent stress and strain distributions in both notched and unnotched graphite/epoxy composites have been obtained. The effect of temperature and ply orientation on the creep and relaxation response is also studied.

Lin, Kuen Y.↗
NASA NTRS1989

Analysis of creep and relaxation in composite laminates with holes

The time-dependent behavior of composite laminates subjected to mechanical loads is studied using linear viscoelastic theory. Three-dimensional finite elements are formulated to solve the integral equilibrium equations. Analyses of creep and stress relaxation in composites with holes are performed. Results indicate that the relaxation of interlaminar stresses depends on temperature and layups, and that the creep response of strains is affected by stress redistribution between plies.

Lin, Kuen Y.↗
NASA NTRS1988

Thermo-viscoelastic analysis of composite materials, volume 1

Advanced composite materials, especially graphite/epoxy, are being applied to aircraft structures in order to improve performance and save weight. An important consideration in composite design is the residual strength of a structure containing holes, delaminations, or interlaminar damage when subjected to compressive loads. Recent studies have revealed the importance of viscoelastic effects in polymer-based composites. The viscoelastic effect is particularly significant at elevated temperature/moisture conditions since the matrix material is strongly affected by the environment. The solution of viscoelastic problems in composites was limited to special cases which can be solved by classical lamination theory. A finite element procedure is presented for calculating time-dependent stresses and strains in composite structures with general configurations and complicated boundary conditions. Using this procedure the in-plane and interlaminar stress distributions and histories in notched and unnotched composites were obtained for mechanical and thermal loads. Both two-dimensional and three-dimensional viscoelastic problems are analyzed. The effects of layup orientation and load spectrum on creep response and stress relaxation were also studied.

Lin, K. Y.↗
NASA NTRS1988

Thermo-viscoelastic response of graphite/epoxy composites

The thermo-viscoelastic behavior of composite material is studied analytically using a special finite-element formulation. Numerical results on stress and deformation histories are obtained for both unnotched and notched graphite/epoxy composites subjected to mechanical and thermal spectrum loads. The results indicate that time-dependent effects are important in composites with matrix-dominated layup orientations. Such effects also strongly depend on the specific environment condition and load spectrum applied.

Lin, Kuen↗
NASA NTRS1986

A long-pulse amplifier for solar-pumped iodine lasers

The characteristics of a photodissociation iodine-laser amplifier pumped with a solar-simulating radiation were studied. Under long-pulse energy extraction, an energy amplification of about three and an energy storage time of longer than 500 microseconds were observed for a one meter long, 10 mm i.d. amplifier tube. The effects of elevated temperatures resulted in little reduction of the amplifier gain. These results confirm that developing an efficient chain of oscillator-amplifiers for a high-power solar-pumped iodine laser is indeed feasible.

Hwang, I. H.↗
NASA NTRS1984

Studies of new media radiation induced laser

Various lasants were investigated especially, 2-iodohepafluoropropane (i-C3F7I) for the direct solar pumped lasers. Optical pumping of iodine laser was achieved using a small flashlamp. Using i-C3F7I as a laser gain medium, threshold inversion density, small signal gain, and laser performance at the elevated temperature were measured. The experimental results and analysis are presented. The iodine laser kinetics of the C3F7I and IBr system were numerically simulated. The concept of a direct solar-pumped laser amplifier using (i-C3F7I) as the laser material was evaluated and several kinetic coefficients for i-C3F7I laser system were reexamined. The results are discussed.

Han, K. S.↗