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Huntress, W.

Publications and source records attributed to Huntress, W..

7 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Association Reactions at Low Pressure: 5. The CH(sub 3)+/HCN System. A Final Word?

The reaction of the methyl cation with hydrogen cyanide is revisited. We have confidence that we have resolved a long standing apparent contradiction of experimental results. A literature history is presented along with one new experiment and a reexamination of an old experiment. In this present work it is shown that all of the previous studies had made consistent observations. Yet, each of the previous studies failed to observe all of the information present. The methyl cation does react with HCN by radiative association, a fact which had been in doubt. The product ions formed in the two-body and three-body processes react differently with HCN. The collisionally stabilized association product formed by a three-body mechanism does not react with HCN and is readily detected in the experiments. The radiatively stabilized association product, formed by a slow two-body reaction, is not detected because it reacts with HCN by a fast proton transfer reaction forming the protonated HCN ion.

methyl cation↗
NASA NTRS1988

The detection of a discrete outflow from the young stellar object GL 490

A high-resolution (0.059/cm) M-band spectrum has been obtained of the embedded young stellar object GL490. The spectrum shows interstellar absorption in the fundamental vibrational band, v = 1-0, of (C-12)O. Two strong and narrow (10 km/s) velocity components are present. One, at the velocity of GL490 (vLSR = -16 km/s), is likely gas in the molecular cloud within which GL490 is embedded. The other component is blueshifted by 13 km/s relative to GL490. An observation of emission from the J = 3-2 transition of HCO(+) using a 20-arcsec beam supports the view that the blueshifted gas is near the central object. The -29-km/s feature is interpreted as a recently ejected shell. It is conjectured that the extended outflows of cold molecular gas seen by millimeter CO emission observations are driven by sporadic outbursts rather than by continuous flows from the central object.

Mitchell, G. F.↗
NASA NTRS1987

Evidence for methane and ammonia in the coma of comet P/Halley

Methane and ammonia abundances in the coma of Halley are derived from Giotto ion mass spectrometer data using an Eulerian model of chemical and physical processes inside the contact surface to simulate Giotto high-intensity spectrometer ion mass spectral data for mass-to-charge ratios (m/q) from 15 to 19. The ratio m/q = 19/18 as a function of distance from the nucleus is not reproduced by a model for a pure water coma. It is necessary to include the presence of NH3, and uniquely NH3, in coma gases in order to explain the data. A ratio of production rates Q(NH3)/Q(H2O) = 0.01 = 0.02 results in model values approximating the Giotto data. Methane is identified as the most probable source of the distinct peak at m/q = 15. The observations are fit best with Q(CH4)/Q(Q2O) = 0.02. The chemical composition of the comet nucleus implied by these production rate ratios is unlike that of the outer planets. On the other hand, there are also significant differences from observations of gas phase interstellar material.

Allen, M.↗
NASA NTRS1974

Science aspects of a 1980 flyby of Comet Encke with a Pioneer spacecraft

Results are presented of an investigation of the feasibility of a 1980 flyby of Comet Encke using a Pioneer class spacecraft. Specific areas studied include: science objectives and rationale; science observables; effects of encounter velocity; science encounter and targeting requirements; selection and description of science instruments; definition of a candidate science payload; engineering characteristics of suggested payload; value of a separable probe; science instruments for a separable probe; science payload integration problems; and science operations profile.

Jaffe, L. D.↗