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Hunten, D. M.

Publications and source records attributed to Hunten, D. M..

At least 19 records

Distribution and Abundance of Mars' Atmospheric Argon

One and one half Mars years (MY 26 and 27) of atmospheric Argon measurements are described and studied in the context of understanding how Argon, a minor constituent of Mars atmosphere that does not condense at Mars temperatures, can be used to study martian circulation and dynamics. Argon data are from the 2001 Mars Odyssey Gamma Subsystem (GS) of the suite of three instruments comprising the Gamma Ray Spectrometer (GRS). A comprehensive data analysis including gamma-ray production and attenuation by the atmosphere is included. Of particular interest is the enhanced abundance of Ar over the observed Ar abundance at lower latitudes at south (up to a factor of 10) and north (up to a factor of 4) polar regions during winter. Calibration of the measurements to actual Ar abundance is possible because GS measurements cover the same latitude and season as measurements made by the gas chromatograph mass spectrometer (GCMS) on Viking Landers 1 and 2 (VL1 and VL2). [2].

Sprague, A. L.

The Gas Chromatograph Mass Spectrometer for the Huygens Probe

Titan is unique in the solar system, the only moon that has a dense atmosphere. The major constituents of the atmosphere, nitrogen and methane, are continuously broken apart by a combination of solar UV, impinging electrons from Saturn s magnetosphere, and a steady flux of cosmic rays. The resulting molecular fragments recombine and form a variety of new species, many of which were detected for the first time by Voyager1 . The ubiquitous, surface- hiding aerosol blanket manifests the existence of still more complex compounds. In addition to hydrocarbons and nitriles, the atmosphere is known to contain CO, CO2 and externally delivered H2O. The Gas Chromatograph Mass Spectrometer (GCMS) on the Huygens Probe will measure the chemical composition of the atmosphere of Titan from 170 Km altitude (approximately 1hPa) to the surface (approximately 1500hPa) and determine the isotope ratios of the major constituents. The GCMS will also analyze gas samples from the Aerosol Collector Pyrolyser (ACP) and may be able to obtain compositional information of several surface materials. The GCMS consists of a quadrupole mass spectrometer (QP) with a secondary electron multiplier ion detector, a three-column gas chromatograph (GC) and an elaborate gas sampling system. The gas sampling system will provide atmospheric samples to the QP for nearly continuous analysis during the Probe descent and batch samples at several altitudes for GC analysis. It also contains a chemical scrubber for noble gas analysis and an enrichment cell for trace constituent enhancement. In addition to the sampling of the atmosphere periodic gas samples, derived from the pyrolysis of aerosols, will be transferred from the ACP to the GCMS for direct QP and full GCMS analysis. The QP can analyze molecular masses from 2 to 141Dalton. The nominal detection threshold is at a mixing ratio of 10E-8. Data rate is 885 bits/sec. The mass of the instrument is 17.3 kg and the energy required for operation during the descent is 110 Watt-hours.

Niemann, H. B.

The Gas Chromatograph Mass Spectrometer for the Huygens Probe

Titan is unique in the solar system, the only moon that has a dense atmosphere. The major constituents of the atmosphere, nitrogen and methane, are continuously broken apart by a combination of solar UV, impinging electrons from Saturn's magnetosphere, and a steady flow of cosmic rays. The resulting molecular fragments recombine and form a variety of new species, many of which were detected for the first time by Voyager 1. The ubiquitous, surface-hiding aerosol blanket manifests the existence of still more complex compounds. In addition to hydrocarbons and nitriles, the atmosphere is known to contain CO, CO2 and externally delivered H2O. The Gas Chromatograph Mass Spectrometer (GCMS) on the Huygens Probe will measure the chemical composition of the atmosphere of Titan from 170 km altitude (approximately lhPa) to the surface (approximately 1500hPa) and determine the isotope ratios of the major constituents. The GCMS will also analyze gas samples from the Aerosol Collector Pyrolyser (ACP) and may be able to obtain compositional information of several surface materials. The GCMS consists of a quadrupole mass spectrometer (QP) with a secondary electron multiplier ion detector, a three-column gas chromatograph (GC) and an elaborate gas sampling system. The gas sampling system will provide atmospheric samples to the QP for nearly continuous analysis during the Probe descent and batch samples at several altitudes for GC analysis. It also contains a chemical scrubber for noble gas analysis and an enrichment cell for trace constituent enhancement. In addition to the sampling of the atmosphere periodic gas samples, derived from the pyrolysis of aerosols, will be transferred from the ACP to the GCMS for direct QP and full GCMS analysis. The QP can analyze molecular masses from 2 to 14lDalton. The nominal detection threshold is at a mixing ratio of 10E-8. Data rate is 885 bits/sec. The mass of the instrument is 17.3 kg and the energy required for operation during the descent is 110 Watt-hours.

Niemann, H. B.

Chemical composition measurements of the atmosphere of Jupiter with the Galileo Probe mass spectrometer

The Galileo Probe entered the atmosphere of Jupiter on December 7, 1995. Measurements of the chemical and isotopic composition of the Jovian atmosphere were obtained by the mass spectrometer during the descent over the 0.5 to 21 bar pressure region over a time period of approximately 1 hour. The sampling was either of atmospheric gases directly introduced into the ion source of the mass spectrometer through capillary leaks or of gas, which had been chemically processed to enhance the sensitivity of the measurement to trace species or noble gases. The analysis of this data set continues to be refined based on supporting laboratory studies on an engineering unit. The mixing ratios of the major constituents of the atmosphere hydrogen and helium have been determined as well as mixing ratios or upper limits for several less abundant species including: methane, water, ammonia, ethane, ethylene, propane, hydrogen sulfide, neon, argon, krypton, and xenon. Analysis also suggests the presence of trace levels of other 3 and 4 carbon hydrocarbons, or carbon and nitrogen containing species, phosphine, hydrogen chloride, and of benzene. The data set also allows upper limits to be set for many species of interest which were not detected. Isotope ratios were measured for 3He/4He, D/H, 13C/12C, 20Ne/22Ne, 38Ar/36Ar and for isotopes of both Kr and Xe.

unmanned

Coronagraphic Observations of Lunar Sodium

This grant supported an investigation of lunar sodium by our coronagraph and spectrograph on nearby Mount Lemmon. We report successful operation and data analysis during International Lunar Atmosphere Week, September 15 - 22, 1995, and submittal of a paper to Icarus. The core of the proposed work was to observe the lunar sodium atmosphere with our classical Lyot coronagraph and specially-built grating spectrograph on Mount Lemmon, a 9400-foot peak about an hour's drive from Tucson. It is optimized for low scattered light and for observing from the Moon's limb to an altitude of approx.1 lunar radius. The grating has 600 lines/mm and a blaze angle of 49 deg., and is used with a somewhat wide slit at a resolving power of about 5000. It is called DARRK for the initials of the people who designed it. The rejection of stray light from the Moon's disk is spectacularly good: when the sky is clear this light is absent right up to a few arcsec from the limb. We use an excellent 1024 by 1024 pixel CCD camera, operated at -100 C; the exposures are 10 to 30 min. Data reduction is done with IRAF running on a Sun Sparcstation.

Hunten, D. M.

Coronagraphic Observations of Lunar Sodium

The core of the proposed work was to observe the lunar sodium atmosphere with our classical Lyot coronagraph and specially-built grating spectrograph on Mount Lemmon, a 9400-foot peak about an hour's drive from Tucson. It is optimized for low scattered light and for observing from the Moon's limb to an altitude of approx. 1 lunar radius. The grating has 600 lines/mm and a blaze angle of 49 deg, and is used with a somewhat wide slit at a resolving power of about 5000. It is called DARRK for the initials of the people who designed it. The rejection of stray light from the Moon's disk is spectacularly good: when the sky is clear this light is absent right up to a few arcsec from the limb. We use an excellent 1024 by 1024 pixel CCD camera, operated at -100 C; the exposures are 10 to 30 min. Data reduction is done with ERAF running on a Sun Sparcstation.

Hunten, D. M.

Planetary Aeronomy and Related Studies

Mercury atmosphere - Sprague and Hunten, in collaboration with Katharina Lodders of Washington University, proposed, mainly on cosmochemical grounds, that S atoms are an important constituent of the atmosphere (30 times more abundant than sodium). This paper has appeared in Icarus. We also suggest that condensed sulfur is an excellent candidate for the radar-bright polar caps, more plausible than water ice because the latter is only barely stable even in permanently-shadowed craters. The best prospect for detection of the vapor is through its resonance lines, a triplet near 1814 A. Mercury is too close to the Sun to be observed by any existing space telescope, but there is some prospect that the search could be made from a Shuttle-based spectrograph such as Lyle Broadfoot's USTAR. Sprague and Hunten have completed an elaborate data analysis of over 100 measurements of the Na D lines, obtained with the 61-inch telescope and our echelle spectrograph. Full account has been taken of the radiative-transfer problem that arises because the Na atmosphere is not optically thin. The output of this code is used in another program that makes an elaborate inverse interpolation in two angles and optical depth and computes the effect of the seeing (always bad for Mercury). The seeing is determined by fitting cuts across a computed image to part of the spectrum adjacent to the sodium lines, and typically ranges from slightly less than 4 arcsec to worse than 6 (diameter at l/e of a Gaussian). The final result is a list of Na abundances, with some information on spatial distribution. One particularly interesting result of further analysis is a strong abundance maximum in the morning relative to the afternoon, confirming an earlier result for potassium, based on much fewer measurements. The analysis are completed during the extension of the present grant. This work depends heavily on the Hapke parameters used to estimate the reflectance of Mercury's surface. The paper by Domingue et al. examines the credibility of the available parameters, which are derived from disk-unresolved photometry, and concludes that errors in the derived Na abundances could be as great as 30%.

Hunten, D. M.

The 825-1110 angstroms EUV spectrum of Venus

On 15 August 1994 we launched the EUVS sounding rocket payload to observe the 825-1110 angstrom region of Venus's far ultraviolet airglow spectrum. The EUVS telescope/spectrograph obtained good data at five times higher spectral resolution than was previously available in the far ultraviolet. We present these data and compare our results to those obtained by the Galileo UVS and Venera 11/12 UV spectrophotometers. We identify several new spectral emission features, including both singly ionized nitrogen and molecular nitrogen in Venus's spectrum. We also see evidence for electron-impact-induced emission from CO. Finally, the EUVS data indicate that the "Ar" emissions detected in Venus's far ultraviolet spectrum by Venera 11/12 spectrophotometers are in fact not due to argon, thus eliminating the discrepancy between in situ and remote sensing measurements.

Flight Experiment

The Galileo probe mass spectrometer: composition of Jupiter's atmosphere

The composition of the jovian atmosphere from 0.5 to 21 bars along the descent trajectory was determined by a quadrupole mass spectrometer on the Galileo probe. The mixing ratio of He (helium) to H2 (hydrogen), 0.156, is close to the solar ratio. The abundances of methane, water, argon, neon, and hydrogen sulfide were measured; krypton and xenon were detected. As measured in the jovian atmosphere, the amount of carbon is 2.9 times the solar abundance relative to H2, the amount of sulfur is greater than the solar abundance, and the amount of oxygen is much less than the solar abundance. The neon abundance compared with that of hydrogen is about an order of magnitude less than the solar abundance. Isotopic ratios of carbon and the noble gases are consistent with solar values. The measured ratio of deuterium to hydrogen (D/H) of (5 +/- 2) x 10(-5) indicates that this ratio is greater in solar-system hydrogen than in local interstellar hydrogen, and the 3He/4He ratio of (1.1 +/- 0.2) x 10(-4) provides a new value for protosolar (solar nebula) helium isotopes. Together, the D/H and 3He/4He ratios are consistent with conversion in the sun of protosolar deuterium to present-day 3He.

NASA Discipline Number 52-10

Mirages and the nature of Pluto's atmosphere

We present model occultation lightcurves demonstrating that a strong thermal inversion layer at the base of Pluto's stratosphere can reproduce the minimum flux measured by the Kuiper Airborne Observatory (KAO) during the 1988 occultation of a star by Pluto. The inversion layer also forms the occultation equivalent of a mirage at a radius of 1198 km, which is capable of hiding tropospheres of significant depth. Pluto's surface lies below 1198 km, its radius depending on the depth of the troposphere. We begin by computing plausible temperature structures for Pluto's lower atmosphere, constrained by a calculation of the temperature of the atmosphere near the surface. We then trace rays from the occulted star through the model atmosphere, computing the resultant bending of the ray. Model light curves are obtained by summing the contribution of individual rays within the shadow of Pluto on Earth. We find that we can reproduce the KAO lightcurve using model atmospheres with a temperature inversion and no haze. We have explored models with tropospheres as deep as 40 km (implying a Pluto radius of 1158 km) that reproduce the suite of occultation data. Deeper tropospheres can be fitted to the data, but the mutual event radius of 1150 km probably provides a lower bound. If Pluto has a shallow or nonexistent troposphere, its density is consistent with formation in the solar nebula with modest water loss due to impact ejection. If the troposhere is relatively deep, implying a smaller radius and larger density, significant amounts of water loss are required.

Stansberry, J. A.

CO2 cooling in terrestrial planet thermospheres

We examine the recent progress in the debate on the CO2-O relaxation rate, its temperature dependence, and its corresponding impact on the thermospheric heat budgets of Venus, Earth, and Mars. This comparative approach provides the broadest range of conditions under which a common CO2-O relaxation rate should provide consistent results. New global mean calculations are presented for the heat budgets of these three planets using large CO2-O relaxation rates that have been inferred recently from Earth CO2 radiance measurements and laboratory studies. Results indicate that available Venus and Mars data constrain the CO2-O relaxation rate to be 2-4 x 10(exp -12)/cu cm/s at 300 K. For Venus, this strong cooling serves as an effective thermostat that gives rise to a small variation of thermospheric temperatures over the solar cycle, just as observed. Conversely, CO2 cooling does not appear to be dominant in the dayside heat budget of the Mars thermosphere over most of the solar cycle. For the Earth, this strong cooling implies that the lower thermosphere does not typically require significant eddy diffusion or heat conduction. However, global-scale dynamics or an additional heating mechanism may be needed to restore calculated temperatures to observed values when relaxation rates exceeding 2 x 10(exp -12)/cu cm/s are employed.

Bougher, S. W.

Atmospheres of the Moon and Mercury

Mercury and the Moon have long been considered to be similar objects, but this view was based on limited information at visible wavelengths. It is now known that real differences exist in the atmospheres and in the rock types as deduced from mid-infrared observations. Lunar Ar and perhaps Ne were observed from Apollo landed experiments in spite of a large local background. An ultraviolet spectrometer (UVS) in orbit placed upper limits on a number of gases including H and O. At Mercury, the UVS on Mariner 10 measured H, He, and perhaps O and again a number of upper limits for other gases. Less than a decade ago, emissions of Na and K were observed from the ground, with abundances 2 orders of magnitude smaller on the Moon than on Mercury. It is likely that impacting meteoroids bring a significant amount of water to Mercury, whose atmosphere should therefore contain water vapor. This notion is supported by the recent discovery of radar-bright polar deposits almost certainly composed of ice. A variety of origins is likely for the different components. Impact of meteoroids could supply water, Na, and K, and could also vaporize surface material; Na, K, and Ar could be degassed from the crust. H is probably from the solar wind, and He could reasonably come from degassing or the solar wind. A substantial loss process for all components is photoionization (or dissociation); ions on one side are swept away into the solar wind and on the other are swept back to the surface. This process is complicated at Mercury by its permanent magnetic field, but there is little doubt that both loss and recycling still occur. Some of the recycling probably occurs by way of the magnetotail through night side auroral precipitation; atoms implanted in the surface will diffuse back into the atmosphere shortly after dawn, an effect that seems to be present for K. Finally the light atoms H and He have high enough velocities to escape directly, an effect that may be enhanced by the suprathermal velocity distributions that are likely to be present.

Hunten, D. M.

Neutral composition measurements by the Pioneer Venus Neutral Mass Spectrometer during orbiter re-entry

Measurements by the Pioneer Venus Orbiter Neutral Mass Spectrometer (ONMS) instrument during Orbiter re-entry have been made from 18-24 hours local solar time, above 170 km, of He, and from midnight to 4.5 hours below 200 km of He, N, O, CO, N2, and CO2. Preliminary results indicate that in the post-midnight sector He is the dominant species above 170 km, O the dominant species from 140-170 km and CO2 the dominant species below 140 km. Estimated scale height temperatures for He, O, and CO2 of about 105-120 K are similar to those observed in 1978-1980 at higher solar activity. The densities at 1 am local solar time and at 150 km are within 35% of those measured earlier. The He bulge is also similar to that observed in 1978-1980 confirming that thermosphere superrotation is still present. Comparison with the results of a Venus Thermosphere General Circulation Model suggests the nightside is not sensitive to changes in solar activity due to the isolation of the day and night thermospheres. apparently, the relatively small changes in the dayside thermosphere with solar activity have little impact on the nightside thermosphere.

Kasprzak, W. T.

Neutral Composition Measurements by the Pioneer Venus Neutral Mass Spectrometer During Orbiter Re-Entry

Measurements by the Pioneer Venus Orbiter Neutral Mass Spectrometer (ONMS) instrument during Orbiter re-entry have been made from 18-24 hours local solar time, above 170 km, of He, and from midnight to 4.5 hours below 200 km of He, N, O, CO, N2, and CO2. Preliminary results indicate that in the post-midnight sector He is the dominant species above 170 km, O the dominant species from 140-170 km and CO2 the dominant species below 140 km. Estimated scale height temperatures for He, O and CO2 of about 105-120 K are similar to those observed in 1978-80 at higher solar activity. The densities at 1 am local solar time and at 150 km are within 35% of those measured earlier. The He bulge is also similar to that observed in 1978-80 confirming that thermosphere superrotation is still present. Comparison with the results of a Venus Thermosphere General Circulation Model suggests the nightside is not sensitive to changes in solar activity due to the isolation of the day and night thermospheres. Apparently, the relatively small changes in the dayside thermosphere with solar activity have little impact on the nightside thermosphere.

Kasprzak, W. T.

The occultation of 28 Sgr by Saturn - Saturn pole position and astrometry

Saturn's ring plane-defined pole position is presently derived from the geometry of Saturn's July 3, 1989 occultation of 28 Sgr, as indicated by the timings of 12 circular edges in the Saturn C-ring as well as the edges of the Encke gap and the outer edge of the Keeler gap. The edge timings are used to solve for the position angle and opening angle of the apparent ring ellipses; the internal consistency of the data set and the redundancy of stations indicates an absolute error of the order of 5 km. The pole position thus obtained is consistent with the pole and ring radius scale derived from Voyager occultation observations.

Hubbard, W. B.

Venus - Lessons for earth

The old idea that Venus might possess surface conditions to those of an overcast earth has been thoroughly refuted by space-age measurements. Instead, the two planets may have started out similar, but diverged because of the greater solar flux at Venus. This cannot be proved, but is consistent with everything known. A runaway greenhouse effect could have evaporated an 'ocean'. The hydrogen would escape, and most of the oxygen would be incorporated into the crust. Without liquid water, CO2 would remain in the atmosphere. Chlorine atoms would catalyze the recombination of any free oxygen back to CO2. The same theories apply to the future of the earth, and to the explanation of the polar ozone holes; the analogies are striking. There is no likelihood that the earth will actually come to resemble Venus, but Venus serves both as a warning that major environmental effects can flow from seemingly small causes, and as a testbed for the predictive models of the earth.

Hunten, D. M.

Galileo Probe Mass Spectrometer experiment

The chemical and isotopic composition of the Jupiter atmosphere's constituents, including their vertical variations, will be measured by the Galileo Probe Mass Spectrometer instrument through in situ sampling; batch sampling will also be undertaken for noble gas composition and isotopic ratio determinations. The instrument's gas-sampling system is connected to a quadrupole mass analyzer for molecular weight analysis. Threshold values are lowered through sample enrichment by a factor of 100-500 for stable hydrocarbons and by a factor of 10 for noble gases. The instrument follows a sampling sequence of 8192 steps, at a rate of 2 steps/sec.

Niemann, H. B.

Galileo Ultraviolet Spectrometer experiment

The Galileo ultraviolet spectrometer experiment uses data obtained by the Ultraviolet Spectrometer (UVS) mounted on the pointed orbiter scan platform and from the Extreme Ultraviolet Spectrometer (EUVS) mounted on the spinning part of the orbiter with the field of view perpendicular to the spin axis. The UVS is a Ebert-Fastie design that covers the range 113-432 nm with a wavelength resolution of 0.7 nm below 190 and 1.3 nm at longer wavelengths. The UVS spatial resolution is 0.4 deg x 0.1 deg for illuminated disk observations and 1 deg x 0.1 deg for limb geometries. The EUVS is a Voyager design objective grating spectrometer, modified to cover the wavelength range from 54 to 128 nm with wavelength resolution 3.5 nm for extended sources and 1.5 nm for point sources and spatial resolution of 0.87 deg x 0.17 deg. The EUVS instrument will follow up on the many Voyager UVS discoveries, particularly the sulfur and oxygen ion emissions in the Io torus and molecular and atomic hydrogen auroral and airglow emissions from Jupiter. The UVS will obtain spectra of emission, absorption, and scattering features in the unexplored, by spacecraft, 170-432 nm wavelength region. The UVS and EUVS instruments will provide a powerful instrument complement to investigate volatile escape and surface composition of the Galilean satellites, the Io plasma torus, micro- and macro-properties of the Jupiter clouds, and the composition structure and evolution of the Jupiter upper atmosphere.

Hord, C. W.