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Hudson, R. D.

Publications and source records attributed to Hudson, R. D..

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

The vertical ozone distribution in the Antarctic ozone minimum measured by SBUV

The ozone profiles measured by SBUV in the region of the Antarctic ozone minimum are in error as archived for altitudes below the 7 mb level in the atmosphere because of the lack of a reasonable climatology to use for the initial guess profile. The ozone profile error in this region is examined, and it is shown that use of a reasonable climatology in this unusual region results in ozone profiles that agree substantially better with the balloon observations available from the Syowa station. The corrected profiles show that by 1984 there was 35 percent less ozone in the 15 to 30 km region than in 1979, and 14 percent less even in the 40 to 50 km region.

Mcpeters, R. D.↗
NASA NTRS1982

Stratospheric ozone and hydroxyl radical measurements by balloon-borne lidar

An experiment is reported in which a balloon-borne lidar system was used to measure ozone and the hydroxyl radical in the stratosphere by two lidar techniques. Ozone was measured in the 20-37 km altitude range using differential absorption lidar, and the hydroxyl radical was measured in the 34-37 km range using remote laser-induced fluorescence. Ozone concentrations were determined with a vertical resolution of 0.5 km, and in addition, horizontally resolved ozone measurements with 0.15-km resolution were obtained over a 2-km range. The temporal variation of the hydroxyl radical concentration ranged from 40 parts/trillion shortly after noon to about 5 parts/trillion two hours after sunset. Possible modifications to the system are discussed which can yield an improvement in the sensitivity of between one and two orders of magnitude, thus permitting measurements of the hydroxyl radical in the 20-30-km altitude range.

Heaps, W. S.↗
NASA NTRS1981

Stratospheric observations of the attenuated solar irradiance in the Schumann-Runge band absorption region of molecular oxygen

A spectrometer flown on the first Solar Absorption Balloon Experiment (SABE-1) observed the attenuated solar irradiance between 184 and 202 nm from an altitude near 40 km. These measurements provide a check on the absorption cross sections of molecular oxygen in the spectral region of the Schumann-Runge bands. Comparison of the measurements with calculations based on cross sections derived from laboratory data shows a general agreement although the irradiance measurements have large error bars near the centers of the absorption bands. The results imply that the 184-200 nm solar irradiance that penetrates to the stratosphere can be computed to an accuracy of + or - 30% or better by using presently available cross sections.

Frederick, J. E.↗
NASA NTRS1981

Temperature dependence of ozone absorption cross section, 280 to 330 nm

A description is presented of the results of an analysis of the presently available data on the variation of the ozone absorption cross section and the O(1D) yield with temperature. The data used in the analysis of the total ozone cross section were obtained by Inn and Tanaka (1953), Vigroux (1953), and Simons et al. (1973). The O(1D) yield data examined include those of Moortgat et al. (1977), Arnold et al. (1977), and Brock and Watson (1980). For the purposes of the analysis the yield measurements were converted to partial cross sections by multiplying the published yield by the published total cross section.

Hudson, R. D.↗
NASA NTRS1981

Penetration of solar irradiance in the Schumann-Runge bands of O2 - A comparison of balloon-borne measurements and calculations

Measurements of the attenuated solar irradiance made from the STRATCOM VIII balloon are compared with calculated values of the solar irradiance reaching the 40 km level for a solar zenith angle of 66.18 deg. The ability of theory to match intensity maxima which correspond to the cross section minima between the bands is investigated. The comparisons show that model results are too small by a factor of 1.8 between 199 and 22 nm, which is attributed to a systematic calibration offset between the balloon data and the irradiances of Bruckner et al. (1976). A large disagreement between the observed and calculated intensities at peaks H and I results from an error in the cross sections used in current aeronomic work.

Frederick, J. E.↗
NASA NTRS1980

Atmospheric opacity in the Schumann-Runge bands and the aeronomic dissociation of water vapor

Knowledge of the aeronomic production of odd hydrogen in the dissociation of water vapor is limited by uncertainties in the penetration of solar irradiance in the Schumann-Runge bands of O2 and by incomplete information concerning the products of photolysis at Lyman alpha. Consideration of all error sources involved in computing the H2O dissociation rate in the wavelength region 175-200 nm leads to an estimated uncertainty of plus or minus 35% at an altitude of 90 km for an overhead sun. The uncertainty increases with decreasing altitude such that the true dissociation rate at 60 km for an overhead sun lies between 0.45 and 1.55 times the results computed using the best input parameters currently available. Calculations of the H2O dissociation rate by Lyman alpha should include the variation in O2 opacity across the solar line width. Neglect of this can lead to errors as large as 50% at altitudes where the process is the major source of odd hydrogen.

Frederick, J. E.↗
NASA NTRS1980

Dissociation of molecular oxygen in the Schumann-Runge bands

Oscillator strengths and predissociation linewidths deduced in recent studies predict a dissociation rate for O2 in the Schumann-Runge bands which is significantly larger in the upper stratosphere and lower mesosphere than previously believed. Error bars on molecular parameters required in the cross-section calculation translate into uncertainties in the dissociation rate which are less than plus or minus 10% at all altitudes where the Schumann-Runge bands are aeronomically significant.

Frederick, J. E.↗
NASA NTRS1979

The stratosphere: Present and future

The present status of stratospheric science is discussed. The three basic elements of stratospheric science-laboratory measurements, atmospheric observations, and theoretical studies are presented along with an attempt to predict, with reasonable confidence, the effect on ozone of particular anthropogenic sources of pollution.

Hudson, R. D.↗
NASA NTRS1979

Minor constituents in the stratosphere and mesosphere

A review of the research in minor constituents in the stratosphere and mesosphere, carried out between 1975 and 1978, is presented. Much of the theoretical research was done with the aid of one-dimensional models. Different aspects of these models are discussed. Measurements of the chlorofluoromethanes, hydrochloric acid, nitric oxide, nitrous oxide, and hydrogen oxide were conducted. It is noted that the hydrogen oxides are now assuming a larger role in stratospheric photochemistry than have been postulated before. The effect of water vapor and the hydrogen oxides on the overall chemistry of the stratosphere was investigated theoretically, along with the possible relationship between solar activity and atmospheric ozone. The mesosphere study included ozone, water vapor, nitric oxide, and odd nitrogen investigations.

Hudson, R. D.↗
NASA NTRS1979

Predissociation of nitric oxide in the mesosphere and stratosphere

Absorption of solar photons by nitric oxide in the wavelength ranges 181.3-183.5 and 189.4-191.6 nm leads to predissociation of the molecule in the mesosphere and upper stratosphere. Molecular oxygen controls the penetration of the required solar irradiance via absorption in the Schumann-Runge bands, while attenuation due to ozone becomes significant in the upper stratosphere. The calculation of the nitric oxide dissociation rate is complicated by the need to include all rotational fine structure in both the NO and O2 cross sections. The dissociation rate computed here for the upper mesosphere is a factor of 3.6 less than that reported in past work when currently accepted values of the oscillator strengths and solar irradiance are used. In addition, improved molecular parameters describing the O2 cross section predict less attenuation of the dissociation rate with decreasing altitude than results previously available.

Frederick, J. E.↗
NASA NTRS1977

Chlorofluoromethanes and the Stratosphere

The conclusions of a workshop held by the National Aeronautics and Space Administration to assess the current knowledge of the impact of chlorofluoromethane release in the troposphere on stratospheric ozone concentrations. The following topics are discussed; (1) Laboratory measurements; (2) Ozone measurements and trends; (3) Minor species and aerosol measurements; (4) One dimensional modeling; and (5) Multidimensional modeling.

Hudson, R. D.↗
NASA NTRS1977

Apollo-Soyuz O/3P/ and N/4S/ density measurement by UV spectroscopy

The densities of O(3P) and N(4S) at 225 km were determined during the Apollo-Soyuz Test Project by a resonance absorption-fluorescence technique in which O I and N I line radiation produced and collimated on board the Apollo was reflected from the Soyuz back to the Apollo for spectral analysis. The two spacecraft maneuvered so that a range of observation angles of plus or minus 25 deg with respect to the normal to the orbital velocity vector was scanned. The measurements described were made at night on two consecutive orbits at spacecraft separations of 150 and 500 m. The results indicate an O density of 1.15 billion per cu cm (plus or minus 30%), agreeing with mass-spectrometric measurements made under similar conditions, and an N density of 5.6 to 11.2 million per cu cm, in good agreement with recent measurements but suggesting a smaller diurnal variation than predicted by present models.

Donahue, T. M.↗
NASA NTRS1977

Ultraviolet absorption: Experiment MA-059

A technique devised to permit the measurement of atmospheric species concentrations is described. This technique involves the application of atomic absorption spectroscopy and the quantitative observation of resonance fluorescence in which atomic or molecular species scatter resonance radiation from a light source into a detector. A beam of atomic oxygen and atomic nitrogen resonance radiation, strong unabsorbable oxygen and nitrogen radiation, and visual radiation was sent from Apollo to Soyuz. The density of atomic oxygen and atomic nitrogen between the two spacecraft was measured by observing the amount of resonance radiation absorbed when the line joining Apollo and Soyuz was perpendicular to their velocity with respect to the ambient atmosphere. Results of postflight analysis of the resonance fluorescence data are discussed.

Donahue, T. M.↗
NASA NTRS1976

Ultraviolet absorption experiment MA-059

The ultraviolet absorption experiment performed during the Apollo Soyuz mission involved sending a beam of atomic oxygen and atomic nitrogen resonance radiation, strong unabsorbable oxygen and nitrogen radiation, and visual radiation, all filling the same 3 deg-wide field of view from the Apollo to the Soyuz. The radiation struck a retroreflector array on the Soyuz and was returned to a spectrometer onboard the Apollo. The density of atomic oxygen and atomic nitrogen between the two spacecraft was measured by observing the amount of resonance radiation absorbed when the line joining Apollo and Soyuz was perpendicular to their velocity with respect to the ambient atmosphere. Information concerning oxygen densities was also obtained by observation of resonantly fluorescent light. The absorption experiments for atomic oxygen and atomic nitrogen were successfully performed at a range of 500 meters, and abundant resonance fluorescence data were obtained.

Donahue, T. M.↗