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Hong, S. D.

Publications and source records attributed to Hong, S. D..

15 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Stress-relaxation and stress-strain behavior of poly(ethylene-co-vinylacetate) at varying crosslink density

The stress-relaxation modulus of an unfilled ethylene vinyl acetate polymer at three different degrees of crosslinking was measured at 15 temperatures over a temperature span of about 160 C. At each temperature, the time response was measured for at least three decades of time. From these data it was possible to construct a master curve for each degree of crosslinking. The time-temperature shift factors, alpha(T), were found to be related to temperature by the relation log alpha(T) = -A(T - 273), where the parameter A has an average value of 0.234 for the three materials.

Fedors, R. F.↗
NASA NTRS1984

Morphology and Dynamic Mechanical Properties of Diglycidyl Ether of Bisphenol-A Toughened with Carboxyl-Terminated Butadiene-Acrylonitrile

The fracture toughness of an incorporation of a carboxyl-terminated butadiene acrylonitrile (CTBN) elastomer in diglycidyl ether bisphenol A (DGEBA) resin was investigated. Measurements of dynamic mechanical properties, scanning electron microscopy and small-angle X-ray scattering were carried out to characterize the state of cure, morphology and particle size and size distribution of the neat resins and their graphite fiber reinforced composites.

Hong, S. D.↗
NASA NTRS1984

Estimating the Lifetimes of Nickel/Cadmium Cells

Equation based on model of flaw growth. Model assumes cell fails by growth of preexisting flaws. Flaws described by three important quantities: total number of flaws, distribution of flaw sizes and rate of flaw growth. When flaw reaches critical size failure occurs. Flaw concept, in addition to providing ready explanation for reduced lifetime, predicts two important charateristics: statistical variability of lifetime data and dependence of lifetime on volume of sample.

Fedors, R. F.↗
NASA NTRS1984

Automated Mercury Dilatometer

Task of reading and recording indications of mercury dilatometer simplified by automatic system. Volume change of sample under test converted into electrical signal. Device modified by addition of resistance wire to mercury column. Height of column read indirectly by measuring resistance between terminals. Signal suitable for strip-chart recording or other processing.

Hong, S. D.↗
NASA NTRS1983

Photothermal degradation of ethylene/vinylacetate copolymer

Photothermal degradation studies were conducted on a 'stabilized' formulation of ethylene/vinyl acetate copolymer (EVA) in the temperature range 25-105 C under three different oxygen environments (in open air, with limited access to O2, and in a dark closed stagnant oven). These studies were performed in order to evaluate the utility of EVA as an encapsulation material for photovoltaic modules. Results showed that at low temperature (25 C), slow photooxidation of the polymer occurred via electronic energy transfer involving the UV absorber incorporated in the polymer. However, no changes in the physical properties of the bulk polymer were detected up to 1500 hours of irradiation. At elevated temperatures, leaching and evaporation of the additives occurred, which ultimately resulted in the chemical crosslinking of the copolymer and the formation of volatile photoproducts such as acetic acid.

Liang, R. H.↗
NASA NTRS1983

Mechanism and kinetics of the curing process in a resin system

The present investigation is concerned with the development of a cure reactivity model for a resin system consisting of tetraglycidyl diaminodiphenyl methane (TGDDM) and diaminodiphenyl sulfone (DDS), taking into account the temperature range from 153 to 177 C. Differential scanning calorimetry and FT-IR spectroscopy have been used to investigate the cure kinetics of the resin with the objective to obtain a correlation between the total conversion and the rates of formation and disappearance of specific functionalities. It was found that the overall process can be satisfactorily described in terms of two first order processes.

Moacanin, J.↗
NASA NTRS1982

A failure model for sealed nickel-cadmium batteries

A model has been developed to describe failure in electrochemical batteries. The model is based on the concept of the existence and subsequent growth of flaws which ultimately lead to battery failure. This model provides, in a natural way, for the statistical variability of lifetime data. The model as applied to the Crane data indicates that when the effects of temperature and depth of discharge are taken into account, the observed variability in lifetime data is due almost entirely to statistical variability inherent in the battery itself.

Fedors, R. F.↗
NASA NTRS1982

Viscoelastic Properties of Polymer Blends

Viscosity, shear modulus and other viscoelastic properties of multicomponent polymer blends are predicted from behavior of individual components, using a mathematical model. Model is extension of two-component-blend model based on Rouse-Bueche-Zimm theory of polymer viscoelasticity. Extension assumes that probabilities of forming various possible intracomponent and intercomponent entanglements among polymer molecules are proportional to relative abundances of components.

Hong, S. D.↗
NASA NTRS1981

Effect of physical aging on stress relaxation of poly/methyl methacrylate/

A study was made on the stress relaxation behavior at 25 C of poly(methyl methacrylate) in uniaxial tension as a function of physical aging at both room temperature and 60 C. Test specimens were compression molded at 165 C, then quenched to room temperature and allowed to age for up to 30 days prior to testing. Stress relaxation curves measured after different aging times could be superposed to a single master curve for each aging temperature. Superposition was achieved by applying vertical and horizontal shifts. Hence, the shape of the response curves was not changed by aging. This is in accordance with observations made by Struik for tensile creep curves. Volume changes as a function of physical aging were also determined. Simple exponential relationships were observed between volume and both horizontal and vertical shifts. The horizontal shift implies a shift in the effective time scale caused by a change in free volume. The vertical shifts could be correlated with changes in Young's modulus caused by a change in density. For the range of aging studied, the response time scale varied over nearly two decades of log-time. For the same conditions modulus varied by 30 percent.

Cizmecioglu, M.↗
NASA NTRS1981

Analysis of the tensile stress-strain behavior of elastomers at constant strain rates. I - Criteria for separability of the time and strain effects

A theoretical analysis of the tensile stress-strain relation of elastomers at constant strain rate is presented which shows that the time and the stress effect are separable if the experimental time scale coincides with a segment of the relaxation modulus that can be described by a single power law. It is also shown that time-strain separability is valid if the strain function is linearly proportional to the Cauchy strain, and that when time-strain separability holds, two strain-dependent quantities can be obtained experimentally. In the case where time and strain effect are not separable, superposition can be achieved only by using temperature and strain-dependent shift factors.

Hong, S. D.↗
NASA NTRS1981

Broadband optical radiation detector

A method and apparatus for detecting optical radiation by optically monitoring temperature changes in a microvolume caused by absorption of the optical radiation to be detected is described. More specifically, a thermal lens forming material is provided which has first and second opposite, substantially parallel surfaces. A reflective coating is formed on the first surface, and a radiation absorbing coating is formed on the reflective coating. Chopped, incoming optical radiation to be detected is directed to irradiate a small portion of the radiation absorbing coating. Heat generated in this small area is conducted to the lens forming material through the reflective coating, thereby raising the temperature of a small portion of the lens forming material and causing a thermal lens to be formed therein.

Gupta, A.↗
NASA NTRS1981

Double-beam optical method and apparatus for measuring thermal diffusivity and other molecular dynamic processes in utilizing the transient thermal lens effect

A sample material was irradiated by relatively high power, short pulses from a dye laser. Energy from the pulses was absorbed by the sample material, thereby forming a thermal lens in the area of absorption. The pulse repetition rate was chosen so that the thermal lens is substantially dissipated by the time the next pulse reaches the sample material. A probe light beam, which in a specific embodiment is a relatively low power, continuous wave (cw) laser beam, irradiated the thermal lens formed in the sample material. The intensity characteristics of the probe light beam subsequent to irradiation of the thermal lens is related to changes in the refractive index of the sample material as the thermal lens is formed and dissipated.

Moacanin, J.↗
NASA NTRS1980

Changes in "thermal lens" measure diffusivity

In an extension of "thermal lens" effect to new applications and better resolution, two laser beams combine to rapidly measure thermal diffusivity and other molecular dynamic properties. New double-beam technique handles very small samples unlike classical techniques for measuring diffusivity. It can be used for measurements on samples undergoing stress, making it applicable to data collection for structural engineering.

Gupta, A.↗
NASA NTRS1979

Viscoelastic properties of entangled polymers - Ternary blends of monodisperse homopolymers

In a previous publication from this laboratory, the Rouse-Bueche-Zimm molecular theory of viscoelasticity has been extended by using a transient network model to apply to binary blends of monodisperse polymers with chain entanglements. The dynamics of the entanglements were modeled both by the enhanced frictional coefficients and by the additional elastic couplings. It was recognized that entanglements not only may form between chains of the same lengths (intracomponent entanglements) but also between those of different lengths (intercomponent entanglements). At a given intercomponent entanglement, the longer chain was assumed to have the frictional coefficient of the shorter chain. Similarly, for blends consisting of several monodisperse components with different molecular weights, such modifications are also required to predict their linear viscoelastic behavior. The frequency of these interactions is assumed to be proportional to the weight ratio of the respective component chains in the blend. Equations of motion are formulated for each component and solved numerically for the relaxation time spectra. Linear viscoelastic properties such as the dynamic mechanical moduli, stress relaxation moduli, and zero-shear viscosity can then be computed for these systems by linear summation of those of the components.

Soong, D.↗