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Hodges, R. R., Jr.

Publications and source records attributed to Hodges, R. R., Jr..

At least 19 records

Isotopic fractionation of hydrogen in planetary exospheres due to ionosphere-exosphere coupling - Implications for Venus

The paper considers isotopic hydrogen fractionation processes in the Venusian exosphere due to ionosphere-exosphere coupling by addressing two deficiencies in the present theory of differential escape. First, a set of D/H isotopic fractionation curves is derived for the ion-neutral interactions of charge and collisional momentum transfer, and these are compared with the results of Gurwell and Yung (1993) for hot O collisional ejection. Then, the question of the relative importance of collisional ejection in atmospheric escape is reexamined using two simple exosphere models. It is shown that O-O collisions suppress the high energy component of the hot O distribution by more than a factor of 10. Moreover, the ballistic trajectories of fast O atoms that reach the nighttime reservoir of exospheric hydrogen favor downward scatter of D and H rather than their escape. It is concluded that, due to severe limits placed on the effectiveness of collisional ejection, the differential escape of D and H from Venus is determined by charge exchange interactions rather than the collisional ejection.

Hodges, R. R., Jr.

Venus methane and water

Data collected by the Pioneer Venus Large Probe Neutral Mass Spectrometer are presented and discussed. Results indicate the presence of a large amount of methane in the Venus atmosphere from 60 km to the surface. Deuterium transfer from atmospheric HDO to poorly deuterated methane may account for the puzzling apparent gradient in the water vapor mixing ration below 10 km. Deuterium transfer within the mass spectrometer may cause reduction in the apparent ratio of HDO to H2O. Accounting for the deuterium atoms leads to a revised water vapor mixing ratio of 28 ppm. Arguments against the methane detected being purely atmospheric are overwhelming. The methane may have been generated by a reaction between a highly deuterated atmospheric constituent and a poorly deuterated instrumental contaminant.

Donahue, Thomas M.

Collision cross sections and diffusion parameters for H and D in atomic oxygen

Modeling the behavior of H and D in planetary exospheres requires detailed knowledge of the differential scattering cross sections for all of the important neutral-neutral and ion-neutral collision processes affecting these species over their entire ranges of interaction energies. In the upper atmospheres of Earth, Venus, and other planets as well, the interactions of H and D with atomic oxygen determine the rates of diffusion of escaping hydrogen isotopes through the thermosphere, the velocity distributions of exospheric atoms that encounter the upper thermosphere, the lifetimes of exospheric orbiters with periapsides near the exobase, and the transfer of momentum in collisions with hot O. The nature of H-O and D-O collisions and the derivation of a data base consisting of phase shifts and the differential, total, and momentum transfer cross sections for these interactions in the energy range 0.001 - 10 eV are discussed. Coefficients of mutual diffusion and thermal diffusion factors are calculated for temperatures of planetary interest.

Hodges, R. R., Jr.

Charge transfer and momentum exchange in exospheric D-H(+) and H-D(+) collisions

Mechanisms that control the escape of deuterium from planetary exospheres include the acceleration of D(+) in the polar wind, and the production of suprathermal D atoms through nonthermal collisions. In this paper we examine the effects of neutral-ion interactions involving deuterium and hydrogen on the velocity distribution of neutral D. A two-center scattering approximation is used as the basis for calculations of the differential cross sections for charge transfer and elastic scatter in collision of H with D(+) and of D with H(+) for ionosphere-exosphere collision energies below 10 e V. These data are used to derive temperature dependent rate coefficients for the charge transfer branches of these interactions, and to determine the effects of ion-neutral temperature differences on the rate of generation of suprathermal D through charge transfer and elastic scatter.

Hodges, R. R., Jr.

Past and present water budget of Venus

Attention is given to a detailed analysis of Pioneer Venus large-probe neutral mass spectrometer data which confirm an earlier report that the abundance of Venus deuterium relative to hydrogen is two orders of magnitude larger than that of terrestrial deuterium. The D/H ratio in the bulk atmosphere of Venus today is found to be between 0.014 and 0.02. The argument that present-day HDO can be in a steady state with exogenous (cometary) sources is based on an underestimate of the hydrogen abundance and an overestimate of current escape rates. The large isotope ratio requires that Venus once had above-surface water amounting to at least a few tenths of a percent of a terrestrial ocean and has since lost almost all of the associated hydrogen.

Donahue, T. M.

Methane measurement by the Pioneer Venus large probe neutral mass spectrometer

The Pioneer Venus Large Probe Mass Spectrometer detected a large quantity of methane as it descended below 20 km in the atmosphere of Venus. Terrestrial methane and Xe-136, both originating in the same container and flowing through the same plumbing, were deliberately released inside the mass spectrometer for instrumental reasons. However, the Xe-136 did not exhibit behavior similar to methane during Venus entry, nor did CH4 in laboratory simulations. The CH4 was deuterium poor compared to Venus water and hydrogen. While the inlet to the mass spectrometer was clogged with sulfuric acid droplets, significant deuteration of CH4 and its H2 progeny was observed. Since the only source of deuterium identifiable was water from sulfuric acid, we have concluded that we should correct the HDO/H2O ratio in Venus water from 3.2 x 10(exp -2) to (5 plus or minus 0.7) x 10(exp -2). When the probe was in the lower atmosphere, transfer of deuterium from Venus HDO and HD to CH4 can account quantitatively for the deficiencies recorded in HDO and HD below 10 km, and consequently, the mysterious gradients in water vapor and hydrogen mixing ratios we have reported. The revision in the D/H ratio reduces the mixing ratio of water vapor (and H2) reported previously by a factor of 3.2/5. We are not yet able to say whether the methane detected was atmospheric or an instrumental artifact. If it was atmospheric, its release must have been episodic and highly localized. Otherwise, the large D/H ratio in Venus water and hydrogen could not be maintained.

Donahue, T. M.

Exospheric transport restrictions on water ice in lunar polar traps

There is little doubt that at least 10 exp 17 g of water has accreted on the moon as a result of the reduction of ferric iron at the regolith surface by solar wind protons, the vaporization of chondrites, and perhaps comet impacts. Lacking an efficient escape mechanism, most of this water (or its progeny) is probably on the moon now. If the water were to have migrated to permanently shaded cold traps near the lunar poles, ice deposts with densities greater than 1000 g/sq cm would cover the traps, providing accessible resources. However, exospheric transport considerations suggest that the actual amount of water ice in the cold traps is probably too small to be of practical interest. The alternative is global assimilation of most of the water into the regolith, a process that must account for about 30 micromoles of water per gram of soil.

Hodges, R. R., Jr.

Ionosphere-exosphere coupling through charge exchange and momentum transfer in hydrogen-proton collisions

The implications of a traditional assumption of exospheric physics, that collisions of hydrogen atoms and protons preferentially result in charge exchange with negligible momentum transfer are examined. Initially adopted as a necessary convenience to accommodate limited computer resources in exosphere model calculations, this approximation results in a direct transformation of the proton velocity distribution into a hot component of neutral hydrogen. With expanding computational facilities, the need for the approximation has passed. As the first step toward its replacement with a realistic, quantum mechanical model of the H - H(+) collision process, differential and cumulative cross sections were calculated for quantum elastic scattering of indistinguishable nuclei for a fine grid of encounter energies and scattering angles. These data are used to study the nature of ionosphere-exosphere coupling through H - H(+) collisions, and to demonstrate that the distribution of velocities of scattered H produced in the traditional exospheric charge exchange approximation, as well as that arising from an alternative, fluid dynamic approach, leads to unacceptable abundances of coronal atoms in long-term, highly elliptic trajectories.

Hodges, R. R., Jr.

Hydrogen Balmer alpha intensity distributions and line profiles from multiple scattering theory using realistic geocoronal models

The H Balmer alpha nightglow is investigated by using Monte Carlo models of asymmetric geocoronal atomic hydrogen distributions as input to a radiative transfer model of solar Lyman-beta radiation in the thermosphere and atmosphere. It is shown that it is essential to include multiple scattering of Lyman-beta radiation in the interpretation of Balmer alpha airglow data. Observations of diurnal variation in the Balmer alpha airglow showing slightly greater intensities in the morning relative to evening are consistent with theory. No evidence is found for anything other than a single sinusoidal diurnal variation of exobase density. Dramatic changes in effective temperature derived from the observed Balmer alpha line profiles are expected on the basis of changing illumination conditions in the thermosphere and exosphere as different regions of the sky are scanned.

Anderson, D. E., Jr.

Monte Carlo models for the terrestrial exosphere over a solar cycle

Improved Monte Carlo exosphere simulations for the concentration and velocity distribution of hydrogen in the terrestrial exosphere were formulated for minimum, medium, and maximum solar cycle conditions. Both the classical exobase source of hot hydrogen and the plasmaspheric source were included, along with solar radiation pressure and photoionization. It was found that at solar minimum the hydrogen from the charge exchange of hot ions in the plasmasphere exceeds that from the exobase source not only for escape but for the population at geocentric distances greater than 2 earth radii. At about two earth radii, the equivalent temperature is about 50 percent greater than that of the exobase, a situation similar to that of the 'two-temperature' Venusian exosphere. Diurnal variations were calculated for altitudes of up to 30 earth radii; for all levels of solar activity, the inclusion of radiation pressure led to a semidiurnal variation at 3-8 earth radii and a high-altitude night/day asymmetry constituting the 'geotail'.

Tinsley, B. A.

Investigation of the daytime lunar atmosphere

Lunar atmosphere research has tended to center on gases with predictably large sources and on those which have been identified by Apollo experiments. An early candidate atmospheric constituent was Ar 40 which was noted by Heyman and Yaniv to have a surface correlated component in returned soil samples, and an abundance in excess of what can be explained by potassium decay. The source of the excess argon was attributed to atmospheric argon ions which have been accelerated by solar wind fields and implanted in soil grains.

Hodges, R. R., Jr.

The influence of thermospheric winds on exospheric hydrogen on Venus

Monte Carlo models of the distribution of atomic hydrogen in the exosphere of Venus were computed which simulate the effects of thermospheric winds and the production of a 'hot' hydrogen component by charge exchange of H(+) and H and Q in the exosphere, as well as classic exospheric processes. A thermosphere wind system that is approximated by a retrograde rotating component with equatorial speed of 100 m/sec superimposed on a diurnal solar tide with cross-terminator day-to-night winds of 200 m/sec is shown to be compatible with the thermospheric hydrogen distribution deduced from Pioneer Venus orbiter measurements.

Hodges, R. R., Jr.

Venus was wet - A measurement of the ratio of deuterium to hydrogen

The deuterium-hydrogen abundance ratio in the Venus atmosphere was measured while the inlets to the Pioneer Venus large probe mass spectrometer were coated with sulfuric acid from Venus' clouds. The ratio is 0.016 + or - 0.002. The hundredfold enrichment of deuterium means that at least 0.3 percent of a terrestrial ocean was outgassed on Venus, but is consistent with a much greater production.

Donahue, T. M.

Charge exchange in the Venus ionosphere as the source of the hot exospheric hydrogen

A global Monte Carlo model of the exosphere of Venus, simulating the normal exospheric processes, as well as the production of a 'hot' hydrogen component by charge exchange of H(+) with H and O, has been computed. The resulting altitude profiles of atomic hydrogen concentration over both the day and night hemispheres are in reasonable agreement with Mariner 5 and Mariner 10 observations of Lyman-alpha, showing that the ionospheric charge exchange reactions are a significant source of 'hot' hydrogen, possibly the dominant source. However, the uncertainties in the available atomic hydrogen data allow for production of a similar amount of nonthermal H by chemical processes involving H2 as suggested by Kumar and Hunten (1974).

Hodges, R. R., Jr.

The effect of the charge exchange source on the velocity and 'temperature' distributions and their anisotropies in the earth's exosphere

The velocity distribution of atomic hydrogen in the earth's exosphere is calculated as a function of altitude and direction taking into account both the classic exobase source and the higher-altitude plasmaspheric charge exchange source. Calculations are performed on the basis of a Monte Carlo technique in which random ballistic trajectories of individual atoms are traced through a three-dimensional grid of audit zones, at which relative concentrations and momentum or energy fluxes are obtained. In the case of the classical exobase source alone, the slope of the velocity distribution is constant only for the upward radial velocity component and increases dramatically with altitude for the incoming radial and transverse velocity components, resulting in a temperature decrease. The charge exchange source, which produces the satellite hydrogen component and the hot ballistic and escape components of the exosphere, is found to enhance the wings of the velocity distributions, however this effect is not sufficient to overcome the temperature decreases at altitudes above one earth radius. The resulting global model of the hydrogen exosphere may be used as a realistic basis for radiative transfer calculations.

Hodges, R. R., Jr.

Krypton and xenon in the atmosphere of Venus

The paper reports a determination by the Pioneer Venus large probe neutral mass spectrometer of upper limits to the concentration of krypton and xenon along with most of their isotopes in the atmosphere of Venus. The upper limit to the krypton mixing ratio is estimated at 47 ppb, with a very conservative estimate at 69 ppb. The probable upper limit to the sum of the mixing ratios of the isotopes Xe-128, Xe-129, Xe-130, Xe-131, and Xe-132 is 40 ppb by volume, with a very conservative upper limit three times this large.

Donahue, T. M.

Methods for Monte Carlo simulation of the exospheres of the moon and Mercury

A general form of the integral equation of exospheric transport on moon-like bodies is derived in a form that permits arbitrary specification of time varying physical processes affecting atom creation and annihilation, atom-regolith collisions, adsorption and desorption, and nonplanetocentric acceleration. Because these processes usually defy analytic representation, the Monte Carlo method of solution of the transport equation, the only viable alternative, is described in detail, with separate discussions of the methods of specification of physical processes as probabalistic functions. Proof of the validity of the Monte Carlo exosphere simulation method is provided in the form of a comparison of analytic and Monte Carlo solutions to three classical, and analytically tractable, exosphere problems. One of the key phenomena in moonlike exosphere simulations, the distribution of velocities of the atoms leaving a regolith, depends mainly on the nature of collisions of free atoms with rocks. It is shown that on the moon and Mercury, elastic collisions of helium atoms with a Maxwellian distribution of vibrating, bound atoms produce a nearly Maxwellian distribution of helium velocities, despite the absence of speeds in excess of escape in the impinging helium velocity distribution.

Hodges, R. R., Jr.

Pioneer Venus Sounder Probe Neutral Gas Mass Spectrometer

A neutral gas mass spectrometer was flown to Venus as part of the Pioneer Venus Multiprobe to measure the composition of its lower atmosphere. The instrument, mounted in the Sounder Probe, was activated after the probe entered the top of the atmosphere, and it obtained data during the descent from 62 km to the surface. Atmospheric gases were sampled through a pair of microleaks, the effluent from which was pumped by a combination of ion and getter pumping. A pneumatically operated valve, controlled by the ambient atmospheric pressure, maintained the ion source pressure at a nearly constant value during descent while the atmospheric pressure varied by three orders of magnitude. A single focusing magnetic sector field mass spectrometer with mass resolution sufficient to reasonably separate argon from C3H4 at 40 amu provided the mass analysis and relative abundance measurements. A microprocessor controlled the operation of the mass spectrometer through a highly efficient peak-tip stepping routine and data compression algorithm that effected a scan of the mass spectrum from 1 to 208 amu in 64 sec while requiring an information rate of only 40 bits/sec to return the data to earth. A subscale height altitude resolution was thus obtained. Weight, size, and power requirements were minimized to be consistent with interplanetary flight contraints.

Hoffman, J. H.