Engineering topics

Hiroi, T.

Publications and source records attributed to Hiroi, T..

At least 19 records

NASA NTRS2018

The Almahata Sitta Polymict Ureilite from the University of Khartoum Collection: Classification, Distribution of Clast Types in the Strewn Field, New Meteorite Types, and Implications for the Structure of Asteroid 2008 TC3

The Almahata Sitta (AhS) polymict ureilite fell in 2008 when asteroid 2008 TC3 impacted over Sudan]. It is the first meteorite to originate from an asteroid that had been tracked and studied in space (with spectral classification) before impact, and provides a unique opportunity to correlate properties of meteorites with those of their parent asteroid. More than 700 monolithologic stones from the AhS fall were collected. Of those previously studied, approx. 70% were ureilites and approx. 30% were chondrites. It has been inferred that 2008 TC3 was loosely aggregated and porous and disintegrated in the atmosphere, with only its most coherent clasts falling as stones. However, understanding the structure of this asteroid is limited by incomplete study of the heterogeneous stones, and the loss of most of the mass of the asteroid. The University of Khartoum (UOK) AhS collection contains over >600 AhS stones with find coordinates. We are studying this collection to determine: 1) the proportion of ureilitic to various non-ureilitic stones; 2) the distribution of types of stones in the strewn field; and 3) the compositional and physical structure of 2008 TC3. We report on 61 new stones, including a unique sample that may represent the bulk of the material lost from 2008 TC3.

Goodrich, C. A.↗

NASA NTRS2014

Compositional Diversity of the Vestan Regolith Derived from Howardite Compositions and Dawn VIR Spectra

Howardite, eucrite and diogenite meteorites likely come from asteroid 4 Vesta [1]. Howardites - physical mixtures of eucrites and diogenites - are of two subtypes: regolithic howardites were gardened in the true regolith; fragmental howardites are simple polymict breccias [2]. The Dawn spacecraft imaged the howarditic surface of Vesta with the visible and infrared mapping spectrometer (VIR) resulting in qualitative maps of the distributions of distinct diogenite-rich and eucrite-rich terranes [3, 4]. We are developing a robust basis for quantitative mapping of the distribution of lithologic types using spectra acquired on splits of well-characterized howardites [5, 6]. Spectra were measured on sample powders sieved to <75 μm in the laboratories of the Istituto di Astrofisica e Planetologia Spaziali and Brown University. Data reduction was done using the methods developed to process Dawn VIR spectra [4]. The band parameters for the ~1 and ~2 μm pyroxene absorption features (hereafter BI and BII) can be directly compared to Dawn VIR results. Regolithic howardites have shallower BI and BII absorptions compared to fragmental howardites with similar compositions. However, there are statistically significant correlations between Al or Ca contents and BI or BII center wavelengths regardless of howardite subtype. Diogenites are poor in Al and Ca while eucrites are rich in these elements. The laboratory spectra can thus be directly correlated with the percentage of eucrite material contained in the howardites. We are using these correlations to quantitatively map Al and Ca distributions, and thus the percentage of eucritic material, in the current regolith of Vesta.

Mittlefehldt, D. W.↗

NASA NTRS2013

Towards Calibrating the Vestan Regolith: Correlating the Petrology, Chemistry and Spectroscopy of Howardites

The Dawn spacecraft carries a visible and infrared mapping spectrometer (VIR) [1] that has acquired spectra for the wavelength range 0.25-5.0 μm at various spatial resolutions covering much of the vestan surface [2]. Through comparison of VIR spectra with laboratory spectra of howardite, eucrite and diogenite meteorites, the distribution of more diogenite-rich and more eucrite-rich terranes on Vesta have been mapped [3], but these maps are qualitative in nature. The available laboratory spectra are not well-integrated with detailed sample petrology or composition limiting their utility for lithologic mapping. Importantly, howardites are now recognized to come in two subtypes, regolithic and fragmental [4]. The former are breccias assembled in part from true regolith, while the latter have had much less exposure to the space environment. We are attempting to develop a more quantitative basis for mapping the distribution of lithologic types on Vesta through acquiring laboratory spectra on splits of howardites that have been petrologically and chemically characterized [5]. Noble gas analyses have been done on some allowing identification of those howardites that have been exposed in the true regolith of Vesta [6].

Mittlefehldt, D. W.↗

NASA NTRS2013

Asteroidal Space Weathering: The Major Role of FeS

Space weathering (SW) effects on the lunar surface are reasonably well-understood from sample analyses, remote-sensing data, and experiments, yet our knowledge of asteroidal SW effects are far less constrained. While the same SW processes are operating on asteroids and the Moon, namely solar wind irradiation, impact vaporization and condensation, and impact melting, their relative rates and efficiencies are poorly known, as are their effects on such vastly different parent materials. Asteroidal SW models based on remote-sensing data and experiments are in wide disagreement over the dominant mechanisms involved and their kinetics. Lunar space weathering effects observed in UVVIS-NIR spectra result from surface- and volume-correlated nanophase Fe metal (npFe(sup 0)) particles. In the lunar case, it is the tiny vapor-deposited npFe(sup 0) that provides much of the spectral reddening, while the coarser (largely melt-derived) npFe(sup 0) produce lowered albedos. Nanophase FeS (npFeS) particles are expected to modify reflectance spectra in much the same way as npFe(sup 0) particles. Here we report the results of experiments designed to explore the efficiency of npFeS production via the main space weathering processes operating in the asteroid belt.

Keller, L. P.↗

NASA NTRS2012

Comparisons of Mineralogy of Lunar Meteorites Possibly from the Farside and The Kaguya Remote Sensing Data to Reconstruct the Earliest Anorthositic Crust of the Moon

Ohtake et al. [1] observed by the Kaguya multiband imager and spectral profiler anorthosites composed of nearly pure anorthite (PAN) at numerous locations in the farside highlands. Based on the Th map made by the GRS group of the Kaguya mission, Kobayashi et al. [2] showed that the lowest Th region in the lunar farside occurs near the equatorial region and noted that the regions well correspond to the lunar highest region and the thickest crust region recently measured by Kaguya mission [3,4]. Such remote sensing data have been interpreted in terms of mineralogical studies of lunar meteorites of the Dhofar 489 group [5,6] (e.g., Dhofar 489, 908, and 307) and Yamato (Y-) 86032 [7], all possibly from the farside highlands. Although the presence of magnesian anorthosites in the Dhofar 489 group has been reported, we have not encountered large clast clearly identifiable as PAN. In this study, we investigated mineralogy and textures of large clasts of nearly pure anorthosites recognized in Dhofar 911 and the d2 clast in Dhofar 489 [8]. The d2 clast is the largest white anorthosite clast in Dhofar 489, but its mineralogy has not been investigated at that time. The low bulk FeO concentrations suggests that the d2 clast may be the pure anorthosite with very low abundance of mafic silicates. In conjunction with all data of the Dhofar 489 group including Dhofar 489, 908, 309 and 307, we propose a model of formation of the farside crust.

Takeda, H.↗

NASA NTRS2012

Diversity in the Visible-NIR Absorption Band Characteristics of Lunar and Asteroidal Plagioclase

Studying the visible and near-infrared (VNIR) spectral properties of plagioclase has been challenging because of the difficulty in obtaining good plagioclase separates from pristine planetary materials such as meteorites and returned lunar samples. After an early study indicated that the 1.25 m band position of plagioclase spectrum might be correlated with the molar percentage of anorthite (An#) [1], there have been few studies which dealt with the band center behavior. In this study, the VNIR absorption band parameters of plagioclase samples have been derived using the modified Gaussian model (MGM) [2] following a pioneering study by [3].

Hiroi, T.↗

NASA NTRS2011

Mineralogy of Inverted Pigeonite and Plagioclase in Cumulate Eucrites Y-980433 and Y-980318 with Reference to Early Crust Formation of the Vesta-Like Body

On July 16, the Dawn spacecraft became the first probe to enter orbit around asteroid 4 Vesta and will study the asteroid for a year before departing for Ceres. The Vesta-HED link is directly tied to the observed and inferred mineralogy of the asteroid and the mineralogy of the meteorites [1]. Pieters et al. [2] reported reflectance spectra of the Yamato- (Y-)980318 cumulate eucrite as a part of their study on the Asteroid-Meteorite Links in connection with the Dawn Mission. Pyroxenes and calcic plagioclase are the dominant minerals present in HED meteorites and provide multiple clues about how the parent body evolved [1]. The differentiation trends of HED meteorites are much simpler than those of the lunar crust

Takeda, H.↗

NASA NTRS2011

Comparisons of Mineralogy Between Cumulate Eucrites and Lunar Meteorites Possibly from the Farside Anorsothitic Crust

Anorthosites composed of nearly pure anorthite (PAN) at many locations in the farside highlands have been observed by the Kaguya multiband imager and spectral profiler [1]. Mineralogical studies of lunar meteorites of the Dhofar 489 group [2,3] and Yamato (Y-) 86032 [4], all possibly from the farside highlands, showed some aspects of the farside crust. Nyquist et al. [5] performed Sm-Nd and Ar-Ar studies of pristine ferroan anorthosites (FANs) of the returned Apollo samples and of Dhofar 908 and 489, and discussed implications for lunar crustal history. Nyquist et al. [6] reported initial results of a combined mineralogical/chronological study of the Yamato (Y-) 980318 cumulate eucrite with a conventional Sm-Nd age of 4567 24 Ma and suggested that all eucrites, including cumulate eucrites, crystallized from parental magmas within a short interval following differentiation of their parent body, and most eucrites participated in an event or events in the time interval ~4400- 4560 Ma in which many isotopic systems were partially reset. During the foregoing studies, we recognized that variations in mineralogy and chronology of lunar anorthosites are more complex than those of the crustal materials of the HED parent body. In this study, we compared the mineralogies and reflectance spectra of the cumulate eucrites, Y-980433 and 980318, to those of the Dhofar 307 lunar meteorite of the Dhofar 489 group [2]. Here we consider information from these samples to gain a better understanding of the feldspathic farside highlands and the Vesta-like body.

Takeda, H.↗

NASA NTRS2011

Space Weathering of Ordinary Chondrite Parent Bodies, Its Impact on the Method of Distinguishing H, L, and LL Types and Implications for Itokawa Samples Returned by the Hayabusa Mission

As the most abundance meteorites in our collections, ordinary chondrites potentially have very important implications on the origin and formation of our Solar System. In order to map the distribution of ordinary chondrite-like asteroids through remote sensing, the space weathering effects of ordinary chondrite parent bodies must be addressed through experiments and modeling. Of particular importance is the impact on distinguishing different types (H/L/LL) of ordinary chondrites. In addition, samples of asteroid Itokawa returned by the Hayabusa spacecraft may re~ veal the mechanism of space weathering on an LLchondrite parent body. Results of space weathering simulations on ordinary chondrites and implications for Itokawa samples are presented here.

Hiroi, T.↗

NASA NTRS2011

Experimental Space Weathering of Ordinary Chondrites by Nanopulse Laser: TEM Results

A set of ordinary chondrite meteorites has been subjected to artificial space weathering by nanopulse laser to simulate the effects of micrometeorite bombardment. Three meteorites, an H (Ehole), L (Chateau Renard - CR), and LL (Appley Bridge - AB) were lasered following the method of Sasaki et al [1]. Near IR spectra were taken before and after exposure to examine the optical changes induced and the samples were examined by scanning and transmission electron microscopy (SEM and TEM) to understand the physical changes.

Noble, S. K.↗

NASA NTRS2006

Asteroid-Meteorite Links: The Vesta Conundrum(s)

Although a direct link between the HED meteorites and the asteroid 4 Vesta is generally acknowledged, several issues continue to be actively examined that tie Vesta to early processes in the solar system. Vesta is no longer the only basaltic asteroid in the Main belt. In addition to the Vestoids of the Vesta family, the small asteroid Magnya is basaltic but appears to be unrelated to Vesta. Similarly, diversity now identified in the collection of basaltic meteorites requires more than one basaltic parent body, consistent with the abundance of differentiated parent bodies implied by iron meteorites. The timing of the formation of the Vestoids (and presumably the large crater at the south pole of Vesta) is unresolved. Peaks in Ar-Ar dates of eucrites suggest this impact event could be related to a possible late heavy bombardment at least 3.5 Gyr ago. On the other hand, the optically fresh appearance of both Vesta and the Vestoids requires either a relatively recent resurfacing event or that their surfaces do not weather in the same manner thought to occur on other asteroids such as the ordinary chondrite parent body. Diversity across the surface of Vesta has been observed with HST and there are hints of compositional variations (possibly involving minor olivine) in near-infrared spectra.

Pieters, C. M.↗

NASA NTRS2005

Observations with Near Infrared Spectrometer for Hayabusa Mission in the Cruising Phase

NIRS is a near infrared spectrometer on-board the spacecraft HAYABUSA, which aims to return samples from a near-earth asteroid, 25143 Itokawa. HAYABUSA was successfully launched by Japanese M-V-5 rocket on May 9, 2003. After the successful earth swing-by on May 19, 2004, the spacecraft is now on the way toward the asteroid, where it will arrive in this summer. During the rendezvous phase with the asteroid, we will observe the asteroid surface using NIRS and obtain reflectance spectra of the surface materials across the wavelength range of 850nm to 2100nm. Based on ground-based observations [1],[2],[3], 25143 Itokawa appears to be an S(IV) type asteroid. NIRS can detect absorption bands due to olivine and pyroxene and investigate the mineralogical composition of the surface materials, and reveal a relationship between asteroids and meteorites.

Abe, M.↗

NASA NTRS2005

Integrated Spectroscopic Studies of Hydrous Sulfate Minerals

Sulfate minerals have been identified in Martian meteorites and on Mars using a suite of instruments aboard the MER rovers. These results have confirmed previous groundbased observations and orbital measurements that suggested their presence. The orbiting OMEGA instrument on Mars Express is also finding evidence for sulfate. In order to better interpret remote-sensing data, we present here the results of a coordinated visible/near infrared (VNIR) reflectance, Moussbauer (MB), and thermal emittance study of wellcharacterized hydrous sulfate minerals.

Dyar, M. D.↗

NASA NTRS2005

Integrated Spectroscopic Studies of MIL03346

Spectroscopic studies of the SNC meteorites continue to be of great interest because they provide the only "ground truth" available for ongoing Mossbauer, thermal emittance, MidIR, nearIR, and visible spectral analysis of the martian surface. We present here results of an integrated series of measurements made on the same split of MIL03346, in order to expand our understanding of the properties of these materials and to relate them to other SNCs.

Dyar, M. D.↗

NASA NTRS2005

Meteorite WIS91600: A New Sample Related to a D- or T-type Asteroid

Since the Tagish Lake meteorite fell in January 2000, the assumed one-of-the-kind meteorite has become the hottest issue among a diversity of scientists. Meanwhile, as the physical origin of the meteorite in our solar system, D or T asteroids have been suggested by Hiroi et al. based on comparison of their visible-near-infrared (VNIR) reflectance spectra. While it is probably still true that the Tagish Lake meteorite is possibly the first recovered sample from a D or T asteroid as a meteorite fall, we report in this paper that the meteorite WIS91600 may actually be the first recovered sample from one of those asteroids as a meteorite find.

Hiroi, T.↗

NASA NTRS2005

Integrated Spectroscopic Studies of Anhydrous Sulfate Minerals

Sulfates have been identified in Martian soils and bedrock and are emerging as an important indicator for aqueous activity on Mars. Sulfate minerals can form in a variety of low-temperature (evaporitic; chemical-weathering) and high-temperature (volcanic/fumarolic; hydrothermal) environments and their formational environments can range from alkaline to acidic. Although sulfates generally form in the presence of water, not all sulfates are hydrous or contain water in their structures. Many of these anhydrous sulfates (Dana group 28; Strunz class 67A) are minerals that form as accompanying phases to the main minerals in ore deposits or as replacement deposits in sedimentary rocks. However, some form from thermal decomposition of OH or H2O-bearing sulfates, such as from the reaction [1]: jarosite = yavapaiite + Fe2O3 + H2O. Where known, the stability fields of these minerals all suggest that they would be stable under martian surface conditions [2]. Thus, anhydrous sulfate minerals may contribute to martian surface mineralogy, so they must be well-represented in spectral libraries used for interpretation of the Martian surface. We present here the preliminary results of an integrated study of emittance, reflectance, and Mossbauer spectroscopy of a suite of wel-lcharacterized anhydrous sulfates.

Lane, M. D.↗

NASA NTRS2005

Extracting Quantitative Data from Lunar Soil Spectra

Using the modified Gaussian model (MGM) developed by Sunshine et al. [1] we compared the spectral properties of the Lunar Soil Characterization Consortium (LSCC) suite of lunar soils [2,3] with their petrologic and chemical compositions to obtain quantitative data. Our initial work on Apollo 17 soils [4] suggested that useful compositional data could be elicited from high quality soil spectra. We are now able to expand upon those results with the full suite of LSCC soils that allows us to explore a much wider range of compositions and maturity states. The model is shown to be sensitive to pyroxene abundance and can evaluate the relative portion of high-Ca and low-Ca pyroxenes in the soils. In addition, the dataset has provided unexpected insights into the nature and causes of absorption bands in lunar soils. For example, it was found that two distinct absorption bands are required in the 1.2 m region of the spectrum. Neither of these bands can be attributed to plagioclase or agglutinates, but both appear to be largely due to pyroxene.

Noble, S. K.↗

NASA NTRS2005

Synchrotron-based Infrared Microspectroscopy as a Useful Tool to Study Hydration States of Meteorite Constituents

The meteorites Dho 225 and Dho 735 were recently found in Oman. Studies of their mineralogical and chemical composition suggest that these unusual meteorites are thermally metamorphosed CM2 chondrites [1,2,3]. Similar to Antarctic metamorphosed carbonaceous chondrites, the Dho 225 and Dho 735 are enriched in heavy oxygen compared to normal CMs [1,2]. However, IR studies indicating dehydration of matrix phyllosilicates are needed to confirm that the two new meteorites from Oman are thermally metamorphosed [4]. Synchrotron-based IR microspectroscopy is a new promising technique which allows the acquisition of IR spectra from extremely small samples. Here we demonstrate that this non-destructive technique is a useful tool to study hydration states of carbonaceous chondrites in situ. In addition, we acquired reflectance spectra of bulk powders of the Dho 225 and Dho 735 in the range of 0.3-50 microns.

Moroz, L. V.↗