Engineering topics

Hipskind, R. Stephen

Publications and source records attributed to Hipskind, R. Stephen.

47 records · Page 3

NASA NTRS2000

Dominant Presence of Oxygenated Organic Species in the Remote Southern Hemisphere Troposphere

Oxygenated organic species are intimately involved with the fate of nitrogen oxides (NO(sub x)) and hydrogen oxides (HO(sub x)), which are necessary for tropospheric ozone formation. A recent airborne experiment (March-April, 1999) focused over the southern hemisphere (SH) Pacific Ocean (PEM-tropics-B) provided a first opportunity for a detailed characterization of the oxygenated organic composition of the remote southern hemisphere troposphere. Three co-located multi-channel airborne instruments measured a dozen key oxygenated species (carbonyls, alcohols, organic nitrates, organic pernitrates, peroxides) along with a comprehensive suite of C2-C8 Nonmethane hydrocarbons (NMHC). These measurements reveal that in the tropical SH (0-30 deg south), oxygenated chemical abundances are extremely large and collectively are nearly five times those of NMHC. Even in the NH remote atmospheres their burden is equal to or greater than that of NMHC. The relatively uniform global distribution oxygenates (EPSILON Ox-org) is indicative of the presence of large natural and distributed sources. A global 3-D model, reflecting the present state of science, is unable to correctly simulate the atmospheric distribution and variability of several of these species.

Singh, H.↗

NASA NTRS2000

Quantifying Subsidence in the 1999-2000 Arctic Winter Vortex

Quantifying the subsidence of the polar winter stratospheric vortex is essential to the analysis of ozone depletion, as chemical destruction often occurs against a large, altitude-dependent background ozone concentration. Using N2O measurements made during SOLVE on a variety of platforms (ER-2, in-situ balloon and remote balloon), the 1999-2000 Arctic winter subsidence is determined from N2O-potential temperature correlations along several N2O isopleths. The subsidence rates are compared to those determined in other winters, and comparison is also made with results from the SLIMCAT stratospheric chemical transport model.

Greenblatt, Jeffery B.↗

NASA NTRS2000

Processes Controlling Water Vapor in the Winter Arctic Stratospheric Middleworld

Abstract: Water vapor in the winter arctic stratospheric middleworld (that part of the stratosphere with potential temperatures lower than the tropical tropopause) is important for two reasons: (1) the arctic middleworld is a source of air for the upper troposphere because of the generally downward motion, and thus its water vapor content helps determine upper tropospheric water, a critical part of the earth's radiation budget; and (2) under appropriate conditions, relative humidities will be large even to the point of stratospheric cirrus cloud formation, leading to the production of active chlorine species that could destroy ozone. On a number of occasions during SOLVE, clouds were observed in the stratospheric middleworld by the DC-8 aircraft. The relationship between ozone and CO from aircraft measurements taken during the early, middle and late part of the winter of 1999-2000 show that recent mixing with tropospheric air extends up to ozone values of about 350-450 ppbv. Above that level, the relationship suggests stratospheric air with minimal tropospheric influence. The transition is quite abrupt, particularly in early spring. Trajectory analyses are consistent with these relationships, with a significant drop-off in the percentage of trajectories with tropospheric PV values in their 10-day history as in-situ ozone increases above 400 ppbv. The water distribution is affected by these mixing characteristics, and by cloud formation. Significant cloud formation along trajectories occurs up to ozone values of about 400 ppbv during the early spring, with small, but nonzero probabilities extending to 550 ppbv. Cloud formation in the stratospheric middleworld is minimal during early and midwinter. Also important is the fact that, during early spring 30% of the trajectories near the tropopause (ozone values less than 200 ppbv) have minimum saturation mixing ratios less than 5 ppmv. Such parcels can mix out into the troposphere and could lead to very dry conditions in the upper troposphere at high latitudes during spring,

Pfister, Leonhard↗

NASA NTRS2000

Defining the Vortex Boundary Using N2O Measurements

Defining the stratospheric vortex boundary is typically done using; the Nash criterion,(a) which determines the maximum gradient of Ertel's potential vorticity (EPV) in the vicinity of maximum zonal winds. However, such a procedure is insensitive to small-scale variations near the boundary, because EPV maps rely on interpolation from sparse data, and are therefore only accurate over large areas. An examination was made of high-speed N2O measurements during SOLVE, from Argus ER-2 flights across the vortex boundary in the 1999-2000 Arctic winter, to see whether sharp changes in N2O concentrations co-occur sufficiently well with the Nash definition of the vortex edge to serve as a reliable alternate definition.

Greenblatt, Jeffery↗

NASA NTRS2000

Comparison of Aerosol Single Scattering Albedos Derived By Diverse Techniques in Two North Atlantic Experiments

Aerosol single scattering albedo w (the ratio of scattering to extinction) is important in determining aerosol climatic effects, in explaining relationships between calculated and measured radiative fluxes, and in retrieving aerosol optical depths from satellite radiances. Recently, two experiments in the North Atlantic region, TARFOX and ACE-2, determined aerosol w by a variety of techniques. The techniques included fitting of calculated to measured fluxes; retrievals of w from skylight radiances; best fits of complex refractive index to profiles of backscatter, extinction, and size distribution; and in situ measurements of scattering and absorption at the surface and aloft. Both TARFOX and ACE-2 found a fairly wide range of values for w at midvisible wavelengths, with 0.85 less than wmidvis less than 0.99 for the marine aerosol impacted by continental pollution. Frequency distributions of w could usually be approximated by lognormals in wmax-w, with some occurrence of bimodality, suggesting the influence of different aerosol sources or processing. In both TARFOX and ACE-2, closure tests between measured and calculated radiative fluxes yielded best-fit values of wmidvis of 0.90+/-0.04 for the polluted boundary layer. Although these results have the virtue of describing the column aerosol unperturbed by sampling, they are subject to questions about representativeness and possible artifacts (e.g., unknown gas absorption). The other techniques gave larger values for wmidvis for the polluted boundary layer, with a typical result of wmidvis = 0.95+/-0.04, Current uncertainties in vv are large in terms of climate effects. More tests are needed of the consistency among different methods and of humidification effects on w.

Russell, P. B.↗

NASA NTRS2000

An NOy Algorithm for Arctic Winter 2000

NOy, total reactive nitrogen, and the long-lived tracer N2O, nitrous oxide, were measured by both in situ and remote sensing instruments during the Arctic winter 1999-2000 SAGE III Ozone Loss and Validation Experiment (SOLVE). The correlation function NOy:N2O observed before the winter Arctic vortex forms, which is known as NOy(sup), is an important reference relationship for conditions in the evolving vortex. NOy(sup) can, with suitable care, be used to quantify vortex denitrification by sedimentation of polar stratospheric cloud particles when NOy data is taken throughout the winter. Observed NOy values less than the reference value can be interpreted in terms of semi-permanent removal of active nitrogen by condensation and sedimentation processes. In this paper we present a segmented function representing NOy(sup) applicable over the full range of altitudes sampled during SOLVE. We also assess the range of application of this function and some of its limitations.

Loewenstein, M.↗

NASA NTRS1998

Making Intercontinental Burning Influences Quantitative: Lessons on Transport and Geochemistry From the 3-D Simulation of CO in PEM-T A and TRACE-A

We report on two aspects of the simulation of global transport of plumes originating from subtropical biomass fires. We use of meteorological assimilation (MM5) at 2-degree resolution with a Grail cloud parameterization and a Blackadar-based planetary boundary layer parameterization. Ames's GRACES model provides emissions, transport, and an appropriate level of simulated chemical transformation. We have worked with passive-tracer CO or linear chemistry. This is appropriate since we find major work to be done in evaluating CO source strengths and transport mechanisms before chemical integrations could be meaningful. First, we present mechanisms by which CO and other pollutants are introduced into the free troposphere, and are then transported with hate dilution from approx. 0 to approx. 180 degrees longitude. One principal conduit for these plumes is the vernal subtropical jet; however the plumes appear at various altitudes and latitudes as they influenced by frontal motions and (most likely) radiative processes. A common, repeated pattern of transport has pollutant plumes arriving in the distant Pacific Ocean from Africa and South America at 25 degrees south and 14 km altitude. Following this, there is then a general appearance of pollution at extending down to 5 kin at more equatorial (10 S) and polar latitudes (to 45 S). Second, we evaluate the quantitative success of our simulation. (Such success requires efforts considerably beyond trajectory analyses, and is necessary for our community to claim an understanding of the effects of biomass burning on global atmospheric chemistry and the planet's trend in oxidizing capacity.) We find that we simulate most pollution episodes sampled by Glenn Sachse's CO instrument and the Blake hydrocarbon analyses during PENT A. We will present our current ideas on why our general levels appear satisfactory when the observations are within 20 ppb of background levels, but substantially miss the variability associated with the most intense biomass burning plumes. As time allows, we will speculate on the origins of a class of plumes that appear in the mid-troposphere, but are missing from our simulations.

Chatfield, Robert↗

NASA NTRS1998

Observations of Subvisible Cirrus Clouds and Gravity Waves at the Tropical Tropopause

Thin, subvisible cirrus (SVC) clouds at the tropical tropopause have been observed by a number of methods in a variety of observational programs, including in situ sampling and aircraft and space-based lidar. Modeling studies suggest that these clouds play an important role in dehydrating tropospheric air as it enters the stratosphere. This is because particles large enough to have significant fall speeds can form under the conditions of slow cooling that are implied by the large horizontal extent of the SVC sheets. The IR radiation that these clouds absorb, and the upward vertical motion this implies, also makes them candidates for a tropical troposphere-to-stratosphere mass transfer mechanism. They may also play a role in the earth's radiation budget. These sheets were observed on five flights during the Tropical Ozone Transport Experiment (TOTE) by the NASA Langley DIAL lidar aboard NASA's DC-8 research aircraft operating during December 1995 and February 1996 south of Hawaii. The relationship of the SVC's observed during TOTE to convection was not a simple one. One class of SVC's are within 1000 km of the persistent strong convection near 15S (the SPCZ). Trajectory analyses indicated that the SVC air masses have in fact passed through the SPCZ within a few days of observation. These clouds are very close to the tropopause, with maximum potential temperatures not much higher than 370K, consistent with in situ water and total water measurements near the tropopause made during the Stratosphere Troposphere Exchange Project in January 1987 at Darwin, Australia. A second class of SVC's are not immediately downstream of convection. These clouds tend to be higher, reaching potential temperatures of 390K or more. Trajectory analyses indicate that the air in these SVC's originates either in the equatorial western Pacific or along the subtropical jet. In any case, the warm temperatures the SVC air masses encounter just prior to the observation time along the back trajectory imply that the clouds cannot be residual particles from cirrus blowoff, but must form locally as the air move upward and equatorward south of Hawaii. Since all the parcels have encountered colder temperatures than those at the time of observation early in their history, subsynoptic scale temperatures colder than the analysis temperatures appear to be required to explain the formation of ice particles. In fact, the sloping shapes of the SVC's do suggest that they are gravity or inertia-gravity waves. In situ meteorological measurements made by the ER-2 within a day of the DC-8 remote lidar observations show a gravity wave structure near the equator with an estimated period of about 30 hours. This is sufficiently long to allow large particles to form and fall out (thus allowing dehydration). Other ER-2 flights south of Hawaii at other times of year show gravity and inertia-gravity waves with a poleward wavenumber component and significant (5 degrees peak to peak) temperature perturbation.

Pfister, Leonhard↗

NASA NTRS1990

Data analysis and archival

The purpose of this task is the acquisition, distribution, archival, and analysis of data collected during and in support of the Upper Atmospheric Research Program (UARP) field experiments. Meteorological and U2 data from the 1984 Stratosphere-Troposphere Exchange Project (STEP) was analyzed to determine characteristics of internal atmospheric waves. CDROM's containing data from the 1987 STEP, 1987 Airborne Antarctic Ozone Expedition (AAOE), and the 1989 Airborne Arctic Stratospheric Expedition (AASE) were produced for archival and distribution of those data sets. The AASE CDROM contains preliminary data and a final release is planned for February 1990. Comparisons of data from the NASA ER-2 Meteorological Measurement System (MMS) with radar tracking and radiosonde data show good agreement. Planning for a Meteorological Support Facility continues. We are investigating existing and proposed hardware and software to receive, manipulate, and display satellite imagery and standard meteorological analyses, forecasts, and radiosonde data.

Danielsen, Edwin F.↗

NASA NTRS1987

Three-dimensional analysis of potential vorticity associated with tropopause folds and observed variations of ozone and carbon monoxide

The usability and reliability of potential vorticity as a meteorological stratospheric tracer are evaluated. The concept of potential vorticity conservation during transport in which stratospheric and tropospheric air are mixing is tested. Aircraft data collected on April 20, 1984 in the western and southwestern U.S. are analyzed in order to derive potential vorticity data; vertical cross sections of constant-pressure data and temperature and wind speed gradients are examined. The tropopause fold observed during the April 20, 1984 aircraft flights is described. The potential vorticity, ozone mixing ratio, and carbon monoxide mixing ratio are compared; a positive correlation between potential vorticity and the ozone mixing ratio and a negative correlation between the potential vorticity and the carbon monoxide mixing ratio are detected. The data support the concepts of the conservation of potential vorticity, the entrainment and mixing of tropospheric air across the boundaries of the fold, and the applicability of potential vorticity as a stratospheric tracer.

Danielsen, Edwin F.↗

NASA NTRS1987

Correlations between ozone and carbon monoxide in the lower stratosphere, folded tropopause, and maritime troposphere

The variations of ozone and carbon monoxide with respect to the atmospheric flow structure are investigated for two aircraft flights: one in the upper troposphere/lower stratosphere over the continental United States on April 20, 1984, and the other in the marine troposphere over the eastern Pacific on April 26, 1984. The high frequency (1 Hz) and precision of the measurements allow detailed analysis of the species distribution down to length scales of the order of 1 km. Correlations between the two species are made on large, medium, and small scales of motion, and the results are interpreted. In general, the correlations are negative with some regions of positive correlation. The interpretation of these results is discussed.

Hipskind, R. Stephen↗