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Herman, J. R.

Publications and source records attributed to Herman, J. R..

At least 55 records · Page 3
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NASA NTRS1987

Infrared spectroscopy of the lower stratosphere with a balloon-borne cryogenic Fourier spectrometer

The IR limb emission of the lower stratosphere has been measured using a balloon-borne liquid nitrogen-cooled Michelson interferometer with liquid helium-cooled Si:Ga detectors. Portions of the thermal emission spectrum have been recorded between 650 and 2000/cm with an unapodized spectral resolution of 0.03/cm. This is the highest spectral resolution limb emission thus far obtained. A preliminary description is given of these data along with a discussion of the significant features. Species identified to date include CO2, O3, CFCl3, CF2Cl2, H2O, CH4, HNO3, N2O, NO2, and ClONO2. A tentative identification is made for NO, representing the first direct spectroscopic detection of NO in emission.

Kunde, Virgil G.↗
NASA NTRS1985

Photolysis rates based on Schumann-Runge band approximations and irradiance measurements

The photolysis rate (J3) for CF2Cl2(F-12) in the stratosphere has been computed for three altitudes using measured solar fluxes from a balloon borne spectrometer. The rate is compared with that obtained by computing the attenuated flux using effective cross sections appropriate for the Schumann-Runge bands (J1) (Allen and Frederick, 1982). The result shows that the error in the F-12 photolysis rate caused by using the Allen and Frederick approximation is about 10 percent (J1 less than J3) for altitudes between 32 and 38 km with solar zenith angles less than about 62 degrees. For species other than O2, this implies that the discrepancy in photolysis rates associated with the Schumann-Runge band approximations are not likely to be important. Within the Schumann-Runge band region the computed errors for F-12 photolysis are about 10.5 percent at 38.13 km and increase with decreasing altitude. If this error applies to O2 photolysis, there may be the possibility of an incorrect calculation of net odd oxygen production in photochemical models.

Herman, J. R.↗
NASA NTRS1985

Atmospheric chlorine and stratospheric ozone nonlinearities and trend detection

It is pointed out that at the present time there is no experimental means to detect the current reduction of stratospheric ozone by chlorine from fluorocarbons relative to its unperturbed amount. The reason for this situation is related to the small changes involved and several possible masking effects. As a substitute for experimental detection, there have been many stratospheric modeling efforts. The history of these efforts has been reviewed by Cicerone et al. (1983). Results obtained by Cicerone et al. imply that the successful detection of net ozone destruction by chlorine would be delayed many years from the present time. The present paper is concerned with a reinvestigation of the photochemical problem discussed by Cicerone et al. on the basis of an independent one-dimensional model reported by Herman (1979). It is concluded that by the year 2020 the total ozone decrease due to ClX should be about 3 percent (2.5 percent with increasing methane). Such a change may already pose environmental problems.

Herman, J. R.↗
NASA NTRS1985

Sun, weather, and climate

The general field of sun-weather/climate relationships, that is, apparent weather and climate responses to solar activity is introduced and theoretical and experimental suggestions for further research to identify and investigate the unknown causal mechanisms are provided. Topics of discussion include: (1) solar-related correlation factors and energy sources; (2) long-term climatic trends; (3) short-term meteorological correlations; (4) miscellaneous obscuring influences; (5) physical processes and mechanisms; (6) recapitulation of sun-weather relationships; and (7) guidelines for experiments.

Herman, J. R.↗
NASA NTRS1984

A diabatic circulation experiment in a two-dimensional photochemical model

A two-dimensional photochemical model based on diabatic circulation has been used to simulate the behavior of N2O, CFCl3(F-11) and CF2Cl2(F-12) The circulation is based on estimates of net heating from the ground to 60 km. Eddy diffusion has been reduced with respect to other model studies with Kzz = 2000 sq cm/s everywhere bove 100 mbar. Resulting tracer profiles show reasonable agreement with measured profiles in the tropics and fall off much more sharply with altitude than those produced by models using larger values of Kzz. The agreement obtained is at least as good as that obtained with adjustable, eddy diffusion parameters. The diabatic circulation treatment is more closely related to related to real physical processes and thus more easily interpreted. Diffusive mixing appears to be more important in determining the details of the tracer distributions than the basic morphology.

Guthrie, P. D.↗
NASA NTRS1983

Influence of peroxyacetyl nitrate (PAN) on odd nitrogen in the troposphere and lower stratosphere

Nonmethane hydrocarbon breakdown in the atmosphere produces aldehydes of which a fraction are transferred into peroxyacetyl nitrates (PAN) in the presence of NO and NO2. Since ethane is destroyed photochemically primarily above 1 km, PAN can be introduced into the upper troposphere and lower stratosphere without the need to be transported from the boundary layer where most hydrocarbons are destroyed and where PAN may be lost due to thermal decomposition and heterogeneous loss. Mixing ratios of ethane in the lower troposphere increase by a factor of 4-8 from equatorial to northern mid-latitudes. This difference is directly translatable into a PAN latitude gradient. At mid-latitudes the concentration of PAN below 20 km is 0.1 ppb comparable to and in some instances larger than predicted HO2NO2 mixing ratios. Like HO2NO2 and HNO3, PAN serves as a reservoir for odd nitrogen.

Aikin, A. C.↗
NASA NTRS1982

O2 absorption cross sections /187-225 nm/ from stratospheric solar flux measurements

The absorption cross sections of molecular oxygen are calculated in the wavelength range from 187 to 230 nm from solar flux measurements obtained within the stratosphere. Within the Herzberg continuum wavelength region the molecular oxygen cross sections are found to be about 30% smaller than the laboratory results of Shardanand and Rao (1977) from 200 to 210 nm and about 50% smaller than those of Hasson and Nicholls (1971). At wavelengths longer than 210 nm the cross sections agree with those of Shardanand and Rao. The effective absorption cross sections of O2 in the Schumann-Runge band region from 187 to 200 nm are calculated and compared to the empirical fit given by Allen and Frederick (1982). The calculated cross sections indicate that the transmissivity of the atmosphere may be underestimated by the use of the Allen and Frederic cross sections between 195 and 200 nm. The ozone column content between 30 and 40 km and the relative ozone cross sections are determined from the same solar flux data set.

Herman, J. R.↗
NASA NTRS1982

Atmospheric chemistry of ethane and ethylene

It is shown by a study of ethane and ethylene photochemistry that the loss of ethane is controlled by OH in the troposphere and Cl in the stratosphere. Ethane observations indicating free Cl concentrations below 30 km that are only 10% of the value predicted by the present model calculations cannot be explained by heterogeneous aerosol concentration processes, and contradict current stratospheric photochemistry. The chemical destruction of ethane and ethylene leads to the generation of such compounds as carbon monoxide and formaldehyde, and it is found that the tropospheric concentrations of the latter are enhanced by nearly a factor of three for an ethylene mixing ratio of 2 ppb.

Aikin, A. C.↗
NASA NTRS1982

The direct and scattered solar flux within the stratosphere

Solar ultraviolet flux data obtained within the atmosphere by using Fastie-Ebert double monochromators carried on a balloon-borne gondola and a rocket payload are analyzed. Both the direct and scattered components of the solar ultraviolet flux at wavelengths from 190 to 320 nm are measured at the balloon float altitude of 40 km. The nearly identical spectrometer carried on the rocket flight measures the direct solar flux from 60 to 38 km during a parachute descent. The ozone column content above 40 km and the temperature profile and ozone density below 40 km are deduced using the scattered and direct solar flux components. It is shown that the Nimbus 7 solar flux data are consistent with the present data and with the ozone absorption cross sections of Inn and Tanake (1959). The calculated and measured values of the scattered solar flux are found to agree fairly closely.

Herman, J. R.↗
NASA NTRS1981

The solar irradiance from 200 to 330 nm

The full disk solar spectrum over the wavelength range 200-330 nm is measured with a spectral resolution of 0.12 nm. The measurement is performed by using a double monochromator pointed at the sun from a high altitude parachute. Only small corrections are required to account for atmospheric absorption. Good agreement is obtained with previously reported measurements.

Mentall, J. E.↗
NASA NTRS1981

Noise and interference study for satellite lightning sensor

The use of radio frequency techniques for the detection and monitoring of terrestrial thunderstorms from space are discussed. Three major points are assessed: (1) lightning and noise source characteristics; (2) propagation effects imposed by the atmosphere and ionosphere; and (3) the electromagnetic environment in near space within which lightning RF signatures must be detected. A composite frequency spectrum of the peak of amplitude from lightning flashes is developed. Propagation effects (ionospheric cutoff, refraction, absorption, dispersion and scintillation) are considered to modify the lightning spectrum to the geosynchronous case. It is suggested that in comparing the modified spectrum with interfering noise source spectra RF lightning pulses on frequencies up to a few GHz are detectable above the natural noise environment in near space.

Herman, J. R.↗
NASA NTRS1980

Solar terrestrial relationships related to thunderstorms and BUV dark current and ozone data

Solar terrestrial interactions as they affect Nimbus 4 BUV dark current and possibly affect thunderstorm occurrence are investigated. A solar wind index is calculated for 1970 to 1971. Dark current enhancements appear to be associated in some way with solar proton events and the solar wind index, but additional investigations by GSFC are required before conclusions can be drawn. Superposed epoch analysis of an index of North American thunderstorm occurrence reveals a discernible increase in the index magnitude on days 1 and 2 following solar proton events. There appears to be little or no 27 day recurrence tendency in thunderstorm occurrence frequency and no association with vorticity area index on a day to day basis.

Herman, J. R.↗
NASA NTRS1979

Coupling processes related to the Sun-weather problem

Physical mechanisms for coupling the energetics of solar activity to meteorological responses are reviewed. Although several hypotheses have been advanced, none can be said to be sufficiently complete to be applied to weather or climate prediction. Solar activity indicators potentially useful for forecasting are identified, including sunspots, solar flares, and magnetic sector boundary crossings. Additional experiments, studies, and analyses are required before Sun-weather concepts can be utilized for predicting meteorological responses.

Goldberg, R. A.↗
NASA NTRS1979

The problem of nighttime stratospheric NO3

Detailed calculations of the behavior of the NO3 column content as a function of time after sunset show that it takes nearly 2 hours to increase from daytime values of approximately 10 to the 11th/sq cm to nighttime values of 10 to the 14th/sq cm. These results appear to be in conflict with the measured NO3-concentration rise time of 40 min after sunset obtained from the 662-nm absorption data of Noxon et al. (1978). Changes in the rate constants affecting the NO, NO2, NO3, N2O5 system, the atmospheric temperature, and the amount of NO2 are not able to bring the calculated rise time for the NO3 column content into agreement with observations.

Herman, J. R.↗
NASA NTRS1979

The response of stratospheric constituents to a solar eclipse, sunrise, and sunset

The use of measurements combined with detailed stratospheric modeling of time dependent events, to confirm chemical mechanisms and their laboratory rate constants, is examined. Careful simultaneous solutions of these equations have shown a significant daytime variation of ozone down to altitudes of about 30 km that can affect the interpretation of spectral absorption type experiments. The calculated sunset variations of NO and HO show a log linear concentration decay for limited time periods that can be readily converted into atmospheric temperatures by using known reaction rates up to about 70-km altitude. Proposed measurements of the time dependent behavior of NO and NO2 to be made by U2 aircraft at 20-km altitude are also discussed.

Herman, J. R.↗
NASA NTRS1979

The effect of energetically produced O2/+/ on the ion temperatures of the Martian thermosphere

The heating rates and ion temperatures of the Martian thermosphere resulting from the thermalization of the energetic O2(+) ions produced by the reactions of the solar ionization products CO2(+) and O(+) with neutral particles are calculated and the effects of small magnetic fields on the ion thermal balance are investigated. The energy transfer and transport of energetic ions is modelled by solving the continuity equation for the ions over a series of finite energy cells yielding the equilibrium densities as a function of energy and altitude. Particles which are able to proceed upwards without collisions are dealt with separately from the continuity equation. It is shown that the thermalization of the energetic O2(+) ions can greatly increase ion temperatures above 200 km compared to those calculated for only ambient electron heating. Current solar wind interaction models predict that small horizontal magnetic fields act to restrict the ion thermal conductivity and to increase upper altitude ion temperatures. The combined effects of these processes provide a partial agreement with measurements made by Viking 1.

Rohrbaugh, R. P.↗