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Herman, J. R.

Publications and source records attributed to Herman, J. R..

At least 19 records

High-Resolution NO2 Observations from the Airborne Compact Atmospheric Mapper: Retrieval and Validation

Nitrogen dioxide (NO2) is a short-lived atmospheric pollutant that serves as an air quality indicator and is itself a health concern. The Airborne Compact Atmospheric Mapper (ACAM) was flown on board the NASA UC-12 aircraft during the Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality Maryland field campaign in July 2011. The instrument collected hyperspectral remote sensing measurements in the 304-910 nm range, allowing daytime observations of several tropospheric pollutants, including nitrogen dioxide (NO2), at an unprecedented spatial resolution of 1.5 × 1.1 sq. km. Retrievals of slant column abundance are based on the differential optical absorption spectroscopy method. For the air mass factor computations needed to convert these retrievals to vertical column abundance, we include high-resolution information for the surface reflectivity by using bidirectional reflectance distribution function data from the Moderate Resolution Imaging Spectroradiometer. We use high-resolution simulated vertical distributions of NO2 from the Community Multiscale Air Quality and Global Modeling Initiative models to account for the temporal variation in atmospheric NO2 to retrieve middle and lower tropospheric NO2 columns (NO2 below the aircraft). We compare NO2 derived from ACAM measurements with in situ observations from NASA's P-3B research aircraft, total column observations from the ground-based Pandora spectrometers, and tropospheric column observations from the space-based Ozone Monitoring Instrument. The high-resolution ACAM measurements not only give new insights into our understanding of atmospheric composition and chemistry through observation of subsampling variability in typical satellite and model resolutions, but they also provide opportunities for testing algorithm improvements for forthcoming geostationary air quality missions.

Lamsal, L. N.

Changes in Cloud and Aerosol Cover (1980-2006) from Reflectivity Time Series Using SeaWiFS, N7-TOMS, EP-TOMS, SBUV-2, and OMI Radiance Data

The amount of solar radiation reflected back to space or reaching the Earth's surface is primarily governed by the amount of cloud cover and, to a much lesser extent, by Rayleigh scatteri ng, aerosols, and various absorbing gases (e.g., O3, NO2, H2O). A useful measure of the effect of cloud plus aerosol cover is given by the amount that the 331 run Lambert Equivalent Reflectivity (LER) ofa scene exceeds the surfuce reflectivity for snow/ice-free scenes after Rayleigh scattering has been removed. Twenty-eight years of reflectivity data are available by overlapping data from several satellites: N7 (Nimbus 7, TOMS; 331 nm) from 1979 to 1992, SBUV-2 series (Solar Backscatter Ultraviolet, NOAA; 331 nm) 1985 to 2007, EP (Earth-Probe, TOMS; 331 nm) 1997 to 2006, SW (SeaWiFS; 412 nm) 1998 to 2006, and OMI (Ozone Measuring Instrument; 331 nm) 2004-2007. Only N7 and SW have a sufficiently long data record, Sun-synchronous orbits, and are adequately calibrated for long-term reflectivity trend estimation. Reflectivity data derived from these instruments and the SBUV-2 series are compared during the overlapping years. Key issues in determining long-term reflecti vity changes that have occurred during the N7 and SW operating periods are discussed. The largest reflectivity changes in the 412 nm SW LER and 331 nm EP LER are found to occur near the equator and are associated with a large EI Nino-Southern Oscillation event. Most other changes that have occurred are regional, such as the apparent cloud decrease over northern Europe since 1998. The fractional occurrence (fraction of days) of high reflectivity values over Hudson Bay, Canada (snow/ice and clouds) appears to have decreased when comparing reflectivity data from 1980 to 1992 to 1997-2006, suggesting shorter duration of ice in Hudson Bay since 1980.

Herman, J. R.

Measurement of Atmospheric Composition from Geostationary Platforms

Satellite instruments flown since 1970 have had great success in elucidating the processes that control stratospheric ozone. In contrast, space-based data for tropospheric constituents that affect air quality and climate have only recently become available. While these datasets highlight the rapidly advancing capabilities of spacebased tropospheric sensors, they are also pointing to the limitations of sun-synchronous, low-earth orbiting (SSO/LEO) satellite platforms for making such measurements. In our talk we will highlight the science requirements for new missions and the technological and algorithmic approaches that we are developing to meet these requirements. From these studies a clear need for advanced atmospheric composition sensors has emerged that can be put on geostationary (GEO) platforms to provide 5 km horizontal resolution with 15-60 minutes repeat cycle. Such measurements have been high priority in the recently released Decadal Survey report by the US National Research Council. The need for GEO is driven not only by the science requirements to track rapidly changing pollution events but also by the need to provide altitude-resolved information about tropospheric constituents. Currently, with the exception of aerosols, it is not possible to derive profile information about lower tropospheric constituents from satellite measurements. New algorithmic approaches are being developed to obtain this information by combining UV and IR data, by monitoring the spatial and temporal structures of the constituents, and by using low-level clouds to separate boundary layer constituents from free troposphere. All these approaches require better spatial and temporal resolution than that provided by LEO sensors.

Bhartia, P. K.

Global Retrieval of Aerosol Properties over Desert and Semi-Desert Regions from SeaWiFS and MODIS

Mineral aerosols (dust) play an important role in both climate forcing and oceanic productivity throughout the entire year. Due to the relatively short lifetime (a few hours to about a week), the distributions of these airborne dust particles vary extensively in both space and time. Consequently, satellite observations are needed over both source and sink regions for continuous temporal and spatial sampling of dust properties. However, despite their importance, the high spatial resolution satellite measurements of dust near its source have been lacking. In this paper, we will demonstrate the capability of a new satellite algorithm to retrieve aerosol optical thickness and single scattering albedo over bright-reflecting surfaces such as urban areas and deserts. Such retrievals have been difficult to perform using previously available algorithms that use wavelengths from the mid-visible to the near IR because they have trouble separating the aerosol signal from the contribution due to the bright surface reflectance. The new algorithm, called Deep Blue, utilizes blue-wavelength measurements from instruments such as SeaWiFS and MODIS to infer the properties of aerosols, sinre the stirfare reflectance nver land in the blue part of the spectrum is much lower than for longer wavelength channels. We have validated the satellite retrieved aerosol optical thickness with data from AERONET sunphotometers over desert and semi-desert regions. The comparisons show reasonable agreements between these two. These new satellite products will allow scientists to determine quantitatively the aerosol properties near sources using high spatial resolution measurements from SeaWiFS and MODIS-like instruments.

Hsu, Nai-Yung

Ocean Color and Evidence of Chlorophyll Signature in the TOMS Minimum Reflectivity Data

Analysis of the TOMS minimum reflectivity data for 380 nm channel (R380) show regions of high reflectivity values (approx. 7 to 8%) over Sargasso Sea in the Northern Atlantic, anti-cyclonic region in the Southern Atlantic, and a large part of the ocean in the Southern Pacific, and low values (5 approx. 6 %) over the rest of the open ocean. Through radiative transfer simulations we show that these features are highly correlated with the distribution of chlorophyll in the ocean. Theoretical minimum reflectivity values derived with the help of CZCS chlorophyll concentration data as input into a vector ocean-atmosphere radiative transfer code developed by Ahmad and Fraser show very good agreement with TOMS minimum reflectivity data for the winter season of year 1980. For the summer season of year 1980, good qualitative agreement is observed in the equatorial and northern hemisphere but not as good in the southern hemisphere. Also, for cloud-free conditions, we find a very strong correlation between R340 minus R380 values and the chlorophyll concentration in the ocean. Results on the possible effects of absorbing and non-absorbing aerosols on the TOMS minimum reflectivity will also be presented. The results also imply that ocean color will affect the aerosol retrieval over oceans unless corrected.

Ahmad, Z.

Changes in Earth 360 380 nm Reflectivity: 1980 2000

The Total Ozone Mapping Spectrometer (TOMS) reflectivity time series 1980 to 1992 and 1997 to 2000 have been combined to estimate change that have occurred over a 21 year period. The relative calibration of the two TOMS (Nimbus-7, N7 and Earth-Probe, EP) has been adjusted using the measured minimum reflectivity over mid-latitude ocean and land locations (50o). The result is that the N7 reflectivity has been decreased by 0.02 to match the better-calibrated Earth-Probe/TOMS. Most of the local trend features seen in the N7 time series (1980 to 1992) have been continued in the combined time series, but the overall zonal average and global trends have changed. The correlation of cloud cover with solar activity (measured by the 10.7 cm solar radiation) that was present during the Nimbus-7 period (1980 to 1992) is no longer evident for the period 1980 to 2000. The UV reflectivity data are compared with changes in the Advanced Very High Resolution Radiometer (AVHRR) Outgoing Long-wavelength Radiation (OLR) and show an expected anti-correlation with cloud-cover changes over the same period for many, but not all, features. The key results include a continuing decrease in cloud cover over Europe and North America and an increase in reflectivity near climatology should be reduced by 0.02. The TOMS reflectivity time series 1980 to 1992 and 1997 to 2000 have been Antarctica. This also means that the previously published N7 UV surface reflectivity.

Herman, J. R.

Changes in Earth 360 380 nm Reflectivity: 1980-2000

The TOMS (Total Ozone Mapping Spectrometer) reflectively time series 1980 to 1992 and 1997 to 2000 have been combined to estimate change that have occurred over a 21 year period. The relative calibration of the two TOMS (Nimbus-7, N7 and Earth-Probe, EP) has been validated using the measured reflectivity R over Hudson Bay, Canada and found to be within 1 RU (R=0.01). Some of the local trend features seen in the N7 time series (1980 to 1992) have been continued in the combined time series, but the overall zonal average and global trends have changed. The UV (ultraviolet) reflectivity data are compared with changes in the AVHRR outgoing long-wavelength radiation (OLR) and show an expected anti-correlation with cloud-cover changes over the same period for many, but not all, features. The key results include a continuing decrease in cloud cover over Europe and North America and an increase in reflectivity near Antarctica.

Herman, J. R.

Changes in Earth 360 to 380 nm Reflectivity: 1980 to 2000

The TOMS reflectivity time series 1980 to 1992 and 1997 to 2000 have been combined to estimate change that have occurred over a 21 year period. The relative calibration of the two TOMS (Nimbus-7, N7 and Earth-Probe, EP) has been adjusted using the measured minimum reflectivity over mid-latitude ocean and land locations (50 deg.). The result is that the N7 reflectivity has been decreased by 0.02 to match the better-calibrated Earth-Probe/TOMS. Most of the local trend features seen in the N7 time series (1980 to 1992) have been continued in the combined time series, but the overall zonal average and global trends have changed. The correlation of cloud cover with solar activity (measured by the 10.7 cm solar radiation) that was present during the Nimbus-7 period (1980 to 1992) is no longer evident for the period 1980 to 2000. The UV reflectivity data are compared with changes in the AVHRR outgoing long-wavelength radiation (OLR) and show an expected anti-correlation with cloud-cover changes over the same period for many, but not all, features. The key results include a continuing decrease in cloud cover over Europe and North America and an increase in reflectivity near Antarctica. This also means that the previously published N7 UV surface reflectivity climatology should be reduced by 0.02.

Herman, J. R.

Long-Term Variability of Airborne Asian Dust Observed from TOMS

Recent studies suggest that airborne Asian dust may not only play an important role in the regional radiation budget, but also influence the air quality over North America through long-range transport. In this paper, we use satellite data to investigate the long-term variability of airborne Asian dust as well as the daily variation of the dust aerosol distribution. By combining the Total Ozone Mapping Spectrometer (TOMS) aerosol index with National Centers for Environmental Prediction (NCEP) wind data, our analysis shows a strong correlation between the generation of dust storms in the region and the passage of springtime weather fronts. This is consistent with earlier studies performed by other researchers. According to both the Nimbus-7 and Earth-Probe TOMS data the Takla Makan desert, the Gobi desert, and the and region of Inner Mongolia are major sources of the eastward-flowing airborne Asian dust. Heavily populated areas in eastern China (e.g., Beijing) are often on the primary path of the dust storms originating in these desert regions. The increasing desertification north of the Beijing region has served to exacerbate problems stemming from these storms. The time series derived from 20 years of TOMS aerosol index data shows the first significant satellite evidence of the atmospheric effect of increasing desertification, indicating that the amount of dust blown eastward has increased strongly during the past few years including the year 2000.

Herman, J. R.

Tropical Tropospheric Ozone and Smoke Interactions: Satellite Observations During the 1997 Indonesian Fires

Biomass burning generates hydrocarbons, nitrogen oxides and carbon monoxide that lead to tropospheric ozone pollution. Other combustion products form soot and various aerosol particles that make up smoke. Since early 1997 smoke and tropospheric ozone have been monitored in real-time from TOMS (Total Ozone Mapping Spectrometer) at toms.gsfc.nasa.gov (smoke aerosol) and metosrv2.umd.edu/-tropo (tropospheric ozone). The striking increase in smoke and tropospheric ozone observed during the 1997 Indonesian fires was the first extreme episode observed. During the August-November period, plumes of excess ozone and smoke coincided at times but were decoupled at other times, a phenomenon followed with trajectories. Thus, trans-boundary evolution of smoke and ozone differed greatly. The second discovery of the 1997 TOMS record was a dynamical interaction of ozone with the strong El Nino Southern Oscillation (ENSO) and Indian Ocean Dipole (IOD) that led to a jump in tropospheric ozone in March 1997 over the entire Indian Ocean, well ahead of the intense burning period. A climatology of smoke and tropospheric ozone from a 1980's TOMS instrument shows offsets in the timing of these pollutants - further evidence that factors other than biomass burning exert a strong influence on tropical tropospheric ozone.

Thompson, A. M.

Interferometric Characterization of the Earth's Atmosphere from Lagrange Point 2

Part of the NASA plans for future Earth-Science missions calls for observations using novel vantage points that can produce science products otherwise unobtainable. Observations of the Earth from the Lagrange-2 point, L-2, (1.5 million kilometers behind the Earth on the Earth-Sun line) affords a unique vantage point for atmospheric science. Special observation of the Earth's atmosphere using solar occultation techniques in the near infrared (1 to 4 microns) provides one of the most accurate method of passively sensing altitude profiles of the major species (CO2, O3, O2, CH4, H2O, N2O). In addition to observation of the Earth's atmosphere, it will be possible to observe a portion of the solar disk at moderate spatial resolution without interference from the Earth.

Herman, J. R.

Urban and Rural Ozone Pollution Over Lusaka (Zambia, 15.5S, 25E) During SAFARI-2000 (September 2000)

In early September, throughout south central Africa, seasonal clearing of dry vegetation and the production of charcoal for cooking leads to intense smoke haze and ozone formation. Ozone soundings made over Lusaka during a six-day period in early September 2000 recorded layers of high ozone (greater than 125 ppbv at 5 km) during two stagnant periods, interspersed by a frontal passage that reduced boundary layer ozone by 30 percent. Smoke aerosol column variations aloft and total ozone were monitored by a sun photometer. During the 6-day measurement period, surface ozone concentrations ranged from 50-95 ppbv and integrated tropospheric ozone from the soundings was 39- 54 Dobson Units (note 1.3 km elevation at the launch site). High ozone concentrations above the mixed and inversion layers were advected from rural burning regions in western Zambia where SAFARI aircraft and ground-based instruments observed intense biomass fires and elevated aerosol and trace gas amounts. TOMS tropospheric ozone and smoke aerosols products show the distribution of biomass burning and associated pollution throughout southern Africa in September 2000. Animations of satellite images and trajectories confirm pollutant recirculation over south central African fires, exit of ozone from Mozambique and Tanzania to the Indian Ocean and the characteristic buildup of tropospheric ozone over the Atlantic from western African outflow.

Thompson, Anne M.

UV 380 nm Reflectivity of the Earth's Surface

The 380 nm radiance measurements of TOMS (Total Ozone Mapping Spectrometer) have been converted into a global data set of daily (1979 to 1992) Lambert equivalent reflectivities R of the Earth's surface and boundary layer (clouds, aerosols, surface haze, and snow/ice). Since UV surface reflectivity is between 2 and 8% for both land and water during all seasons of the year (except for ice and snow cover), reflectivities larger than the surface value indicates the presence of clouds, haze, or aerosols in the satellite field of view. Statistical analysis of 14 years of daily data show that most snow/ice-free regions of the Earth have their largest fraction of days each year when the reflectivity is low (R less than 10%). The 380 nm reflectivity data shows that the true surface reflectivity is 2 to 3% lower than the most frequently occurring reflectivity value for each TOMS scene. The most likely cause of this could be a combination of frequently occurring boundary-layer water or aerosol haze. For most regions, the observation of extremely clear conditions needed to estimate the surface reflectivity from space is a comparatively rare occurrence. Certain areas (e.g., Australia, southern Africa, portions of northern Africa) are cloud-free more than 80% of the year, which exposes these regions to larger amounts of UV radiation than at comparable latitudes in the Northern Hemisphere. Regions over rain-forests, jungle areas, Europe and Russia, the bands surrounding the Arctic and Antarctic regions, and many ocean areas have significant cloud cover (R greater than 15%) more than half of each year. In the low to middle latitudes, the areas with the heaviest cloud cover (highest reflectivity for most of the year) are the forest areas of northern South America, southern Central America, the jungle areas of equatorial Africa, and high mountain regions such as the Himalayas or the Andes. The TOMS reflectivity data show the presence of large nearly clear ocean areas and the effects of the major ocean currents on cloud production.

Herman, J. R.

Actinic Flux Calculations: A Model Sensitivity Study

calculate direct and diffuse surface irradiance and actinic flux (downwelling (2p) and total (4p)) for the reference model. Sensitivity analysis has shown that the accuracy of the radiative transfer flux calculations for a unit ETS (i.e. atmospheric transmittance) together with a numerical interpolation technique for the constituents' vertical profiles is better than 1% for SZA less than 70(sub o) and wavelengths longer than 310 nm. The differences increase for shorter wavelengths and larger SZA, due to the differences in pseudo-spherical correction techniques and vertical discretetization among the codes. Our sensitivity study includes variation of ozone cross-sections, ETS spectra and the effects of wavelength shifts between vacuum and air scales. We also investigate the effects of aerosols on the spectral flux components in the UV and visible spectral regions. The "aerosol correction factors" (ACFs) were calculated at discrete wavelengths and different SZAs for each flux component (direct, diffuse, reflected) and prescribed IPMMI aerosol parameters. Finally, the sensitivity study was extended to calculation of selected photolysis rates coefficients.

Krotkov, Nickolay A.

A Long-term Record of Saharan Dust Aerosol Properties from TOMS Observations: Optical Depth and Single Scattering Albedo

The interaction between the strong Rayleigh scattering in the near UV spectral region (330-380 nm) and the processes of aerosol absorption and scattering, produce a clear spectral signal in the upwelling radiance at the top of the atmosphere. This interaction is the basis of the TOMS (Total Ozone Mapping Spectrometer) aerosol retrieval technique that can be used for their characterization and to differentiate non-absorbing sulfates from strongly UV-absorbing aerosols such as mineral dust. For absorbing aerosols, the characterization is in terms of the optical depth and single scattering albedo with assumptions about the aerosol plume height. The results for non-absorbing aerosols are not dependent on plume height. Although iron compounds represent only between 5% to 8% of desert dust aerosol mass, hematite (Fe2O3) accounts for most of the near UV absorption. Because of the large ultraviolet absorption characteristic of hematite, the near UV method of aerosol sensing is especially suited for the detection and characterization of desert dust aerosols. Using the combined record of near UV measurements by the Nimbus7 (1978-1992) and Earth Probe (1996-present) TOMS instruments, a global longterm climatology of near UV optical depth and single scattering albedo has been produced. The multi-year long record of mineral aerosol properties over the area of influence of the Saharan desert, will be discussed.

Torres, Omar

Global and Seasonal Aerosol Optical Depths Derived From Ultraviolet Observations by Satellites (TOMS)

It has been shown that absorbing aerosols (dust, smoke, volcanic ash) can be detected in the ultraviolet wavelengths (331 nm to 380 nm) from satellite observations (TOMS, Total Ozone Mapping Spectrometer) over both land and water. The theoretical basis for these observations and their conversions to optical depths is discussed in terms of an aerosol index AI or N-value residue (assigned positive for absorbing aerosols). The theoretical considerations show that negative values of the AI frequently represent the presence of non-absorbing aerosols (NA) in the troposphere (mostly pollution in the form of sulfates, hydrocarbons, etc., and some natural sulfate aerosols) with particle sizes near 0.1 to 0.2 microns or less. The detection of small-particle non-absorbing aerosols from the measured backscattered radiances is based on the observed wavelength dependence from Mie scattering after the background Rayleigh scattering is subtracted. The Mie scattering from larger particles, 1 micron or more (e.g., cloud water droplets) has too small a wavelength dependence to be detected by this method. In regions that are mostly cloud free, aerosols of all sizes can be seen in the single channel 380 nm or 360 nm radiance data. The most prominent Al feature observed is the strong asymmetry in aerosol amount between the Northern and Southern Hemispheres, with the large majority of NA occurring above 20degN latitude. The maximum values of non-absorbing aerosols are observed over the eastern U.S. and most of western Europe corresponding to the areas of highest industrial pollution. Annual cycles in the amount of NA are observed over Europe and North America with maxima occurring in the summer corresponding to times of minimum wind transport. Similarly, the maxima in the winter over the Atlantic Ocean occurs because of wind borne transport from the land. Most regions of the world have the maximum amount of non-absorbing aerosol in the December to January period except for the eastern North America and Europe. Comparisons of the estimated TOMS aerosol optical depths show good agreement in magnitude and seasonal dependence with sun-photometer optical depths obtained at Goddard Space Flight Center (39degN 76.88degW) in the U.S. and in Lille (50.63degN 3.07degE) in France. The study of these aerosols is important for detecting the sources of industrial pollution and its redistribution by winds on a global basis, as well as its effect on reducing the UV irradiance at the Earth's surface.

Herman, J. R.

Current Status of Aerosol Retrievals from TOMS

Properties of atmospheric aerosols over all land and water surfaces are retrieved from TOMS measurements of backscattered radiances. The TOMS technique, uses observations at two wavelengths. In the near ultraviolet (330-380 nm) range, where the effects of gaseous absorption are negligible. The retrieved properties are optical depth and a measure of aerosol absorptivity, generally expressed as single scattering albedo. The main sources of error of the TOMS aerosol products are sub-pixel cloud contamination and uncertainty on the height above the surface of UV-absorbing aerosol layers. The first error source is related to the large footprint (50 x 50 km at nadir) of the sensor, and the lack of detection capability of sub-pixel size clouds. The uncertainty associated with the height of the absorbing aerosol layers, on the other hand, is related to the pressure dependence of the molecular scattering process, which is the basis of the near-UV method of absorbing aerosol detection. The detection of non-absorbing aerosols is not sensitive to aerosol layer height. We will report on the ongoing work to overcome both of these difficulties. Coincident measurements of high spatial resolution thermal infrared radiances are used to address the cloud contamination issue. Mostly clear scenes for aerosol retrieval are selected by examining the spatial homogeneity of the IR radiance measurements within a TOMS pixel. The approach to reduce the uncertainty associated with the height of the aerosol layer by making use of a chemical transport model will also be discussed.

Torres, O.

Interannual Variability of Ozone and Ultraviolet Exposure

Annual zonal averages of ozone amounts from Nimbus-7/TOMS (Total Ozone Mapping Spectrometer) (1979 to 1992) are used to estimate the interannual variability of ozone and UVB (290 - 315 nm) irradiance between plus or minus 60 deg. latitude. Clear-sky interannual ozone and UVB changes are mainly caused by the Quasi Biennial Oscillation (QBO) of stratospheric winds, and can amount to plus or minus 15% at 300 nm and plus or minus 5% at 310 nm (or erythemal irradiance) at the equator and at middle latitudes. Near the equator, the interannual variability of ozone amounts and UV irradiance caused by the combination of the 2.3 year QBO and annual cycles implies that there is about a 5-year periodicity in UVB variability. At higher latitudes, the appearance of the interannual UVB maximum is predicted by the QBO, but without the regular periodicity. The 5-year periodic QBO effects on UVB irradiance are larger than the currently evaluated long-term changes caused by the decrease in ozone amounts.

Herman, J. R.