Use of fiber-like materials to augment cycle life of thick, thermoprotective-seal coatings
(Previously announced in STAR as N82-32633)
Engineering topics
Publications and source records attributed to Hendricks, R. C..
(Previously announced in STAR as N82-32633)
An analysis has been developed which relates the effects of inelastic behavior of Y2O3 stabilized ZrO2 (YSZ) materials. The results show these materials to be sensitive to small changes in temperature and are supported by measurements of inelastic behavior in disk and bar specimens at temperatures as low as 1010 C (1850 F). At higher thermomechanical loads, the test specimens can deform to strains greater than 1 percent and for bar specimens, with sufficient strength, to remain bonded to the metallic substrate.
Some experimental and analytical studies of plasma sprayed ZrO2-Y2O3 thick seal thermoprotective materials over NiCrAlY bond coats with testing to 1040 deg C in a Mach 0.3 burner flame are reviewed. These results indicate the need for material to have both compliance and sufficient strength to function successfully as a thick thermoprotective seal material. Fibrous materials may satisfy many of these requirements. A preliminary analysis simulating the simplified behavior of a 25 mm cylindrical SiO2-fiber material indicated significant radial temperature gradients, a relatively cool interface and generally acceptable stresses over the initial portion of the thermal cycle. Subsequent testing of these fiberlike materials in a Mach 0.3 Jet A/air burner flame confirmed these results.
Chocked flow rate and pressure profile data were taken and studied for configurations consisting of four axially aligned, sequential orifice inlets of 0.5 length diameter ratio with separation distances of 0.66 and 32 diameters. A flow coefficient - reduced temperature plot represents the flow rate data for the two cases. At a separation distance of 32 diameters the pressure profiles dropped sharply at the entrance and partially recovered within each orifice - the exception being at low temperatures, where fluid jetting through the last orifice occurred. At a separation distance of 0.66 diameter fluid jetting was prevalent at the lower inlet temperatures. These results are in qualitative agreement with data for four axially aligned, sequential Borda inlets and for tubes with single sharp edge orifice or Borda inlets to L/D's of 105 and with a water flow visualization study.
An analysis of thermal cycle life data for four sets of eight thermal barrier coated specimens representing arc currents (plasma gun power) of 525, 600, 800, or 950 amps is presented. The ZrO2-8Y2O3/NiCrAlY plasma spray coated Rene 41 rods were thermal cycled to 1040 C in a Mach 0.3-Jet A/air burner flame. The experimental results indicate the existance of a minimum or threshold power level which coating life expectancy is less than 500 cycles. Above the threshold power level, coating life expectancy more than doubles and increases with arc current.
Flow rates and pressure thermal profiles for two phase choked flows of fluid nitrogen were studied theoretically and experimentally in a four sequential orifice configuration. Both theory and experimental evidence demonstrate that heat addition in the first spacer-reservoir adjacent to the inlet orifice is most effective in reducing the flow rate and that heat addition in the last spacer-reservoir is least effective. The flows are choked at the exit orifice for large spacings and at the inlet orifice for small spacings. The moderate addition of heat available for this experiment did not materially alter this result for large spacings; however, significant heat addition for the small spacings tended to shift the choke point to the exit orifice. Nitrogen is used as the working fluid over a range of states from liquid to gas with a reduced inlet stagnation pressure range to P sub r, o = 2.
Some conditions under which boiling and two-phase flow can occur in or near a wet sliding contact are determined and illustrated. The experimental apparatus consisted of a tool pressed against an instrumented slider plate and motion picture sequences at 4000 frames/sec. The temperature and photographic data demonstrated surface conditions of boiling, drying, trapped gas evolution (solutions), and volatility of fluid mixture components. The theoretical modeling and analysis are in reasonable agreement with experimental data.
Experimental pressure profiles and leak rate characteristics for three shaft seal prototype model configurations proposed for the space shuttle turbopump were assessed in the concentric and fully eccentric, to point of rub, positions without the effects of rotation. The parallel-cylindrical configuration has moderate to good stiffness with a higher leak rate. It represents a simple concept, but for practical reasons and possible increases in stability, all such seals should be conical-convergent. The three-stepdown-sequential, parallel-cylindrical seal is converging and represents good to possible high stiffness when fluid separation occurs, with a significant decrease in leak rate. Such seals can be very effective. The three-stepdown-sequential labyrinth seal of 33-teeth (i.e., 12-11-10 teeth from inlet to exit) provides excellent leak control but usually has very poor stiffness, depending on cavity design. The seal is complex and not recommended for dynamic control.
Some conditions under which boiling and two-phase flow can occur in or near a wet sliding contact are determined and illustrated. The experimental apparatus consisted of a tool pressed against an instrumented slider plate and motion picture sequences at 4000 frames/sec. The temperature and photographic data demonstated surface conditions of boiling, dry, trapped gas evolution (solutions), and volatility of fluid mixture components. The theoretical modeling and analysi are in reasonable agreement with experimental data. Previously announced in STAR as N82-28574
Calculated values of the acoustic velocity are presented for single-component and two-component, two-phase mixtures. Three different analytic models were employed. For purposes of comparison, all three models were used in making acoustic-velocity calculations for single-component, equivalent bubbly two-phase mixtures (with insoluble gas) of oxygen and helium and hydrogen and helium. In all cases the results are shown graphically so that the effects of variation in quality or void fraction, temperature and pressure are illustrated.
Choked flow rate and pressure profile data were taken on sequential axially aligned inlets of the orifice and Borda type. The configuration consisted of from two to four inlets spaced at two nominal separation distances of 0.7 and 30 diameters. At the nominal 30 diameter spacing, the reduced flow rate follows a simple empirical relation based on the reduced flow rate for a single inlet. At the nominal 0.7 diameter spacing, fluid jetting was prevalent at low temperatures and flow rates were the same as for a single inlet. Previously announced in STAR as N81-30391
The effects of inelastic behavior of yttria-stabilized zirconia (YSZ) materials were analyzed. The results show these materials to be sensitive to small changes in temperature and are supported by measurements of inelastic behavior in disc and bar specimens at temperatures as low as 1010 C (1850 F). At higher thermomechanical loadings, the test specimens can deform to strains above 1 percent.
Choked flow rate and pressure profile data were taken and studied for two axially aligned sequential configurations consisting of: (1) Four Borda type inlets of 1.9 1/D with two separation distances of 0.8 and 30 diameters. (2) Four orifice type inlets of 0.5 1/D with two separation distances of 0.66 and 32 diameters. A flow-coefficient reduced-temperature plot can be used to represent the flow rate data for each geometry. At the larger separation distances, the pressure profiles dropped sharply at the entrance and partially recovered within each of the Borda and orifice inlet configurations; the exception being the last inlet where at low entrance temperatures, fluid jetting could occur. For the smaller spacings fluid jetting was prevalent throughout each of the inlet configurations at lower inlet temperatures. These results are in qualitative agreement with data of tubes with single Borda or sharp-edge orifice type inlets to 105 1/D and water flow visualization studies.
The reported study had the purpose to examine variations in cyclic life and in adhesive/cohesive coating strength. Possible effects of heating rate, stress reversal, temperature level, and ceramic deposition methods on coating life were also investigated. Life cycle data for 22 thermal barrier coated rods were examined and found to be statistically modeled by normal or log-normal distributions. The sample mean was 1330 cycles with a standard deviation of 520 cycles. Adhesive/cohesive pulloff strength data for 20 thermal barrier coated flat head piston specimens were taken. The average pulloff stress was 9 MPa with a standard deviation of 4.2 MPa. It was found that variations in heating rate can produce significant variations in the life cycle data.
Thermal barrier coatings applied to the heated side of engine components such as seals, combustor, and blades of a gas turbine offer a potential increase in efficiency through the use of higher gas temperatures or less cooling air or benefits arising from extended component life by reducing component metal temperatures. The considered investigation has the objective to show that while a thermal barrier coated (TBC) specimen can be brought to a fixed temperature using various fuel-air ratio (F/A) values, lower calculated stresses are associated with lower (F/A) values. This implies that control of (F/A) values (i.e., rates of heat input) during the starting transient and to a lesser extent during shutdown and operation, offers a potential method of improving TBC lifetime through thermal cycle management.
Choked flow rate and pressure profile data were obtained and studied for two axially aligned sequential configurations consisting of four Borda type inlets of 1.9 1/D with two separation distances of 0.8 and 30 diameters and four orifice type inlets of 0.5 1/D with two separation distances of 0.66 and 32 diameters. Data were obtained using fluid nitrogen over the reduced inlet temperature and pressure range 0.68 T/T sub c gas and P/P sub c to 2. A flow coefficient reduced temperature plot can be used to represent the flow rate data for each geometry. At the larger separation distances, the pressure profiles dropped sharply at the entrance and partially recovered within each of the Borda and orifice inlet configurations; the exception being the last inlet where at low entrance temperatures, fluid jetting could occur. For the smaller spacings fluid jetting was prevalent throughout each of the inlet configurations at lower inlet temperatures. These results are in qualitative agreement with data of tubes with single Borda or sharp edge orifice type inlets to 105 1/D and water flow visualization studies.
Measurements were made of the rate of increase in temperature of a ZrO2-8Y2O3 thermal barrier coated (TBC) specimen for various values of fuel/air (F/A) ratios when the specimen is exposed to a 0.3 Mach burner flame. For rod specimens in a carousel, the heating rates increased with (F/A) ratio and were higher at the inward facing surface for a given (F/A). Plate specimens were more sensitive to burner variations. Calculated results are given for the radial stress in the coated rod specimens for variations in (F/A) ratios from 0.04 to 0.065. Over this range, the radial stress varies from 4.3 to 5.3 MPa. The results indicate that controlling the heating rate of a TBC by controlling the (F/A) ratio offers a potential method to prolong TBC cyclic life; uncontrolled (F/A) ratios will produce scatter in experimental results. Geometric arrangement can have an equivalent effect, but is usually fixed by design.
An analysis of thermal cycle life data for 22 thermal barrier coated (TBC) specimens was conducted. The Zr02-8Y203/NiCrAlY plasma spray coated Rene 41 rods were tested in a Mach 0.3 Jet A/air burner flame. All specimens were subjected to the same coating and subsequent test procedures in an effort to control three parametric groups; material properties, geometry and heat flux. Statistically, the data sample space had a mean of 1330 cycles with a standard deviation of 520 cycles. The data were described by normal or log-normal distributions, but other models could also apply; the sample size must be increased to clearly delineate a statistical failure model. The statistical methods were also applied to adhesive/cohesive strength data for 20 TBC discs of the same composition, with similar results. The sample space had a mean of 9 MPa with a standard deviation of 4.2 MPa.