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Harpold, Dan

Publications and source records attributed to Harpold, Dan.

Abundance and Isotopic Composition of Gases in the Martian Atmosphere: First Results from the Mars Curiosity Rover

Repeated measurements of the composition of the Mars atmosphere from Curiosity Rover yield a (40)Ar/N2 ratio 1.7 times greater and the (40)Ar/(36)Ar ratio 1.6 times smaller than the Viking Lander values in 1976. The unexpected change in (40)Ar/N2 ratio probably results from different instrument characteristics although we cannot yet rule out some unknown atmospheric process. The new (40)Ar/(36)Ar ratio is more aligned with Martian meteoritic values. Besides Ar and N2 the Sample Analysis at Mars instrument suite on the Curiosity Rover has measured the other principal components of the atmosphere and the isotopes. The resulting volume mixing ratios are: CO2 0.960(+/- 0.007); (40)Ar 0.0193(+/- 0.0001); N2 0.0189(+/- 0.0003); O2 1.45(+/- 0.09) x 10(exp -3); and CO 5.45(+/- 3.62) x 10(exp 4); and the isotopes (40)Ar/(36)Ar 1.9(+/- 0.3) x 10(exp 3), and delta (13)C and delta (18)O from CO2 that are both several tens of per mil more positive than the terrestrial averages. Heavy isotope enrichments support the hypothesis of large atmospheric loss. Moreover, the data are consistent with values measured in Martian meteorites, providing additional strong support for a Martian origin for these rocks.

Results from Curiosity↗

Silicon Microleaks for Inlets of Mass Spectrometers

Microleaks for inlets of mass spectrometers used to analyze atmospheric gases can be fabricated in silicon wafers by means of photolithography, etching, and other techniques that are commonly used in the manufacture of integrated circuits and microelectromechanical systems. The microleaks serve to limit the flows of the gases into the mass-spectrometer vacuums to specified very small flow rates consistent with the capacities of the spectrometer vacuum pumps. There is a need to be able to precisely tailor the dimensions of each microleak so as to tailor its conductance to a precise low value. (As used here, "conductance" signifies the ratio between the rate of flow in the leak and the pressure drop from the upstream to the downstream end of the leak.) To date, microleaks have been made, variously, of crimped metal tubes, pulled glass tubes, or frits. Crimped-metal and pulled-glass-tube microleaks cannot readily be fabricated repeatably to precise dimensions and are susceptible to clogging with droplets or particles. Frits tend to be differentially chemically reactive with various gas constituents and, hence, to distort the gas mixtures to be analyzed. The present approach involving microfabrication in silicon largely overcomes the disadvantages of the prior approaches.

Harpold, Dan↗

Mass Spectrometers in Deep Space Missions

Mass spectrometers have been included in the payloads of several deep space missions over the past three decades. Our laboratory has designed and developed mass spectrometers for the Galileo Probe into the atmosphere of Jupiter, the Pioneer Venus Orbiter, the Cassini Orbiter Mission to Saturn, the Cassini/Huygens Probe Mission to Saturn's moon Titan, the Nozomi Mission to Mars, and most recently the CONTOUR comet nucleus flyby mission. Each mission has required attention to miniaturization, autonomous sampling, and consideration of the special hazards and measurement requirements of the target environment. Development ongoing in our laboratory includes further miniaturization, improved performance in the areas of sensitivity and precision for the important isotope measurements, and adaptation for the unusual environments to be encountered in locations such as the surface or subsurface of Europa or Mars. Various aspects of both the technical implementation of these delivered and planned experiments and the science drivers will be described.

Mahaffy, Paul↗

An Overview of the Comet Nucleus TOUR Discovery Mission and a Description of Neutral Gas and Ion Measurements Planned

The CONTOUR (Comet Nucleus TOUR) Mission led by its Principal Investigator Professor Joseph Veverka of Cornell is presently under development at the Johns Hopkins Applied Physics Laboratory for launch in July of 2002 with a flyby of Comet Encke scheduled for November 3, 2003 at a solar distance of 1.07 au. A robust Whipple dust shield is designed to allow a close nucleus approach distance (less than 150 km). The 2nd nominal CONTOUR target is Comet Schwassmann-Wachmann 3, although the spacecraft can alternately be directed to a new comet if such an interesting target is discovered. CONTOUR contains 4 instruments: an imaging spectrometer (CRISP) developed at APL that will obtain both high resolution nucleus images through 8 filters and IR spectra (800 to 2550 nm) of the nucleus, a narrow field of view forward imager (CFI) to locate the target days before the encounter, a dust composition time of flight mass spectrometer (CIDA) provided by Dr. J. Kissel and von Hoemer & Sulger, GmbH, and a mass spectrometer (NGIMS) provided by Goddard Space Flight Center to measure neutral gas and ambient ions. Laboratory calibration of the NGIMS has now been completed. NGIMS also includes an in-flight calibration system that we plan to exercise before and after each comet encounter. We will provide an overview of the CONTOUR Mission and discuss more specifically the NGIMS measurement goals for this mission.

Mahaffy, Paul↗

Pump Effects in Planetary Mass Spectrometers

Mass spectrometers provide a useful tool in solar system exploration since fundamental questions of Solar System formation and evolution may be constrained by models based on the chemical and isotopic data provided by these instruments. For example, comparison of such data between the atmospheres of the terrestrial planets enables an understanding of mechanisms of atmospheric loss to space and production sources such as from planetary outgassing and from infall from objects such as comets. Over the past 25 years, mass spectrometers have been sent to Mars, Venus, Comet Halley, and Jupiter and are presently in transit to the Saturnian system to sample the atmosphere of Saturn's moon Titan. The quality of data derived from a very small, lightweight, and rugged instrument is constrained not only by the mass analyzer itself, but also by the performance of its gas sampling and pumping systems. A comparison of several planetary mass spectrometer experiments is provided with a focus on the demands placed on the gas processing and pumping systems. For example, the figure below is a mass spectrum from deep in the atmosphere of Jupiter obtained from a quadrupole mass spectrometer developed in the early 1980's for the Galileo Probe (Niemann et al., Space Sci. Rev., 60, 111-142 (1992)). Measurements of Jovian noble gases and other species with this system is described.

Mahaffy, Paul↗