Engineering Papers⌕ Search

Engineering topics

Green, B. D.

Publications and source records attributed to Green, B. D..

Space Active Modular Materials Experiments (SAMMES): Low Earth Orbital mission aboard the Space Test Experiments STEP-3 platform

The requirement of satellite systems to survive in the space environment for 5 to 10 years to achieve greater cost effectiveness is discussed. Characterization of the orbital space environment and its effects on spacecraft systems have received considerable research attention. Instrumentation for long term measurement of key physical parameters characterizing the low Earth orbit (LEO) environment and its effects on degradation of spacecraft materials and solar arrays is reported. These measurements enable active, real time monitoring of the health of spacecraft and payload systems. SAMMES is designed to be autonomous, compact, low power, and lightweight.

Joshi, P.↗

Infrared spectral measurement of Space Shuttle glow

The USAF and NASA successfully conducted infrared spectral measurements of the Space Shuttle glow during STS-39. Preliminary analysis indicates that NO, NO(+), OH, and CO produce infrared glow during quiescent orbiter conditions. During orbiter thruster firings the glow intensities in the infrared are enhanced by factors of 10X and 100X with significant changes in spectral distribution. These measurements were obtained with the Spacecraft Kinetic Infrared Test payload which included a cryogenic infrared circular variable filter infrared spectrometer covering the 0.7 to 5.4 microns wavelength region. Approximately 14,000 spectra of Shuttle glow, airglow, aurora, and the orbiter environment were obtained during the eight day mission. The STS-39 Space Shuttle Discovery was launched from the NASA Kennedy Space Center on 28 April, 1991 into a 57-deg inclination circular orbit at an altitude of 260 km.

Ahmadjian, Mark↗

Solar cell arcing: The role of outgassing and contamination

The effect of outgassing, venting, and thruster firing events on spacecraft system performance has been a long standing issue. Recent laboratory measurements on negatively biased high voltage solar cells at Physical Sciences Inc. (PSI) suggest that some currently designed and certainly future space power systems must address/re-evaluate this issue. Our observations show that exposing these cells to moderate levels (10 exp -3 torr-min) of H2O vapor enhances the arcing frequency, while heating to 85 C to remove water vapor significantly reduces the arc frequency. The interaction of the adhesive used to attach the cover glass to the solar cell with ambient water vapor is the key factor in determining arcing rates. Elimination of adhesive exposed to the environmental plasma reduces the arc frequency more than two orders of magnitude, and eliminates any sensitivity to H2O exposure. The adhesive may also become a source of spacecraft contamination. Macroscopic amounts were observed to blow off some arc events, and (we assume) electrostatically precipitate at other negatively biased locations. Data, analysis, and potential impact for future space platforms are discussed.

Marinelli, W. J.↗

SKIRT Space Shuttle glow experiment

This paper describes a spectrometer/radiometer experiment to obtain infrared, visible, and ultraviolet measurements of Space Shuttle glow. The payload, Spacecraft Kinetic Infrared Test (SKIRT), is a cryogenic circular variable filter infrared spectrometer with a number of infrared, visible, and ultraviolet radiometers covering the spectral range of 0.2-5.4 microns and 9.9-10.3 microns. It will measure Shuttle glow as a function of mission elapsed time, orbiter attitude, temperature, and orbiter events such as thruster firings. The measured data should have sufficient spectral resolution and sensitivity to identify molecular species contributing to Shuttle glow emissions. SKIRT is manifested on STS-39.

Ahmadjian, M.↗

Origin of the Shuttle glow

On a recent Shuttle mission four gases, NO, CO2, Xe, and Ne were released for a plasma experiment. Unintentionally, enough gas was scattered onto the surfaces of the Shuttle tail that when NO was released a much more intense version of Shuttle glow was observed. The other gases did not affect the normal Shuttle glow. Under normal conditions the adsorbed NO that causes the glow probably come either from the ambient atmosphere or from reactions in exhaust gases from the Shuttle thrusters.

Viereck, R. A.↗

Collisional quenching of atoms and molecules on spacecraft thermal protection surfaces

Preliminary results of a research program to determine energy partitioning in spacecraft thermal protection materials due to atom recombination at the gas-surface interface are presented. The primary focus of the research is to understand the catalytic processes which determine heat loading on Shuttle, Aeroassisted OTV, and NASP thermal protection surfaces in nonequilibrium flight regimes. Highly sensitive laser diagnostics based on laser-induced fluorescence and resonantly-enhanced multiphoton ionization spectroscopy are used to detect atoms and metastable molecules. At low temperatures, a discharge flow reactor is employed to measure deactivation/recombination coefficients for O-atoms, N-atoms, and O2. Detection methods are presented for measuring O-atoms, O2 and N2, and results for deactivation of O2 and O-atoms on reaction-cured glass and Ni surfaces. Both atom recombination and metastable product formation are examined. Radio-frequency discharges are used to produce highly dissociated beams of atomic species at energies characteristic of the surface temperature. Auger electron spectroscopy is employed as a diagnostic of surface composition in order to accurately define and control measurement conditions.

Marinelli, W. J.↗

Calculation of space station infrared irradiance from atmosphere-induced emissions

The excitation mechanisms and radiance estimates over the 1 to 10 micron region for CO2(v), H2O(v), CO(v), OH(v), NO2(2B-2A) and N2(B3 pi - A3 sigma) are discussed. The infrared irradiance of the Space Station at an altitude of 460 km was estimated. The surface material was presumed to be non-carbonaceous and inert. The determined number densities of the various gases relevant to the Space Station from both ambient and outgassing sources are presented. A model for the production of and emission from the infrared active molecules was constructed that considers two classes of production processes: (1) gas phase excitation of molecules in the near Station environment by collision with ambient flux; and (2) surface processes that lead to molecular excitation. A composite spectrum of all major emitting species shows that the observed irradiance is non-uniform over the 1 to 8 micron region. The comparison of predicted irradiance with the zodiacal background indicates that the Space Station infrared background from atmosphere-induced emissions may be a problem of consequence.

Fraser, M. E.↗

Chemical interactions in Low Earth Orbit (LEO)

Although several observations of material changes on-orbit have been reported, mechanistic understanding has not yet become clear because new sets of non-intuitive processes are occurring on orbit. Reactant kinetic energy, low collision rates and surface/adsorbate interactions must be considered in the analysis of these observations. The specific example of oxide formation of elemental materials is examined in terms of thermodynamics and possible reaction pathways. On the basis of this approach, a rational trend emerges from the orbital behavior of these samples. The role of reactant kinetic energy as opposed to internal energy in chemiluminescent product formation is also presented. Development of a systematic thermochemical approach may be useful in making screening predictions of long-term material behavior on-orbit.

Green, B. D.↗

Spectral identification/elimination of molecular species in spacecraft glow

Computer models of molecular electronic and vibrational emission intensities were developed. Known radiative emission rates (Einstein coefficients) permit the determination of relative excited state densities from spectral intensities. These codes were applied to the published spectra of glow above shuttle surface and to the Spacelab 1 results of Torr and Torr. The theoretical high-resolution spectra were convolved with the appropriate instrumental slit functions to allow accurate comparison with data. The published spacelab spectrum is complex but N2+ Meinel emission can be clearly identified in the ram spectrum. M2 First Positive emission does not correlate well with observed features, nor does the CN Red System. Spectral overlay comparisons are presented. The spectrum of glow above shuttle surfaces, in contrast to the ISO data, is not highly structured. Diatomic molecular emission was matched to the observed spectral shape. Source excitation mechanisms such as (oxygen atom)-(surface species) reaction product chemiluminescence, surface recombination, or resonance fluorescent re-emission will be discussed for each tentative assignment. These assignments are the necessary first analytical step toward mechanism identification. Different glow mechanisms will occur above surfaces under different orbital conditions.

Green, B. D.↗

Laser absorption spectroscopy - Method for monitoring complex trace gas mixtures

A frequency stabilized CO2 laser was used for accurate determinations of the absorption coefficients of various gases in the wavelength region from 9 to 11 microns. The gases investigated were representative of the types of contaminants expected to build up in recycled atmospheres. These absorption coefficients were then used in determining the presence and amount of the gases in prepared mixtures. The effect of interferences on the minimum detectable concentration of the gases was measured. The accuracies of various methods of solution were also evaluated.

Green, B. D.↗

Monitoring complex trace-gas mixtures by long-path laser absorption spectrometry

Laser-based spectrophotometric methods, which have been proposed for the detection of trace concentrations of gaseous contaminants, include Raman and passive radiometry. The paper discusses a simple long-path laser absorption method which is capable of resolving complex mixtures of closely related trace contaminants at ppm levels. A number of species were selected which are most likely to accumulate in closed environments, such as submarines or long-duration manned space flights. Absorption coefficients at CO2 laser wavelengths were measured, accurate to + 3 per cent or better, for each of these species. This data base was then used to determine the presence and concentration of the contaminants in prepared mixtures of 12 to 15 gases. Computer programs have been developed which will permit a real-time analysis of the monitored atmosphere. Minimum detectable concentrations for individual species are generally in the ppm range, and are not seriously degraded by interferences even in complex mixtures. Estimates of the dynamic range of this monitoring technique for various system configurations and comparison with other methods of analysis are discussed

Green, B. D.↗