Laser Pollutant-Measuring Systems
Laser optical system for remote gas pollutant measurements surveyed. Laser systems discussed in published report, and choices of appropriate gasmeasuring instruments and their sensitivities evaluated.
Engineering topics
Publications and source records attributed to Grant, W. B..
Laser optical system for remote gas pollutant measurements surveyed. Laser systems discussed in published report, and choices of appropriate gasmeasuring instruments and their sensitivities evaluated.
A detailed study of the detection of trace gases at atmospheric pressure using tunable diode lasers is described. The influence of multipass cells, retroreflectors and topographical targets is examined. The minimum detectable infrared absorption ranges from 0.1 percent for a pathlength of 1.2 km to 0.01 percent over short pathlengths. The factors which limit this sensitivity are discussed, and the techniques are illustrated by monitoring atmospehric CO2 and CH4.
A portable laser system for remote detection of methane gas leaks and concentrations is disclosed. The system transmitter includes first and second lasers, tuned respectively to a wavelength coincident with a strong absorption line of methane and a reference wavelength which is weakly absorbed by methane gas. The system receiver includes a spherical mirror for collecting the reflected laser radiation and focusing the collected radiation through a narrowband optical filter onto an optial detector. The filter is tuned to the wavelength of the two lasers, and rejects background noise. The output of the optical detector is processed by a lock-in detector synchronized to the chopper, and which measures the difference between the first wavelength signal and the reference wavelength signal.
The absorption spectra of three hydrazines and four of their air-oxidation products were measured in the 9-12-micron spectral region with a Fourier transform infrared (FTIR) spectrometer with a 0.05-kayser resolution to determine absorption coefficients at CO2 and tunable diode laser wavelengths. The measurements agreed well with published CO2 laser determinations for many of the absorption coefficients, except where the published values are thought to be in error. The coefficients were then used to estimate the sensitivity for remote detection of these gases using CO2 and tunable diode lasers in long-path differential absorption measurements.
Remote sensor uses laser radiation backscattered from natural targets. He/Ne Laser System for remote scanning of Methane leaks employs topographic target to scatter light to receiver near laser transmitter. Apparatus powered by 1.5kW generator transported to field sites and pointed at suspected methane leaks. Used for remote detection of natural-gas leaks and locating methane emissions in landfill sites.
Several advanced atmospheric remote sensing systems developed at the Jet Propulsion Laboratory were demonstrated under various field conditions to determine how useful they would be for general use by the California Air Resources Board and local air quality districts. One of the instruments reported on is the Laser Absorption Spectrometer (LAS). It has a pair of carbon dioxide lasers with a transmitter and receiver and can be flown in an aircraft to measure the column abundance of such gases as ozone. From an aircraft, it can be used to rapidly survey a large region. The LAS is usually operated from an aircraft, although it can also be used at a fixed location on the ground. Some tests were performed with the LAS to measure ozone over a 2-km horizontal path. Another system reported on is the Microwave Atmospheric Remote Sensing System (MARS). It is tuned to microwave emissions from water vapor, liquid water, and oxygen molecules (for atmospheric temperature). It can measure water vapor and liquid water in the line-of-sight, and can measure the vertical temperature profile.
In order to test the possibility that tunable diode laser (TDL) systems using topographic targets can be applied to the measurement of a variety of gases at concentrations and distances characteristic of industrial gas leaks, a single-ended TDL system was assembled for use with selected topographic targets to detect NO2 at atmospheric pressure and NO2 and NH3 at low pressures. In both cases, the intensity distribution of radiation backscattered from selected targets was found to be heavily weighted to a specular rather than a Lambertian distribution. A sensitivity of 5 ppm-m has been demonstrated for the case of NO2.
Applications of the Differential Absorption Lidar (DIAL) technique to the remote sensing of pollutant gases are surveyed. In the DIAl technique, the differential absorption of two laser beams reflected back to a receiver from a target determines the concentration of the gas being studied. The types of instruments available are considered in detail: dye lidar (to measure nitrogen dioxide, sulfur dioxide, and ozone); carbon dioxide laser (for ozone, ethylene, ammonia, and hydrazine), helium-neon laser (for methane); hydrogen fluoride laser (for HF); and tunable diode laser (for nitric oxide and carbon monoxide). DIAL instruments are compared with other optical remote sensors such as Fourier-transform infrared spectrometers, correlation spectrometers (COSPEC and GASPEC), and grating spectrometers; and criteria for the selection of an appropriate gas measuring system are suggested. Laser and other optical remote sensors are found to be cost effective in many cases, despite the fact that they are more costly than point-monitoring systems.
Extensive data from large regions are needed as a basis for the study of anthropogenic trace gases in the troposphere. The need arises, therefore, for an instrument which is capable to monitor rapidly the atmosphere in a region. The present investigation is concerned with the results of efforts to develop an instrument which is capable of remotely measuring gases in the troposphere. The Laser Absorption Spectrometer (LAS) was designed for use in aircraft, and was employed to measure tropospheric ozone distribution since 1977. Attention is given to a description of the LAS instrument, the theoretical basis of instrument operation, LAS measurement programs, the results of the LAS development program, and future work.
This project demonstrated the feasibility of using laser remote sensing technology as a tool for leak survey work in natural gas distribution systems. A laboratory device was assembled using a pair of helium neon (HeNe) lasers to measure methane. One HeNe laser emits radiation at a wavelength of 3.3922 micrometers, which corresponds to a strong absorption feature of methane, while the other emits radiation at a wavelength of 3.3911 micrometers, which corresponds to a weak absorption by methane. As a particular area is scanned for leaks, the laser is pointed at convenient topographic targets within its operating range, about 25 m. A portion of the backscattered radiation is collected by a receiver and focused onto an indium antimonide (InSb) photodetector, cooled to 77K. Methane concentrations were determined from the differential absorption at the two wavelengths for the backscattered radiation.
Differential absorption lidar (DIAL) measurements of atmospheric gases and temperature made using topographic targets to provide the backscattered signal are subject to errors from the differential spectral reflectance of the target materials. The magnitude of this effect is estimated for a number of DIAL measurements reported in the literature. Calculations are presented for several topographic targets. In general the effect on a DIAL measurement increases directly with increasing wavelength and laser line separation, and inversely with differential absorption coefficient and distance to the target. The effect can be minimized by using tunable or isotope lasers to reduce the laser line separation or by using additional reference wavelengths to determine the surface differential spectral reflectance.
The laser absorption spectrometer (LAS) is an airborne instrument able to perform remote measurement of trace atmospheric gases. The instrument uses a pair of carbon dioxide laser-heterodyne receiver systems that are directed downward from an airplane and determines gas concentration by the differential absorption method. Configured to measure tropospheric ozone, the LAS has been used in conjunction with another instrumented aircraft to test the accuracy of this method of measurement. A complete description of the instrument is presented, and the results of extensive flight testing are summarized.
The effects of the proposed solar power satellite (SPS) operations on electronic equipment and systems by fundamental, harmonic, and intermodulation component emissions from the orbital station; and the fundamental, harmonic, and structural intermodulation emissions from the rectenna site were evaluated. The coupling and affects interactions affecting a wide spectrum of electronic equipment are considered. The primary EMC tasking areas are each discussed separately.
The susceptibility of various operational and planned low Earth orbit satellites to solar power satellite (SPS) operations was examined. Functional degradation for the electronic systems on LANDSAT, the global positioning system, and the space telescope is described in relation to the amplitude of the SPS illumination components. Analyses include the modes of coupling to devices and subsystems, and performance effects in relation to satellite mission.