Engineering topics

Gore, Warren J.

Publications and source records attributed to Gore, Warren J..

51 records · Page 3

NASA NTRS2000

Quantifying Denitrification and Its Effect on Ozone Recovery

Upper Atmosphere Research Satellite observations indicate that extensive denitrification, without significant dehydration, currently occurs only in the Antarctic during mid to late June. The fact that denitrification occurs in a relatively warm month in the Antarctic raises concern about the likelihood of its occurrence, and associated effects on ozone recovery, in a future colder and possibly more humid Arctic lower stratosphere. Polar stratospheric cloud lifetimes required for Arctic denitrification to occur in the future are presented and contrasted against the current Antarctic cloud lifetimes. Model calculations show widespread severe denitrification could enhance future Arctic ozone loss by up to 30%.

Tabazadeh, A.↗

NASA NTRS2000

Discriminating Type 1a and 1b PSCs in Satellite Data

We explore the use of satellite observations in discriminating types of PSCs and their ramifications. Polar Stratospheric Clouds (PSCs), which form in the winter polar vortex, have been identified as effecting ozone loss. One major result from the recent SOLVE mission is in-situ evidence of the existence of very large particles that contain nitric acid. These particles are consistent with Type la PSCs. The significance of this finding is that these large particles will have appreciable sedimentation velocities, taking nitric acid out of the stratospheric regions, causing denitrification. Since nitric acid typically mitigates ozone loss, denitrification leads to increased ozone loss. Type lb PSCs are smaller and do not sediment to any appreciable degree. Satellite measurements are made continuously throughout the winter, and offer more global coverage than in situ measurements. Thus, it would very useful to be able to discriminate PSC types from satellite measurements. Our long-term goals are to better understand the formation mechanisms and effects of PSCs. Discriminating PSC type using satellite data will give us a very important tool in this effort. A multi-wavelength analysis of POAM aerosol extinction during SOLVE has revealed differences in the radiative characteristics of PSC events. We explore the use of POAM observations to discriminate between Type la and lb Pscs. A trajectory model is used to simulate PSC la and lb particles. Calculated radiative properties act as a guide for discriminating the satellite occultation measurements. Aircraft based PSC observations are-used as confirmation of these observations.

Strawa, Anthony W.↗

NASA NTRS2000

Precipitating Condensation Clouds in Substellar Atmospheres

We present a method to calculate vertical profiles of particle size distributions in condensation clouds of giant planets and brown dwarfs. The method assumes a balance between turbulent diffusion and precipitation in horizontally uniform cloud decks. Calculations for the Jovian ammonia cloud are compared with previous methods. An adjustable parameter describing the efficiency of precipitation allows the new model to span the range of predictions from previous models. Calculations for the Jovian ammonia cloud are found to be consistent with observational constraints. Example calculations are provided for water, silicate, and iron clouds on brown dwarfs and on a cool extrasolar giant planet.

Ackerman, Andrew S.↗

NASA NTRS1998

A Modeling Approach to Global Land Surface Monitoring with Low Resolution Satellite Imaging

The effects of changing land use/land cover on global climate and ecosystems due to greenhouse gas emissions and changing energy and nutrient exchange rates are being addressed by federal programs such as NASA's Mission to Planet Earth (MTPE) and by international efforts such as the International Geosphere-Biosphere Program (IGBP). The quantification of these effects depends on accurate estimates of the global extent of critical land cover types such as fire scars in tropical savannas and ponds in Arctic tundra. To address the requirement for accurate areal estimates, methods for producing regional to global maps with satellite imagery are being developed. The only practical way to produce maps over large regions of the globe is with data of coarse spatial resolution, such as Advanced Very High Resolution Radiometer (AVHRR) weather satellite imagery at 1.1 km resolution or European Remote-Sensing Satellite (ERS) radar imagery at 100 m resolution. The accuracy of pixel counts as areal estimates is in doubt, especially for highly fragmented cover types such as fire scars and ponds. Efforts to improve areal estimates from coarse resolution maps have involved regression of apparent area from coarse data versus that from fine resolution in sample areas, but it has proven difficult to acquire sufficient fine scale data to develop the regression. A method for computing accurate estimates from coarse resolution maps using little or no fine data is therefore needed.

Hlavka, Christine A.↗

NASA NTRS1998

Detecting a Terrestrial Biosphere Sink for Carbon Dioxide: Interannual Ecosystem Modeling for the Mid-1980s

There is considerable uncertainty as to whether interannual variability in climate and terrestrial ecosystem production is sufficient to explain observed variation in atmospheric carbon content over the past 20-30 years. In this paper, we investigated the response of net CO2 exchange in terrestrial ecosystems to interannual climate variability (1983 to 1988) using global satellite observations as drivers for the NASA-CASA (Carnegie-Ames-Stanford Approach) simulation model. This computer model of net ecosystem production (NEP) is calibrated for interannual simulations driven by monthly satellite vegetation index data (NDVI) from the NOAA Advanced Very High Resolution Radiometer (AVHRR) at 1 degree spatial resolution. Major results from NASA-CASA simulations suggest that from 1985 to 1988, the northern middle-latitude zone (between 30 and 60 degrees N) was the principal region driving progressive annual increases in global net primary production (NPP; i.e., the terrestrial biosphere sink for carbon). The average annual increase in NPP over this predominantly northern forest zone was on the order of +0.4 Pg (10 (exp 15) g) C per year. This increase resulted mainly from notable expansion of the growing season for plant carbon fixation toward the zonal latitude extremes, a pattern uniquely demonstrated in our regional visualization results. A net biosphere source flux of CO2 in 1983-1984, coinciding with an El Nino event, was followed by a major recovery of global NEP in 1985 which lasted through 1987 as a net carbon sink of between 0.4 and 2.6 Avg C per year. Analysis of model controls on NPP and soil heterotrophic CO2 fluxes (Rh) suggests that regional warming in northern forests can enhance ecosystem production significantly. In seasonally dry tropical zones, periodic drought and temperature drying effects may carry over with at least a two-year lag time to adversely impact ecosystem production. These yearly patterns in our model-predicted NEP are consistent in magnitude with the estimated exchange of CO2 by the terrestrial biosphere with the atmosphere, as determined by previous isotopic (delta (sup 13 C) convolution analysis. Ecosystem simulation results can help further target locations where net carbon sink fluxes have occurred in the past or may be verified in subsequent field studies.

Potter, Christopher S.↗

NASA NTRS1998

Line Assignments and Position Measurements in Several Weak CO2 Bands Between 4590/cm and 7930/cm

A substantial set of CO2 spectra from 4500 to 12000/cm has been obtained at Ames with 1500 m path length using a Bomem DA8 FTS. The signal/noise was improved compared to prior spectra obtained in this laboratory by including a filter wheel limiting the band-pass of each spectrum to several hundred per cm. We have measured positions of lines in several weak bands not previously resolved in laboratory spectra. Using our positions and assignments of lines of the Qbranch of the 31103-00001 vibrational band at 4591/cm, we have redetermined the rotational constants for the 31103f levels. Q-branch lines of this band were previously observed, but misassigned, in Venus spectra by Mandin. The current HITRAN values of the rotational constants for this level are incorrect due to the Q-branch misassignments. Our prior measurements of the 21122-00001 vibrational band at 7901/cm were limited to Q-and R-branch lines; with the improved signal/noise of these new spectra we have now measured lines in the weaker P branch. The 21122 (Gv = 790148/cm) levels are known to be perturbed by the 32211 (G(sub v) = 789757/cm) levels; new DND calculations predict that high-J lines of the forbidden 32211-00001 vibrational band 'borrow' intensity from the corresponding transitions of the 21122-00001 band. We have identified such Q- and R-branch transitions of the 32211-00001 band from 26 < J" < 44, based on our position measurements of lines in the 32211-02201 band at 6562/cm.

Giver, L. P.↗

NASA NTRS1998

Stratospheric Sulfuric Acid and Black Carbon Aerosol Measured During POLARIS and its Role in Ozone Chemistry

Stratospheric aerosol can affect the environment in three ways. Sulfuric acid aerosol have been shown to act as sites for the reduction of reactive nitrogen and chlorine and as condensation sites to form Polar Stratospheric Clouds, under very cold conditions, which facilitate ozone depletion. Recently, modeling studies have suggested a link between BCA (Black Carbon Aerosol) and ozone chemistry. These studies suggest that HNO3, NO2, and O3 may be reduced heterogeneously on BCA particles. The ozone reaction converts ozone to oxygen molecules, while HNO3 and NO2 react to form NOx. Finally, a buildup of BCA could reduce the single-scatter albedo of aerosol below a value of 0.98, a critical value that has been postulated to change the effect of stratospheric aerosol from cooling to warming. Correlations between measured BCA amounts and aircraft usage have been reported. Attempts to link BCA to ozone chemistry and other stratospheric processes have been hindered by questions concerning the amount of BCA that exists in the stratosphere, the magnitude of reaction probabilities, and the scarcity of BCA measurements. The Ames Wire Impactors (AWI) participated in POLARIS as part of the complement of experiments on the NASA ER-2. One of our main objectives was to determine the amount of aerosol surface area, particularly BCA, available for reaction with stratospheric constituents and assess if possible, the importance of these reactions. The AWI collects aerosol and BCA particles on thin Palladium wires that are exposed to the ambient air in a controlled manner. The samples are returned to the laboratory for subsequent analysis. The product of the AWI analysis is the size, surface area, and volume distributions, morphology and elemental composition of aerosol and BCA. This paper presents results from our experiments during POLARIS and puts these measurements in the context of POLARIS and other missions in which we have participated. It describes modifications to the AWI data analysis procedures in which the collection of BCA is modeled as a fractal aggregate. The new analysis results in an increase in BCA surface area of approximately 24 and an increase in mass of 7-10 from the previous method. For the current study, BCA surface area is used in computer models that attempt to predict measured NOx/NOy ratios and O3 depletion rates. Inclusion of the HNO3 reaction with BCA in one model tends to improve the agreement of calculated to measured NOx/NOy ratio. However, it was found that these trends are viable only if the reactions are catalytic.

Strawa, Anthony W.↗

NASA NTRS1998

Stratospheric Aerosol Measurements

Stratospheric aerosols affect the atmospheric energy balance by scattering and absorbing solar and terrestrial radiation. They also can alter stratospheric chemical cycles by catalyzing heterogeneous reactions which markedly perturb odd nitrogen, chlorine and ozone levels. Aerosol measurements by satellites began in NASA in 1975 with the Stratospheric Aerosol Measurement (SAM) program, to be followed by the Stratospheric Aerosol and Gas Experiment (SAGE) starting in 1979. Both programs employ the solar occultation, or Earth limb extinction, techniques. Major results of these activities include the discovery of polar stratospheric clouds (PSCs) in both hemispheres in winter, illustrations of the impacts of major (El Chichon 1982 and Pinatubo 1991) eruptions, and detection of a negative global trend in lower stratospheric/upper tropospheric aerosol extinction. This latter result can be considered a triumph of successful worldwide sulfur emission controls. The SAGE record will be continued and improved by SAGE III, currently scheduled for multiple launches beginning in 2000 as part of the Earth Observing System (EOS). The satellite program has been supplemented by in situ measurements aboard the ER-2 (20 km ceiling) since 1974, and from the DC-8 (13 km ceiling) aircraft beginning in 1989. Collection by wire impactors and subsequent electron microscopic and X-ray energy-dispersive analyses, and optical particle spectrometry have been the principle techniques. Major findings are: (1) The stratospheric background aerosol consists of dilute sulfuric acid droplets of around 0.1 micrometer modal diameter at concentration of tens to hundreds of monograms per cubic meter; (2) Soot from aircraft amounts to a fraction of one percent of the background total aerosol; (3) Volcanic eruptions perturb the sulfuric acid, but not the soot, aerosol abundance by several orders of magnitude; (4) PSCs contain nitric acid at temperatures below 195K, supporting chemical hypotheses implicating manmade fluorocarbons as cause of the --'ozone hole'; (5) The current soot loading is too small to be of environmental (radiative and chemical) consequence. However, the fractal nature of soot distinguishes it aerodynamically and radiatively from sulfuric acid droplets such that its stratospheric residence time is longer, mainly because of vertical transport against gravity due to gravito-photophoretic forces. Thus it may accumulate and become of environmental concern in the future.

Pueschel, Rudolf, F.↗

NASA NTRS1998

Line Intensity and Position Measurements and Derived Band Parameters of the 31103-00001 C-12 O-16(2) Band and its Two Nearby Hot Bands

A set of CO2 spectra from 4500 to 4780/cm has been obtained an Ames with 1500 m path length using a Bomem DA8 FTS. This spectral region contains a number of weak bands and minor isotopic bands that have been studied at high resolution in the reflection spectrum of Venus by Mandin. Improved laboratory intensity and position measurements should assist modeling the Venus reflection spectra and improve understanding of Venus' upper atmosphere. Also, the laboratory measurements will assist DND intensity computations of weaker bands that cannot be measured, but which are nevertheless significant absorbers in Venus' hot, deep CO2, atmosphere. For example, some of the weaker bands that are members of the same polyads as the bands in this presentation lie in the nearby 2.3 microns emission window in Venus' night-side spectrum.

Giver, Lawrence P.↗

NASA NTRS1996

Temperature Dependence of Nitrogen Broadening of the NO Fundamental Vibrational Band

We report measured N2-broadening coefficients, gamma (T), of approximately 70 transitions of the ground electronic state fundamental vibration-rotation band (v=1 (left arrow) 0) of NO at 183, 213 and 296K. In addition to the broadening asymmetry previously observed between the 2 pi 3/2 and 2 pi 1/2 state transitions, we also observed for most of the 2 pi 1/2 transitions an increased broadening of the f-lambda over e-lambda components. The temperature dependence of the broadening coefficients was characterized by the power law, gamma T = gamma 296 (296/T) (sup n).

Spencer, M. N.↗

NASA NTRS1996

Subsonic Aircraft Soot: A Tracer Documenting Stratospheric Vertical Mixing and Barriers to Inter-Hemispheric Exchanges

Pole-to-pole variability of soot aerosol from subsonic aircraft is evidence of two important aspects of stratospheric transport. Vertical transport to 20 km pressure altitude from flight levels near 10-12 km cannot be explained by isentropic mixing. Instead, lofting in the tropics is a possibility. A strong meridional gradient implies that stratospheric soot aerosol residence time is shorter than are mixing times between the hemispheres. Therefore, little if any of exhaust constituents (with residence times similar to that of aircraft soot aerosol), emitted in heavily traveled flight corridors in northern mid-latitudes by a future supersonic fleet, would be transported to the southern hemisphere. However, a significant fraction of NOx could be lofted to altitudes above flight levels where it would dominate ozone depletion.

Pueschel, Rudolf F.↗

NASA NTRS1996

A Comparison of Cloud Microphysical and Optical Properties during TOGA-COARE

The impact of cirrus clouds on climate is an issue of research interest currently. Whether cirrus clouds heat or cool the Earth-atmosphere system depends on the cloud shortwave albedo and infrared reflectance and absorptance. These in turn are determined by the size distribution, phase, and composition of particles in the clouds. The TOGA-COARE campaign presented an excellent opportunity to study cirrus clouds and their influence on climate. In this campaign, a microphysics instrument package was flown aboard the DC-8 aircraft at medium altitudes in cirrus clouds. This package included a 2D Greyscale Cloud Particle Probe, a Forward Scattering Spectrometer Aerosol Probe, and an ice crystal replicator. At the same time the ER-2 equipped with a radiation measurement system flew coordinated flight tracks above the DC-8 at very high altitude. The radiation measurement made were short and long wave fluxes, as well as narrowband fluxes, both upwelling and downwelling. In addition LIDAR data is available. The existence of these data sets allows for a the comparison of radiation measurement with microphysical measurements. For example, the optical depth and effective radius retrieved from the ER-2 radiation measurements can be compared to the microphysical data. Conversely, the optical properties and fluxes produced by the clouds can be calculated from the microphysical measurements and compared to those measured aboard the ER-2. The assumptions required to make these comparisons are discussed. Typical microphysical results show a prevalence of micron-sized particles, in addition to the cloud particles that exceed 100 mm. The large number of small particles or "haze" cause the effective cloud radii to shift to smaller sizes, leading to changes in optical parameters.

Strawa, A. W.↗

NASA NTRS1995

The Rovibrational Intensities of the (40 deg 1) and (00 deg 0) Pentad Absorption Bands of 12C16O2 Between 7284 and 7921 cm(exp-1)

Carbon dioxide is the major constituent of the atmospheres of both Mars and Venus. Correct interpretations of spectra of these atmospheres require accurate knowledge of a substantial number of absorption bands of this gas. This is especially true for Venus; many weak CO2 bands that are insignificant in the earth's atmosphere are prominent absorbers in Venus' hot, dense lower atmosphere. Yet, recent near-infrared spectra of Venus' nightside have discovered emission windows, which occur between CO2 absorption bands, at 4040-4550 cm(exp-1), 5700-5900 cm(exp-1), and several smaller ones between 7500 and 9400 cm(exp-1). This radiation is due to thermal emission from Venus' lower atmosphere, diminished by scattering and absorption within the sulfuric acid clouds on its way to space. Simulations of these data with radiative transfer models can provide improved information on the abundances of a number of constituents of the lower atmosphere (e.g. H2O, CO, HDO, HCl, HF, and OCS) and the optical properties of the clouds, whose spatial variation modulates the brightness of the emissions. However, the accuracy of these retrievals has been limited by insufficient knowledge of the opacity of some of the gas species, including CO2, at the large pathlengths and high temperatures and pressures that exist on Venus. In particular, modeling the emission spectrum did not produce a good fit for the emission window centered at 7830 cm(exp-1). In an ongoing effort to assist analyses of these Venus spectra, we have been making laboratory intensity measurements of several weak bands of CO2 which are significant absorbers in these Venus emission windows. The CO2 bands that are prominent in the 7830 cm(exp-1) region belong to the vibrational sequence 4v1+v3 and associated hot bands. Only 2 of the 5 bands of this sequence have been previously measured. Modeling Venus' emission spectrum in the 7830 cm(exp-1) region had to rely on calculated intensity values for the weak ground state band at 7921 cm-1 and the associated hot bands. Since the calculated intensities of ground state bands are known to have significant uncertainties, we decided to measure this (40 deg 1)I (left arrow) (00 deg 0) band with the Ames 25 meter multiple reflection absorption cell and Fourier transform spectrometer. We also measured the (40 deg 1) (sub IV) (left arrow) (00 deg 0) band at 7460 cm(exp-1), which also had not been previously measured. These measurements are reported in this article, and we also give our reanalysis of the prior measurements of the (40 deg 1) (sub III) (left arrow) (00 deg 0) bands. These measurements provide the basis for improving calculated intensities for related hot bands as well as simulations of Venus' spectrum.

Giver, L. P.↗

NASA NTRS1994

Intensity Measurements of the 01(sup 1)21-00(sup 0)01 Perpendicular CO2 band at 5315 cm (sup -1) and 4 related hot bands

The near-infrared thermal emission windows in the spectrum of the night-side of Venus have stimulated new determinations of the intensities of weak CO2 bands which are prominent absorption features in Venus spectra. We have previously measured the 31(sup 1)04-00(sup 0)01 band at 4416 cm (sup -1), which dominates a portion of the 2.2 micrometer window, using the 25-meter White absorption cell at Ames. Parameters for many of the unmeasured bands have been recomputed for the HITRAN compilation using direct numerical diagonalization. This procedure has some uncertainties, particularly for higher overtone-combination perpendicular bands, and substantial differences were noted for these bands when comparing the 1986 HITRAN tabulation with the 1992 values. To clarify this situation, we decided to measure the intensities of several of these bands; L.R.B. obtained spectra using the McMath FTS and 6 meter White cell, covering the region 3800 to 7700 cm (sup -1). A table is provided in which we compare our measured intensities and Herman-Wallis al parameters for the 01(sup 1)21-00(sup 0)01 band and 4 associated hot bands with both Hitran tabulations. It is anticipated that these measured values will be useful in further DND calculations of many very weak unmeasurable bands.

Giver, Lawrence P.↗

NASA NTRS1994

Physical and Optical/Radiative Properties of Arctic Aerosols: Potential Effects on Arctic Climate

We have determined the abundance of light-scattering sulfuric acid (H2SO4/H2O) and light-absorbing black carbon aerosol (BCA) in Spring 1992 in the Arctic atmosphere by airborne in situ sampling with impactors, and measured particle sizes and morphologies by scanning electron microscopy. The mass of BCA in the Arctic troposphere is one percent of the total aerosol, reduced to one part in 104 in the stratosphere. A Mie algorithm permits the calculation of the optical properties of the various aerosol components, and an algorithm developed by Ackerman and Toon and modified to serve our needs lets us calculate the optical effects of the black carbon aerosol that is mixed internally with the sulfuric acid aerosol. It follows that the effect of internally-mixed BCA on the aerosol scattering and absorption properties depends on its location within the droplet. BCA concentrated near the droplet surface has a greater effect on absorption of solar radiation than does the same amount of BCA located near its center. Single scatter albedos of the combined system are omega(sub 0)=1.0 in the post-Pinatubo Arctic stratosphere, and as low as 0.94 in the troposphere. The aerosol has the potential to regionally warm the Arctic earth-atmosphere system, because of the high surface albedo of the snow-covered Arctic.

Pueschel, R. F.↗