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Glen C King

Publications and source records attributed to Glen C King.

Polyvinyl Alcohol and Medium Density Polyethylene Composite Materials for Neutron Radiation Shielding

Manned spacecraft venturing beyond the Earth’s Van Allen Belts will be subjected to high levels of radiation from both energetic particles emanating from the sun and from galactic atomic events, such as supernovae. The metal shell of a spacecraft offers some protection from gamma radiation and high energy particles originating from both the sun and cosmic sources. The interaction of these high energy particles and radiation with the spacecraft hull create secondary radiation and neutrons, additional hazards for astronauts and electronic systems. Shielding of neutrons is the most challenging of the high energy radiation, since neutrons have zero charge and are least affected by electrical fields, magnetic fields, and atomic forces. Previous studies showed that polyethylene is an effective neutron shielding material, due to its high hydrogen content. High energy neutrons are slowed to thermal neutrons through multiple collisions with the hydrogen atoms, increasing the effectiveness of neutron capture by boron-10 atoms. This study discusses the fabrication and testing of polyvinyl alcohol (PVOH) samples as a neutron shielding material, with comparison to medium density polyethylene (MDPE) composite samples to be used for neutron shielding for spacecraft. PVOH, an aqueous polymer, was chosen for hydrogen content and for enabling the use of organic reinforcement such as cellulose for secondary structural composites. OLTARIS (On-Line Tool for the Assessment of Radiation in Space) was used for radiation shielding simulation and compared with experimental data. Modeling indicates that the most effective shielding from radiation was in an aluminum layer backed by a polymer layer, either MDPE or PVOH. Cross-linked PVOH was also included in the OLTARIS modeling. All 3 polymer cases showed shielding improvement over aluminum alone, with similar dose equivalent reduction for galactic cosmic radiation(GCR)and for radiation from a solar particle event (SPE). Fourier Transform Infrared (FTIR) Spectroscopy was used to confirm the cross-linking in the PVOH sample and to determine the uniformity through the thickness. PVOH, cross-linked PVOH, and MDPE samples were tested for neutron shielding effectiveness using a 1 curie Americium-Beryllium neutron source. Test results indicated the most shielding in the cross-linked PVOH, followed by the pristine PVOH, and MDPE. Neutron testing suggests that polyvinyl alcohol is a good alternative to polyethylene for neutron shielding. The neutron shielding materials, PVOH and cross-linked PVOH developed under this research will enable the safe operation of spacecraft beyond the Earth’s protective Van Allen Radiation Belts. It will be crucial for NASA’s manned missions to the Moon or Mars to protect the health of astronauts and equipment from the harmful effects of excessive radiation.

neutron, shielding, radiation, polyvinyl alcohol, ↗

Assessing Degradation of Advanced Coatings for Carbon/Carbon Composites

Carbon/carbon (C/C) composites are a well-utilized material system for hot structures to enable hypersonic flight. However, C/C materials are susceptible to attack by environmental degradation mechanisms, notably oxidation, which can limit the durability of components resulting in premature failure. Environmental barrier coatings (EBCs) have been developed to mitigate deleterious oxidation. Coating compositions based on silicon carbide (SiC) offer promise as a protective coating material for C/C composites. Under particular hypersonic flight conditions, a passivating silica scale can form at the surface of the EBC, acting as a barrier that can protect the underlying coating and substrate. However, the transition from passive to active oxidation, which varies with temperature and pressure, causes the formation of gaseous SiO that volatilizes leading to detrimental consumption of the SiC coating. In this work, arc-jet testing of SiC-based coatings developed to protect Advanced C/C-6 (ACC-6) was performed under a range of conditions to replicate varying oxidation conditions. In-situ optical emission spectroscopic measurements of the gas-surface interactions were collected and evaluated to render compositional degradation of the coating and underlying composite during arc-jet testing. Specimens were evaluated before, during and after arc-jet testing using destructive and non-destructive materials characterization methods, including optical and scanning electron microscopy and energy dispersive spectroscopy.

Coatings, Hypersonics, Composites↗

An Overview of LO-DuSST (Lunar Occupancy Dust Surface Separation Technologies) Objectives

Of the myriad of issues facing lunar exploration and maintaining an extended lunar presence, lunar dust is possibly the most pervasive. These jagged, chemically reactive, electrostatically charged, sometimes magnetic particles can impact every aspect of a lunar surface mission ranging from abrading extra-vehicular activity (EVA) suits to disrupting lunar vehicle thermal management systems to impeding efficacy of excavation equipment to impacting lunar inhabitant health. NASA’s Lunar Occupancy Dust Surface Separation Technologies (LO-DuSST) task, as a part of the broader Lunar Surface Innovation Initiative (LSII) project, seeks to implement synergistic active and passive lunar dust management and mitigation technologies for an array of applications. One such application is protection of power generation capabilities via solar panel arrays. Plasma dust lofting coupled with a piezoelectric-driven vibration technology will be demonstrated on solar panel surfaces contaminated with lunar dust simulant. Intrinsically low adhesion coatings will be applied to these surfaces to enhance dust removal. Electrostatic repulsion in confined geometries and materials to manage high velocity lunar dust wear will also be investigated. Collectively, these active and passive mitigation technologies will facilitate lunar surface operations including occupancy logistics, landing pad operations, power generation, and transportation. Initial results regarding lunar simulant-contaminated solar panel performance experiments, dust lofting using an electron beam, surface interactions of high velocity lunar dust arising from lunar lander plume-surface interactions, and lunar dust simulant-material interaction experiments will be discussed.

Lunar dust↗

Passive Dust Mitigation Technologies Being Developed for Demonstration Under Patch Plate Materials Compatibility Analysis Task

With the Artemis program, we are planning longer stays on the surface, with more activities that have the potential to put the astronauts and equipment in contact with greater quantities of lunar dust. The success of these missions will depend on our understanding of material interactions with lunar dust and the development of ways to mitigate dust effects in cases where exposure to dust will lead to failure of components, unacceptable loss of power or thermal control, unacceptable loss of visibility, or health issues. Passive dust mitigation by coating or surface alteration is one method that is being developed and demonstrated under the Space Technology Mission Directorate’s Game Changing Technology, Dust Mitigation Program as part of the Patch Plate Materials Compatibility Assessment Task. The goal of the task is to alter the surfaces of materials in order to passively reduce the adhesion of dust, demonstrate their performance in relevant ground-based tests using lunar simulants, and prepare them for demonstration through experiment on the lunar surface. Optically transparent, sputter deposited, work function matching coatings are being developed to reduce adhesion of dust to windows, lenses and display panels by matching the minimum energy to remove an electron from the surface to that of lunar dust in order to reduce adhesion due to charge transfer. Low surface energy coatings and surfaces for thermal control are also being developed to reduce the bonding of dust with the surface enabling it to be removed more easily. Conductive coatings with the ability to shed dust more easily are being developed for use with the active Electrodynamic Dust Shield technology to help reduce the power needed to remove dust from the surface. Passive dust mitigation surfaces for metals such as aluminum, stainless steel, and titanium are being developed that reduce the area of dust contact with the surfaces through topographical modification using laser ablation patterning to impart hierarchical topographies with nanometer to micrometer length scales in a single step. Topographically modified polymeric materials, both those with extensive space heritage and those with lower technology readiness levels, are also being evaluated. Space suit fabric surfaces that can reduce dust penetration into and through the fabric are also being investigated as well as pristine and topographically modified ceramic materials that exhibit high wear resilience. An overview of the passive dust mitigation surfaces and coatings being developed under this task, ground testing being conducted using lunar simulants, characterization techniques, and materials preparation for flight sample delivery for integration into the Alpha Space Regolith Adherence Characterization experiment going to the lunar surface on a Commercial Lunar Payload Services (CLPS) lander in 2023 will be discussed.

Lunar dust, passive mitigation, lunar simulant, co↗

Evaluation of Materials and Surfaces for Lunar Regolith Adherence Characterization (RAC) Payload Samples

As the quest for long term lunar exploration and habitation comes closer to reality, widespread efforts are ongoing to effectively mitigate lunar dust surface contamination and infiltration. This dust is hazardous to humans and tends to adhere tenaciously to all exposed surfaces, causing performance issues and ultimately failure. While several active and passive technologies have been developed to address this challenge, assessing the performance of these technologies in the actual lunar environment is extremely important. The regolith adherence characterization (RAC) experiment payload provides an important opportunity for this evaluation. The RAC payload is designed by Alpha Space for the National Aeronautics and Space Administration (NASA)and scheduled to be flown to the moon in 2023 on the Firefly Aerospace Blue Ghost lander. As there were a limited number of slots available for materials to be chosen for this mission, it was critical to make an informed selection. Two polymers, a carbon fiber reinforced composite and a metal alloy were chosen to be a diverse selection of structural materials from NASA Langley Research Center. Each material was topographically modified using laser ablation patterning. This article briefly describes the selection and testing procedure and some of the results obtained for the passive dust mitigating materials and surfaces selected for this lunar surface experiment.

Lunar Dust↗

Protective Coatings for Mitigating Lunar Dust Abrasion and Adhesion

Materials resistant to the harsh lunar environment are needed to support long duration, sustainable missions on the Moon’s surface. Lunar dust poses a significant threat to the durability of components and vehicles due to its fine, jagged morphology and highly abrasive nature. These characteristics result in particles eroding, adhering and/or embedding onto component surfaces and into device confined geometries (e.g., gear housing, interlocking systems, etc.) potentially leading to premature failure. The aim of this work is to identify and characterize wear-resistant materials, including advanced ceramics, for use as protective coatings to minimize abrasion and adhesion caused by lunar dust. Results from testing and evaluation methods devised to elucidate and mimic aspects of lunar dust degradation, including adhesion, abrasion and erosion, as well as the lunar environment, will be presented. Discussion on balancing the need for dust management and tolerance versus dust adhesion mitigation will be shared in context of relevant lunar applications within the NASA Lunar Occupancy Dust Surface Separation Technologies effort, which is part of a NASA-wide effort to enable a sustained lunar presence through the Lunar Surface Innovation Initiative.

lunar dust mitigation↗

Materials for Extreme Environments: Paving the Way for Lunar Exploration

As humanity expands its ventures into lunar and planetary exploration, the demand intensifies for resilient materials capable of enduring extreme environmental and service conditions. The Moon’s surface presents numerous challenges, including ultra-high vacuum exposure, temperature extremes and intense radiation. Additionally, lunar regolith poses a significant threat to component durability and reusability due to its abrasive nature. Lunar dust particles scoring, adhering, or embedding into surfaces and within device-confined geometries, such as bearings, drive mechanisms and connectors, can cause premature component wear or failure. Furthermore, the interaction between the rocket plume and the surface during vehicle landings and ascents creates severe erosive conditions near critical vehicle components and adjacent infrastructure. A key barrier hindering materials discovery for lunar dust tolerant applications is a lack of standard laboratory methods to evaluate material properties and performance under representative operating conditions. A case will be presented for research activities supporting identification, processing and characterization of candidate materials in conjunction with innovations in standardized testing and qualification. Results will highlight current and emerging test methods for simulating lunar dust exposure and component degradation, paving the way for a new generation of robust materials and coatings for space exploration.

Lunar dust↗