Engineering topics
Publications and source records attributed to Gilligan, J. E..
Use of decomposable precursors to enhance zinc oxide-titanium dioxide reaction and rapid fixing results in rapid preparation of zinc orthotitanate powder pigment. Preparation process allows production under less stringent conditions. Elimination of powder grinding results in purer that is less susceptible to color degradation.
Zinc orthotitanate suitable for use as a pigment for spacecraft thermal control coatings is prepared by heating a slightly zinc deficient reaction mixture of precipitated oxalates of zinc and titanium. The reaction mixture can be formed by coprecipitation of zinc and titanium oxalates from chloride solution or by mixing separately precipitated oxalates. The mixture is first heated to 400 to 600 C to remove volatiles and is then rapidly heated at 900 to 1200 C. Zinc orthotitanate produced by this method exhibits the very fine particle size needed for thermal control coatings as well as stability in a space environment.
A program was conducted to develop and test electrically conductive paint coatings for spacecraft. A wide variety of organic and inorganic coatings were formulated using conductive binders, conductive pigments, and similar approaches. Z-93, IITRI's standard specification inorganic thermal control coating, exhibits good electrical properties and is a very space-stable coating system. Several coatings based on a conductive pigment (antimony-doped tin oxide) in silicone and silicate binders offer considerable promise. Paint systems using commercially available conductive polymers also appear to be of interest, but will require substantial development. Evaluations were made based on electrical conductivity, paint physical properties, and the stability of spectral reflectance in space environment testing.
The potential of zinc orthotitanate as a pigment for spacecraft thermal control was demonstrated. The properties and performance of pigments prepared by solid state, coprecipitation, and mixed oxalate methods were compared. Environmental tests and subsequent spectral analysis were given primary emphasis.
Pigment manufacturing development, binder development, environmental effects evaluations, and general coatings investigations are discussed. The relative emphasis on each of these tasks varied according to the urgency of the problems elucidated and the availability of time and funds. Emphasis is placed on the development of a mixed oxalate precursor zinc orthotitanate pigment manufacturing method and related studies and on complementary environmental testing and evaluation activities.
The development of a large scale manufacturing method for the production of a stable zinc orthotitanate pigment is studied, with emphasis placed on the comprehensive analysis of the properties and environmental stability of oxalate precursor zinc orthotitanate pigments and of the preparative conditions (time and temperature) leading to optimum properties and optical stability.
The development of a large scale manufacturing method for the production of a stable zinc orthotitanate pigment is discussed. Major emphasis was placed on the evaluation of ultraviolet radiation stability tests of pigments derived from coprecipitated and individually precipitated oxalates. Emphasis was also placed on an investigation of the conditions (time and temperature) leading to high reflectance and high optical stability. Paints were formulated in OI-650 and in OI-650G vehicles from pigments which were prepared at various temperatures. Analyses of ultraviolet irradiation test data were conducted regarding optimum pigment preparation parameters and treatment conditions.
The development of a large scale manufacturing method for the production of a stable zinc orthotitanate pigment is discussed. Major emphasis was placed on the evaluation of the radiation stability of Tektronix, Inc. pigments and of the conditions (time and temperature) leading to high reflection and high optical stability. Paints were formulated in OI-650 and in OI-650G vehicles from pigments which were prepared at various temperatures, some of which were chemically treated to remove ZnO. Ultraviolet irradiation tests of these paints were performed, and observations made regarding optimum pigment preparation parameters.
The development of a large scale manufacturing method for the production of a stable zinc orthotitanate pigment by means of an oxalate co-precipitation method is examined. Pigments were prepared at various temperatures, and major emphasis was placed on the determination of the important parameters of post-precipitation firing and treatment. A large-scale process for the modification of a glass resin binder was developed and paints were formulated using the binder.
A comprehensive program to develop low solar absorptance/high emittance coatings, to be successful, must coordinate basic materials preparation, coatings technology, environmental simulation, production, and flight-test evaluation. The prime criteria for 'white' thermal-control coatings are low solar absorptance and, most importantly, solar-absorptance stability. Many variables affect the solar absorptance and its stability. These effects must be discerned and evaluated. The factors involved, however, are not entirely independent; accordingly, the present paper emphasizes the major variables, the relationships among them, and how important they are in improving the properties and performance of the coatings.
Silicone elastomer is placed in evacuating system, heated to 160 C and held at this temperature for 24 hours. Elastomer is then cooled to room temperature in vacuum, producing upgraded, low outgassing polymer of increased molecular weight.
An experimental program in which salt-spray-exposed coatings have been irradiated is described and discussed.
Accomplishments made during study of coatings are reported. Development of structure/property theory for selecting most appropriate pigments for space vehicle paints is discussed along with improvements made in zinc-oxide pigmented potassium silicate paint.
Samples of S-13G that had been exposed to the salt air environment of Cape Kennedy, Florida were irradiated with simulated solar ultraviolet radiation after various cleaning treatments. In both of the the tests conducted two of the salt air exposed samples were not cleaned, two were lightly cleaned with water and detergent (i.e. rinsed), and two were vigorously scrubbed. Several other white thermal control coatings were also irradiated. The solar absorptance values of these coatings before and as a result of the ultraviolet irradiation are reported for exposure levels up to approximately 2000 ESH.
A reserach project to develop space stable thermal control coatings for large surfaces is discussed. Four major tasks are considered: (1) pigment development, (2) binder development, (3) environmental effects evaluations, and (4) general coatings investigations.
Experimental technique used in study of damage mechanism to semiconductor pigments exposed to ultraviolet radiation can be adapted for investigations of surface chemistry and may be used analytically to determine contamination.
The state-of-the-art of spacecraft thermal-control materials technology has been significantly advanced during the past 4 years. Selective black coatings are discussed together with black paints, dielectric films on metal surfaces, and white radiator coatings. Criteria for the selection of thermal-control surfaces are considered, giving attention to prelaunch protection, the capability of being measured, reproducibility, simulator response, and aspects of a nonindigenous space environment. Progress in space simulation is related to vacuum technology, ultraviolet sources, solar wind simulation, and the production of protons. Advances have been made in the protection against space environmental effects, and in the development of thermal-control surfaces and pigments.
The evaluation and environmental testing of zinc orthotitanate pigments for use as space stable thermal control coatings on large space vehicles are discussed. Electron paramagnetic resonance spectra of the pigments and their precursor compounds are examined. A continuing study of the spectral intensity of mercury-argon and mercury-xenon sources in reported. Results of long term environmental testing of commercially available, strippable, protective coatings are discussed.