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Garcia, R. R.

Publications and source records attributed to Garcia, R. R..

Long-Term Atmospheric Changes Caused by the Very Large Solar Proton Event in July 2000

Solar cycle 23 was accompanied by eight very large solar proton events (SPEs) between 2000 and 2005, along with numerous smaller events. The very large SPE in July 2000, which was associated with the well-known 'Bastille Day Solar Storm,' caused very substantial changes in the polar mesosphere and stratosphere. Significant downward transport of the SPE-produced NO(x) from the polar lower mesosphere and upper stratosphere during the Southern Hemisphere winter period resulted in huge enhancements (>100%) in middle stratospheric NO(x) (NO+NO2) during September 2000 in the polar vortex, which were measured by UARS HALOE (C. E. Randall et al., Geophys. Res. Lett., 28,2385-2388,2001). We have used the Whole Atmosphere Community Climate Model (WACCM) to study the longer-term impact of the July 2000 SPE, the third largest SPE period in the past 40 years. This very large SPE provided a wonderful opportunity to study the downward transport of energetic particle precipitation effects in the middle atmosphere. Not surprisingly, the WACCM-simulated polar Northern Hemisphere influences from the July (mid-summer) 2000 SPE were significant for a few months, but the constituent changes were not transported below about 20 hPa. However in the polar Southern Hemisphere (SH) region, the persistent downward transport in the vortex during the months of July-August-September resulted in significant modeled influences for about a year past the SPE. The SH odd nitrogen family, NO(y) (N, NO, NO2, NO3, N2O5, HNO3, HO2NO2, ClONO2, BrONO2), was greatly enhanced by this SPE and these increases were transported to the lower stratosphere. The SPE-enhanced polar NO(y) resulted in long-lasting ozone decreases (from catalytic NO(y) destruction of ozone) and ozone increases (from NO(y) interference in the chlorine and bromine catalytic ozone destruction cycles). These ozone changes resulted in simulated SH polar stratospheric temperature decreases (1-2 K) and increases (1-3 K)..

Jackman, C. H.

Observations of Intermediate-Scale Diurnal Waves in the Equatorial Mesosphere and Lower Thermosphere

The purpose of this study is to seek observational evidence for diurnal, vertically propagating inertia-gravity waves (IGWs) in the mesosphere and lower thermosphere (MLT). Numerical modeling studies indicate that vertically propagating IGWs excited by tropical heating provide a significant source of momentum for the semiannual oscillation (SAO) in the equatorial zonal mean winds. The power spectrum of these waves has a strong diurnal component. We analyze global patterns of ascending and descending node differences in MLT satellite temperatures, which are assumed in this study to be proxies for waves of diurnal period. Juxtaposed upon the planetary-scale features are localized variations with longitudinal wavelengths ranging from 25 deg to 50 deg, and with vertical wavelengths between 13 and 25 km. These intermediate-scale variations are spatially coherent, and persist for several weeks. Their amplitudes generally increase with altitude, while their phase structures suggest both eastward and westward propagation. The variance of wave numbers 9-17 in the MLT is examined in relation to the underlying stratospheric zonal mean zonal gradient winds. Stronger variances generally coincide with periods where the underlying zonal mean winds are relatively light, or unidirectional. The weak inverse association between variance strength and zonal wind magnitude is suggestive of a wave filtering mechanism.

Lieberman, R. S.

Ozone Depletion at Mid-Latitudes: Coupling of Volcanic Aerosols and Temperature Variability to Anthropogenic Chlorine

Satellite observations of total ozone at 40-60 deg N are presented from a variety of instruments over the time period 1979-1997. These reveal record low values in 1992-3 (after Pinatubo) followed by partial but incomplete recovery. The largest post-Pinatubo reductions and longer-term trends occur in spring, providing a critical test for chemical theories of ozone depletion. The observations are shown to be consistent with current understanding of the chemistry of ozone depletion when changes in reactive chlorine and stratospheric aerosol abundances are considered along with estimates of wave-driven fluctuations in stratospheric temperatures derived from global temperature analyses. Temperature fluctuations are shown to make significant contributions to model calculated northern mid-latitude ozone depletion due to heterogeneous chlorine activation on liquid sulfate aerosols at temperatures near 200-210 K (depending upon water vapor pressure), particularly after major volcanic eruptions. Future mid-latitude ozone recovery will hence depend not only on chlorine recovery but also on temperature trends and/or variability, volcanic activity, and any trends in stratospheric sulfate aerosol.

Solomon, S.

OH-asterisk (7-5) Meinel band dayglow and nightglow measured by the SME limb scanning near infrared spectrometer - Comparison of the observed seasonal variability with two-dimensional model simulations

Seasonal variations of the OH-asterisk (7-5) mesospheric hydroxyl emission at 1.89 microns observed by the SME near-IR spectrometer are compared with the theoretical predictions of a two-dimensional dynamical/chemical model. The good agreement found at low latitudes for both dayglow and nightglow provides support for the model assumption that breaking gravity waves induce seasonal and latitudinal variations in diffusion. The seasonal behavior of atomic hydrogen in the upper mesosphere (related to vertical transport) and/or uncertainties in the OH Meinel band parameters are proposed as possible explanations for the discrepancy noted between model and observational data for the middle latitudes.

Le Texier, H.

The role of molecular hydrogen and methane oxidation in the water vapour budget of the stratosphere

The detailed photochemistry of methane oxidation has been studied in a coupled chemical/dynamical model of the middle atmosphere. The photochemistry of formaldehyde plays an important role in determining the production of water vapor from methane oxidation. At high latitudes, the production and transport of molecular hydrogen is particularly important in determining the water vapor distribution. It is shown that the ratio of the methane vertical gradient to the water vapor vertical gradient at any particular latitude should not be expected to be precisely 2, due both to photochemical and dynamical effects. Modeled H2O profiles are compared with measurements from the Limb Infrared Monitor of the Stratosphere (LIMS) experiment at various latitudes. Molecular hydrogen is shown to be responsible for the formation of a secondary maximum displayed by the model water vapor profiles in high latitude summer, a feature also found in the LIMS data.

Le Texier, H.

Seasonal variability of the OH Meinel bands

The influence of seasonal and latitudinal changes in the distribution of mesospheric components on the OH Meinel-band nightglow is investigated by means of numerical simulations using the two-dimensional dynamical/chemical model of Garcia and Solomon (1985). The processes responsible for the formation and destruction of vibrationally excited OH in the mesosphere are described; the seasonal/latitudinal evolution for the higher (v greater than 6) and lower (v = 1-6) levels is shown in graphs and maps and characterized in detail; and the theoretical results are compared with published observational data. The lower-level emission is shown to depend on both O and H, suggesting that the variation of the Meinel-band nightglow can provide important information on the roles of advection and diffusion in the transport of water vapor and odd oxygen near the mesopause.

Le Texier, H.

Joule heating in the mesosphere and thermosphere during the July 13, 1982, solar proton event

The solar proton event of July 13, 1982 produced considerable ionization in the polar-cap mesosphere. Energetic solar proton fluxes were measured by the NOAA-6 satellite. The DE-2 satellite measured the low-energy electrons, the ion drift velocity, and other atmospheric and ionospheric properties during the event in the region of the measured maximum electric field (189 mV/m at 2215 UT near 60 deg N), a Joule heating rate of 1-3 K/day is calculated between 70 and 80 km, exceeding the heating due to ozone absorption at noon in the summer hemisphere in that altitude range. The Joule heating rate above 90 km greatly exceeded 20 K/day. The calculated height-integrated Joule heating rate above 100 km in the same region exceeded 400 ergs/sq cm sec, and DE-2 near 350 km measured neutral winds of nearly 1000 m/s and neutral gas temperatures of over 2000 K. The overall ionospheric structure calculated below the DE-2 satellite is described.

Roble, R. G.

Tracer transport by the diabatic circulation deduced from satellite observations

Nimbus-7 sensor data were used to track the diabatic circulation in the stratosphere to study the advective transport of CH4 and N2O as tracer species. Advective transport by the mean circulation was found to be a function of the temperature field and associated deviations from radiative equilibrium. A photochemical model was applied to account for the disappearance of the tracer species from the stratosphere. Comparisons between the SAMS data and modeling on the basis of the chemical loss rates of the tracers and the LIMS circulation data showed that the model predictions underestimated the resident abundances, although the global distributions and circulations exhibited a good match.

Solomon, S.

The effect of breaking gravity waves on the dynamics and chemistry of the mesosphere and lower thermosphere (invited review)

The influence of breaking gravity waves on the dynamics and chemical composition of the 60 to 110 km region is investigated with a two dimensional model that includes a parameterization of gravity wave momentum deposition and diffusion. The dynamical model is described by Garcia and Solomon (1983) and Solomon and Garcia (1983) and includes a complete chemical scheme for the mesosphere and lower thermosphere. The parameterization of Lindzen (1981) is used to calculate the momentum deposited and the turbulent diffusion produced by the gravity waves. It is found that wave momentum deposition drives a very vigorous mean meridional circulation, produces a very cold summer mesopause and reverse the zonal wind jets above about 85 km. The seasonal variation of the turbulent diffusion coefficient is consistent with the behavior of mesospheric turbulences inferred from MST radar echoes. The large degree of consistency between model results and various types of dynamical and chemical data supports very strongly the hypothesis that breaking gravity waves play a major role in determining the zonally-averaged dynamical and chemical structure of the 60 to 110 km region of the atmosphere.

Garcia, R. R.

On the atmospheric photochemistry of nitric acid

Measurements of the temporal and spatial variations in HNO3, particularly those from the Nimbus 7 limb IR monitor of the stratosphere (LIMS) satellite experiment, are compared to both a two-dimensional chemical/dynamical model and to chemistry/parcel trajectory analyses. Significant discrepancies are found between the observed and modeled variations in the winter season, especially in the polar night region. The study of the evolution of HNO3 suggests that an important source exists for this species in the high-latitude winter stratosphere that is not included in presently accepted photochemical schemes. Possible reactions to account for this discrepancy are explored.

Austin, J.

Transport processes and ozone perturbations

Current understanding of stratospheric transport in the meridional plane is reviewed, and the implications of that conceptual framework for the ozone response to chlorofluorocarbon increases are considered. The possibility of seasonal and latitudinal variations in that response is stressed. Calculations of the changes in ozone that may have occurred between the period before widespread chlorofluorocarbon usage and the present day, and the changes that would be expected to occur at steady state for 1980 chlorofluorocarbon production levels, are presented. Finally, some of the uncertainties in the adopted transport framework and its applicability to the evaluation of future perturbations are explored.

Solomon, S.

Transient response to localized episodic heating in the tropics

It is generally recognized that equatorial disturbances in the lower stratosphere are excited by convective latent heat release associated with the Internal Tropical Convergence Zone (ITCZ). Recently, attention has also focused on tropical convection with regard to extratropical teleconnection patterns. Unlike equatorial waves which are trapped about the equator but propagate vertically, the latter extend well out of the tropics but are barotropic. They have been most widely discussed in connection with long-term climatological features. Both types of disturbances have been examined largely from the standpoint of steady monochromatic forcing, in the latter case zero frequency or time-mean heating. However, tropical convection as revealed by recent geostationary satellite imagery is anything but regular, surely not steady. Much of the heating variance is concentrated spatially within three localized convective centers: Indonesia, the Amazon, and the Congo. Convective activity within these regions undergoes an irregular evolution over the span of a couple of days. It involves a rather broad spectrum of spatial and temporal scales. The analysis of cloud brightness over the Eastern Atlantic and Africa suggests a characteristic time scale of 3-4 days and correlations scales in latitude and longitude of approximately 30 deg.

Salby, M. L.

Vacillations induced by interference of stationary and traveling waves

It was shown that there exists a correspondence between interference of the 16-day wave with the stationary planetary wave and vacillations in eddy heat and momentum fluxes. There has been speculation on the role such interference may play in stratospheric warmings. The appearance of higher-order normal modes, e.g., the 16-day wave, prior to disturbances in the stratospheric vortex has also been noted. Since amplitudes of the 16-day wave are compared to those of the stationary component, it can significantly alter the instantaneous total wave field. The behavior of the wave number 1 height field at 60 deg N during January 1979 is shown when a large amplitude disturbance retrogressed barotropically around the globe over much of the troposphere and stratosphere. This transient disturbance has been identified with the 16-day wave. More generally, the presence of fluctuating planetary wave activity can, through combined interference, alter the instantaneous planetary wave field as well as the transports it produces. The implications of such interference in a quasi-geostrophic framework has been explored, using the Eliassen-Palm (EP) flux as a diagnostic.

Salby, M. L.

Assessment models

The types of models used in assessment of possible chemical perturbations to the stratosphere are reviewed. The statue of one and two dimensional models are discussed. The problem of model validation is covered before the status of photochemical modeling efforts is discussed. A hierarchy of tests for photochemical models is presented.

Pyle, J. A.