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Garcia, Hector D.

Publications and source records attributed to Garcia, Hector D..

Got Mercury?

Many of the operational and payload lighting units used in various spacecraft contain elemental mercury. If these devices were damaged on-orbit, elemental mercury could be released into the cabin. Although there are plans to replace operational units with alternate light sources, such as LEDs, that do not contain mercury, mercury-containing lamps efficiently produce high quality illumination and may never be completely replaced on orbit. Therefore, exposure to elemental mercury during spaceflight will remain possible and represents a toxicological hazard. Elemental mercury is a liquid metal that vaporizes slowly at room temperature. However, it may be completely vaporized at the elevated operating temperatures of lamps. Although liquid mercury is not readily absorbed through the skin or digestive tract, mercury vapors are efficiently absorbed through the respiratory tract. Therefore, the amount of mercury in the vapor form must be estimated. For mercury releases from lamps that are not being operated, we utilized a study conducted by the New Jersey Department of Environmental Quality to calculate the amount of mercury vapor expected to form over a 2-week period. For longer missions and for mercury releases occurring when lamps are operating, we conservatively assumed complete volatilization of the available mercury. Because current spacecraft environmental control systems are unable to remove mercury vapors, both short-term and long-term exposures to mercury vapors are possible. Acute exposure to high concentrations of mercury vapors can cause irritation of the respiratory tract and behavioral symptoms, such as irritability and hyperactivity. Chronic exposure can result in damage to the nervous system (tremors, memory loss, insomnia, etc.) and kidneys (proteinurea). Therefore, the JSC Toxicology Group recommends that stringent safety controls and verifications (vibrational testing, etc.) be applied to any hardware that contains elemental mercury that could yield airborne mercury vapor concentrations greater than 0.1 mg/cu m in the total spacecraft atmosphere for exposures lasting 30 days or less or 0.01 mg/cu m mercury vapor for exposures lasting more than 30 days. We also encourage the use of alternative devices that do not contain mercury.

Meyers, Valerie E.↗

JSC Toxicology Web Site

Data on chemical and biological materials to be flown in the pressurized volumes of habitable spacecraft, including the International Space Station (ISS), are needed by JSC toxicologists to assess the toxicity and assign hazard levels. This document defines submission schedules and establishes requirements for the types and format of these data. JSC 27472 Rev A is a major revision of JSC 25607, "Requirements for Submission of Test Sample-Materials Data for Shuttle Payload Safety Evaluations", dated October 1994, which was subsequently re-issued (September 1996) with a new document number, JSC 27472, but with the same title and date and no revisions. The revisions in the present document have been necessitated by the recent introduction of a two-step process (described in this document) for verification of data for flight materials and by the anticipated needs of the ISS. The requirements -for data submission apply to items which contain liquids, gases, gels, greases, powders/ particulates, radioisotopes, or biological materials and are located in the habitable pressurized volume of ISS or U.S. operated spacecraft. These include, but are not limited to, science payloads, government furnished equipment (GFE), risk mitigation experiments (RmEs), development test objectives (DTOs), detailed supplementary objectives (DSOs), life science experiments, and medical studies.

Garcia, Hector D.↗

Setting Spacecraft Maximum Allowable Concentrations for 1 hour or 24 hour contingency exposures to airborne chemicals

Since the early years of the manned space program, NASA has developed and used exposure limits called Spacecraft Maximum Allowable Concentrations (SMACs) to help protect astronauts from airborne toxicants. Most of these SMACS are based on an exposure duration of 7 days, since this is the duration of a 'typical' mission. A set of 'contingency SMACs' is also being developed for scenarios involving brief (1-hour or 24- hour) exposures to relatively high levels of airborne toxicants from event-related 'contingency' releases of contaminants. The emergency nature of contingency exposures dictates the use of different criteria for setting exposure limits. The NASA JSC Toxicology Group recently began a program to document the rationales used to set new SMACs and plans to review the older, 7-day SMACs. In cooperation with the National Research Council's Committee on Toxicology, a standard procedure has been developed for researching, setting, and documenting SMAC values.

Garcia, Hector D.↗