DOE OSTI2015
Lithium-ion batteries are the preferred energy storage devices for portable electronics and are playing an even more important role in large-scale applications, such as electrical vehicles and grid storage. Developing new materials for these demanding applications requires a better understanding of how electrode materials function and why they fail by tracking electrochemical reactions in working electrodes. Many of the currently available synchrotron x-ray techniques are well suited to in-situ studies of structural changes in bulk electrodes, but are limited by spatial resolution. In collaboration with Hummingbird Scientific, we will use their existing liquid-flow holder platform for electrochemistry for simultaneous electron imaging, diffraction and spectroscopy, to perform in situ electrochemical studies. With this configuration of the design, we will be able to make the real time nanoelectrochemistry measurements of the specially designed electrodes in a real battery environment, and study the lithium reaction kinetics of individual nanoparticles. The results will yield new insights into intercalation reactions, and guide the development of new battery electrodes. In addition, the unique approach of studying individual nanoparticles in real time will be broadly applicable to a variety of energy-storage materials, including grid-scale storage.
99 GENERAL AND MISCELLANEOUS↗