Low Ozone Anomalies in the Winter Middle Stratosphere
Microwave Limb Sounder observations of mid-stratospheric ozone during stratospheric warmings show tongues of high ozone drawn up from low latitudes into the developing anticyclone.
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Publications and source records attributed to Froidevaux, L..
Microwave Limb Sounder observations of mid-stratospheric ozone during stratospheric warmings show tongues of high ozone drawn up from low latitudes into the developing anticyclone.
UARS MLS measurements of lower stratospheric CIO during the 1992-93 and 1993-94 Arctic winters are presented.
Satellite observations of ozone and chlorine monoxide in the Arctic lower stratosphere during winter 1992-1993 are compared with observations during other winters, observations of long-lived tracers and the evolution of the polar vortex. Chlorine in the lower stratospheric vortex during February 1993 was mostly in chemically reactive forms.
The first two years of MLS temperature and ozone data are used to examine the tropical upper stratospheric SAO. Time series analysis revealed the strongest amplitudes of the SAO to occur near the equator at 2 mb for temperature and 5 mb for ozone, consistent with previous observations.
This paper describes the validation of ozone data from the Upper Atmosphere Research Satellite (UARS) Microwave Limb Sounder (MLS). The MLS ozone retrievals are obtained from the calibrated microwave radiances (emission spectra) in two separate bands, at frequencies near 205 and 183 GHz.
The severe depletion of stratospheric ozone over Antarctica in late winter and early spring is caused by enhanced CLO abundances arising from heterogeneous reactions on polar stratospheric clouds (PSCs). CLO abundances comparable to those over Antarctica have also been observed throughout the Arctic Vortex, but the accompanying loss of Arctic ozone has been much less severe.
The effect of early winter stratospheric minor warmings on the development of the polar vortex is discussed, for winters since the launch of the Upper Atmosphere Research Satellite (UARS).
The evolution of polar ozone observed by the Upper Atmosphere Research Satellite Microwave Limb Sounder is described for the northern hemisphere (NH) winters of 1991/1992, 1992/1993, and 1993/1994, and the southern hemisphere (SH) winters of 1992 and 1993. Ozone in the mid-stratospheric vortex increases over the winter, with largest increases associated with stratospheric warmings, and a much larger increase in the NH than in the SH.
Global ozone observations from the Microwave Limb Sounder (MLS) aboard the Upper Atmosphere Research Satellite (UARS) are presented, in both vertically resolved and column abundance formats.
Initial results of upper tropospheric water vapor obtained from the Microwave Limb Sounder (MLS) on the Upper Atmosphere Research Satellite (UARS) are presented.
Analysis of Upper Altmosphere Research Satellite (UARS) Microwave Limb Sounder (MLS) observations in early January 1992 shows a clear relationship between predicted polar stratospheric cloud formation along the back trajectory and elevated ClO amounts. These findings are in good agreement with aircraft observations. The MLS observed variation of ClO amounts within the vortex also fits the pattern of ClO change as a result of air parcel solar exposure and nitric acid photolysis. Outside the polar vortex, the occasional highly elevated ClO appear statistically consistent with MLS measurement noise.
Microwave Limb Sounder (MLS) H2O Cryogenic Limb Array Etalon Spectrometer (CLAES) N2O and potential vorticity calculated from UK Meteorological Office data are used to study mid-stratospheric vortex processes in the northern hemisphere winter of 1991-1992. Areas of moist air (at approx. 20 hPa) and N2O-poor air (at approx. 10hPa) are well-correlated with high values of potential vorticity and there is little or no large scale mixing across the vortex edge. We find evidence for the descent of relatively dry mesospheric air to the 840 K (approx. 10 hPa) level, as well as descent of moist air from the upper stratosphere to the 655 K (approx. 20 hPa) level. A reduction in the areas of the vortex and both the moist and H2O-poor regions is observed and there is evidence of moist and N2O-poor air parcels being extruded from the vortex.
The evolution of ozone observed by UARS MLS in the polar regions is shown throughout the stratosphere, focusing on the southern hemisphere winter of 1993.
Variations in ozone and chlorine monoxide observed by the Microwave Limb Sounder (MLS) abroad the Upper Atmosphere Research Satellite (UARS) during the first two years of operation are presented. We focus on mid-latitudes, where significant ozone decreases are observed in the lower stratosphere, and we offer some comparisons with other data sets. We will attempt to place the mid-latitude changes in context with changes observed at other latitudes. Possible correlations between the MLS ozone and CIO observations will be discussed.
UARS MLS measurements of ClO in the 1992 Southern Hemisphere winter are described. Lower stratospheric ClO abundances greater than 1 ppbv were observed in the vortex beginning 1 June. The enhanced ClO reached largest areal extent in mid-August, then retreated poleward. ClO abundances at 22 hPa decreased in early September while those at 46 hPa remained high. O3 decrease within the vortex was observed by mid-August, and was coincident with the enhanced ClO.
The effects of the break-up of the Antarctic vortex on the water vapor distribution are studied using MLS measurements of water vapor made during September 1991 and November 1991. In early November at 22 hPa a moist area is found within the polar vortex, consistent with an observed descent of order 10 km and strong radiative cooling. As the vortex erodes (beginning of November 1991), parcels of moist air become detached from the edge of the vortex and mix rapidly (within 2-3 days) with drier mid-latitude air. When the vortex breaks up (mid-November), larger parcels of moist air from both the edge and the inner vortex migrate to mid-latitudes. These parcels have a longer lifetime than those produced by vortex erosion, probably because they are correlated with higher potential vorticity gradients. The break-up of the vortex is accompanied by a mean adiabatic equatorward transport resulting in a significant increase in midstratospheric water vapor values at mid-latitudes in late spring.
The Microwave Limb Sounder observed waves in stratospheric temperature and O3 during the 1992 southern winter. Wave 1 intensifies three times from mid August through mid September, when a 9 day eastward traveling wave becomes in phase with the stationary wave 1. During the periods of wave intensification, minor sudden warmings and increased zonal mean O3 are observed. The waves have a westward phase tilt which results in an intensified baroclinic zone when the waves are in phase. Waves in T and O3 are positively correlated near 5 - 10 hPa, implying transport by planetary waves; this is supported by larger O3 wave amplitudes than expected from photochemistry alone.
Early in December 1991, high values of ClO are seen by the Microwave Limb Sounder (MLS) on the Upper Atmosphere Research Satellite at latitudes south of areas of temperatures cold enough to form polar stratospheric clouds (PSCs). A 3D simulation shows that the heterogeneous conversion of chlorine reservoirs to reactive chlorine on the surfaces of PSCs (processing) takes place at high latitudes. Often the processed air must be transported to lower latitudes, where the reactive chlorine is photochemically converted to ClO, to be observed by MLS. In this simulation, one incidence of cold temperatures is associated with an anticyclone, and a second with a cyclone. The transport of processed air associated with the anticyclone is marked by shearing; a decrease in the maximum of the processed air is accompanied by growth of the area influenced by the processing. In contrast, the air processed in the cyclonic event spreads more slowly. This shows that transport and shearing is a crucial element to the evolution of reactive chlorine associated with a processing event. In particular, transport and shearing, as well as photochemical processes, can cause variations in observed ClO.