Atomically Precise Fabrication Templated by Hydrogen and Halogen Monolayer Resists
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Butera, Robert↗
Engineering topics
Frederick, Esther
Publications and source records attributed to Frederick, Esther.
Deprotonation of phenol linked to a silicon dioxide surface using adaptive feedback laser control with a heterodyne detected sum frequency generation signal
Phenol molecules bound to a silicon dioxide surface where the hydroxyl group undergoes deprotonation under the action of the shaped optical pulse.
Goun, Alexei↗
Area-Selective Atomic Layer Deposition Templated by Atomic Precision Fabrication.
Abstract not provided.
Frederick, Esther↗
Synthesis and Mechanical Properties of sub 5‐μm PolyUiO‐66 Thin Films on Gold Surfaces
Abstract Metal‐organic framework (MOF) thin films currently lack the mechanical stability needed for electronic device applications. Polymer‐based metal‐organic frameworks (polyMOFs) have been suggested to provide mechanical advantages over MOFs, however, the mechanical properties of polyMOFs have not yet been characterized. In this work, we developed a method to synthesize continuous sub‐5 μm polyUiO‐66(Zr) films on Au substrates, which allowed us to undertake initial mechanical property investigations. Comparisons between polyUiO‐66 and UiO‐66 thin films determined polyUiO‐66 thin films exhibit a lower modulus but similar hardness to UiO‐66 thin films. The initial mechanical characterization indicates that further development is needed to leverage the mechanical property advantages of polyMOFs over MOFs. Additionally, the demonstration in this work of a continuous surface‐supported polyUiO‐66 thin film enables utilization of this emerging class of polyMOF materials in sensors and devices applications.
Frederick, Esther↗
Reaction of Dichlorophenylborane with H–Si(100)
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗