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Fernandez-Pello, A. C.

Publications and source records attributed to Fernandez-Pello, A. C..

Piloted Ignition to Flaming in Smoldering Fire-Retarded Polyurethane Foam

Experimental results are presented on the piloted transition from smoldering to flaming in the fire-retarded polyurethane foam Pyrell . The samples are small rectangular blocks with a square cross section, vertically placed in the wall of a vertical wind tunnel. Three of the vertical sample sides are insulated and the fourth side is exposed to an upward oxidizer flow of variable oxygen concentration and to a variable radiant heat flux. The gases emitted from the smoldering reaction pass upwards through a pilot, which consists of a coiled resistance heating wire. In order to compensate for the solid-phase and gas-phase effects of the fire retardants on the piloted transition from smoldering to flaming in Pyrell, it was necessary to assist the process by increasing the power supplied to the smolder igniter and the pilot (compared to that used for non-fire retarded foam). The experiments indicate that the piloted transition from smoldering to flaming occurs when the gaseous mixture at the pilot passes the lean flammability limit. It was found that increasing the oxygen concentration or the external heat flux increases the likelihood of a piloted transition from smoldering to flaming, and generally decreases the time delay to transition. The piloted transition to flaming is observed in oxygen concentrations of 23% and above in both low-density and high-density Pyrell. Comparisons with previous experiments show that the piloted transition from smoldering to flaming is possible under a wider range of external conditions (i.e. lower oxygen concentration) than the spontaneous transition from smoldering to flaming. The results show that the fire retardants in Pyrell are very effective in preventing the piloted transition to flaming in normal air, but Pyrell is susceptible to smoldering and the piloted transition to flaming in oxygen-enriched environments. Therefore, precautions should be taken in the design of applications of Pyrell in oxygen-enriched environments to reduce to the risk of a piloted transition to flaming.

Putzeys, O.

Effects of Heat Flux, Oxygen Concentration and Glass Fiber Volume Fraction on Pyrolysate Mass Flux from Composite Solids

Experimental work on the effects of heat flux, oxygen concentration and glass fiber volume fraction on pyrolysate mass flux from samples of polypropylene/glass fiber composite (PP/G) is underway. The research is conducted as part of a larger project to develop a test methodology for flammability of materials, particularly composites, in the microgravity and variable oxygen concentration environment of spacecraft and space structures. Samples of PP/G sized at 30 x 30 x 10 mm are flush mounted in a flow tunnel, which provides a flow of oxidizer over the surface of the samples at a fixed value of 1 m/s and oxygen concentrations varying between 18 and 30%. Each sample is exposed to a constant external radiant heat flux at a given value, which varies between tests from 10 to 24 kW/sq m. Continuous sample mass loss and surface temperature measurements are recorded for each test. Some tests are conducted with an igniter and some are not. In the former case, the research goal is to quantify the critical mass flux at ignition for the various environmental and material conditions described above. The later case generates a wider range of mass flux rates than those seen prior to ignition, providing an opportunity to examine the protective effects of blowing on oxidative pyrolysis and heating of the surface. Graphs of surface temperature and sample mass loss vs. time for samples of 30% PPG at oxygen concentrations of 18 and 21% are presented in the figures below. These figures give a clear indication of the lower pyrolysis rate and extended time to ignition that accompany a lower oxygen concentration. Analysis of the mass flux rate at the time of ignition gives good repeatability but requires further work to provide a clear indication of mass flux trends accompanying changes in environmental and material properties.

Rich, D. B.

Transition from Forward Smoldering to Flaming in Small Polyurethane Foam Samples

Experimental observations are presented of the effect of the flow velocity and oxygen concentration, and of a thermal radiant flux, on the transition from smoldering to flaming in forward smoldering of small samples of polyurethane foam with a gas/solid interface. The experiments are part of a project studying the transition from smolder to flaming under conditions encountered in spacecraft facilities, i.e., microgravity, low velocity variable oxygen concentration flows. Because the microgravity experiments are planned for the International Space Station, the foam samples had to be limited in size for safety and launch mass reasons. The feasible sample size is too small for smolder to self propagate because of heat losses to the surrounding environment. Thus, the smolder propagation and the transition to flaming had to be assisted by reducing the heat losses to the surroundings and increasing the oxygen concentration. The experiments are conducted with small parallelepiped samples vertically placed in a wind tunnel. Three of the sample lateral-sides are maintained at elevated temperature and the fourth side is exposed to an upward flow and to a radiant flux. It is found that decreasing the flow velocity and increasing its oxygen concentration, and/or increasing the radiant flux enhances the transition to flaming, and reduces the delay time to transition. Limiting external ambient conditions for the transition to flaming are reported for the present experimental set-up. The results show that smolder propagation and the transition to flaming can occur in relatively small fuel samples if the external conditions are appropriate. The results also indicate that transition to flaming occurs in the char left behind by the smolder reaction, and it has the characteristics of a gas-phase ignition induced by the smolder reaction, which acts as the source of both gaseous fuel and heat.

Bar-Ilan, A.

Effects of Heat Flux, Oxygen Concentration and Glass Fiber Volume Fraction on Pyrolysate Mass Flux from Composite Solids

Experimental work on the effects of heat flux, oxygen concentration and glass fiber volume fraction on pyrolysate mass flux from samples of polypropylene/glass fiber composite (PP/G) is underway. The research is conducted as part of a larger project to develop a test methodology for flammability of materials, particularly composites, in the microgravity and variable oxygen concentration environment of spacecraft and space structures. Samples of PP/G sized at 30x30x10 mm are flush mounted in a flow tunnel, which provides a flow of oxidizer over the surface of the samples at a fixed value of 1 m/s and oxygen concentrations varying between 18 and 30%. Each sample is exposed to a constant external radiant heat flux at a given value, which varies between tests from 10 to 24 kW/m2. Continuous sample mass loss and surface temperature measurements are recorded for each test. Some tests are conducted with an igniter and some are not. In the former case, the research goal is to quantify the critical mass flux at ignition for the various environmental and material conditions described above. The later case generates a wider range of mass flux rates than those seen prior to ignition, providing an opportunity to examine the protective effects of blowing on oxidative pyrolysis and heating of the surface. Graphs of surface temperature and sample mass loss vs. time for samples of 30% PPG at oxygen concentrations of 18 and 21% are presented in the figures below. These figures give a clear indication of the lower pyrolysis rate and extended time to ignition that accompany a lower oxygen concentration. Analysis of the mass flux rate at the time of ignition gives good repeatability but requires further work to provide a clear indication of mass flux trends accompanying changes in environmental and material properties.

Rich, D. B.

Forced Forward Smoldering Experiments Aboard The Space Shuttle

Smoldering is a basic combustion problem that presents a fire risk because it is initiated at low temperatures and because the reaction can propagate slowly in the material interior and go undetected for long periods of time. It yields a higher conversion of fuel to toxic compounds than does flaming, and may undergo a transition to flaming. To date there have been a few minor incidents of overheated and charred cables and electrical components reported on Space Shuttle flights. With the establishment of the International Space Station, and the planning of a potential manned mission to Mars, there has been an increased interest in the study of smoldering in microgravity. The Microgravity Smoldering Combustion (MSC) experiment is part of a study of the smolder characteristics of porous combustible materials in a spacecraft environment. The aim of the experiment is to provide a better fundamental understanding of the controlling mechanisms of smoldering combustion under normal- and microgravity conditions. This in turn will aid in the prevention and control of smolder originated fires, both on earth and in spacecrafts. The microgravity smoldering experiments have to be conducted in a space-based facility because smoldering is a very slow process and consequently its study in a microgravity environment requires extended periods of time. The microgravity experiments reported here were conducted aboard the Space Shuttle. The most recent tests were conducted during the STS-105 and STS-108 missions. The results of the forward smolder experiments from these flights are reported here. In forward smolder, the reaction front propagates in the same direction as the oxidizer flow. The heat released by the heterogeneous oxidation reaction is transferred ahead of the reaction heating the unreacted fuel. The resulting increase of the virgin fuel temperature leads to the onset of the smolder reaction, and propagates through the fuel. The MSC data are compared with normal gravity data to determine the effect of gravity on smolder.

Fernandez-Pello, A. C.

Piloted Ignition of Polypropylene/Glass Composites in a Forced Air Flow

The Forced Ignition and Spread Test (FIST) is being used to study the flammability characteristics of combustible materials in forced convective flows. The FIST methodology is based on the ASTM E-1321, Lateral Ignition and Flame Spread Test (LIFT) which is used to determine the ignition and flame spread characteristics of materials, and to produce 'Flammability Diagrams' of materials. The LIFT apparatus, however, relies on natural convection to bring air to the combustion zone and the fuel vapor to the pilot flame, and thus cannot describe conditions where the oxidizer flow velocity may change. The FIST on the other hand, by relying on a forced flow as the dominant transport mechanism, can be used to examine variable oxidizer flow characteristics, such as velocity, oxygen concentration, and turbulence intensity, and consequently has a wider applicability. Particularly important is its ability to determine the flammability characteristics of materials used in spacecraft since in the absence of gravity the only flow present is that forced by the HVAC of the space facility. In this paper, we report work on the use of the FIST approach on the piloted ignition of a blended polypropylene fiberglass (PP/GL) composite material exposed to an external radiant flux in a forced convective flow of air. The effect of glass concentration under varying external radiant fluxes is examined and compared qualitatively with theoretical predictions of the ignition process. The results are used to infer the effect of glass content on the fire safety characteristics of composites.

Fernandez-Pello, A. C.

Smoldering, Transition and Flaming in Microgravity

A research project is underway to study smolder and the transition to flaming in microgravity. The Microgravity Smoldering Combustion (MSC) flight project is an ongoing research project to provide a better understanding of the controlling mechanisms of smoldering combustion. The Smoldering Transition and Flaming (STAF) project is a recently established research program that will utilize the Fluids and Combustion Facility (FCF) of the ISS to examine the transition from smolder to flaming in microgravity. In forced flow smolder experiments ambient pressure in the MSC chamber rises, thus motivating the need to understand the effects of pressure on smoldering combustion. Further, the STAF experiment has constraints on experimental scale and testing at elevated pressure may be a mechanism to reduce the sample size by enhancing the smolder reaction. In the work we are reporting here, a series of ground-based tests determine the effects of pressure on smoldering combustion. These tests are compared with data obtained from experiments conducted aboard the Space Shuttle in flights STS-69 and STS-77. Measurements of one-dimensional smolder propagation velocity are made by thermocouple probing and a non-intrusive Ultrasound Imaging System (UIS)]. Thermocouples are also used to obtain reaction temperatures and the UIS is used to determine permeabilities of the fuel in real-time.

Fernandez-Pello, A. C.

Theoretical Prediction of Microgravity Ignition Delay of Polymeric Fuels in Low Velocity Flows

A new flammability apparatus and protocol, FIST (Forced Flow Ignition and Flame Spread Test), is under development. Based on the LIFT (Lateral Ignition and Flame Spread Test) protocol, FIST better reflects the environments expected in spacebased facilities. The final objective of the FIST research is to provide NASA with a test methodology that complements the existing protocol and provides a more comprehensive assessment of material flammability of practical materials for space applications. Theoretical modeling, an extensive normal gravity data bank and a few validation space experiments will support the testing methodology. The objective of the work presented here is to predict the ignition delay and critical heat flux for ignition of solid fuels in microgravity at airflow velocities below those induced in normal gravity. This is achieved through the application of a numerical model previously developed of piloted ignition of solid polymeric materials exposed to an external radiant heat flux. The model predictions will provide quantitative results about ignition of practical materials in the limiting conditions expected in space facilities. Experimental data of surface temperature histories and ignition delay obtained in the KC-135 aircraft are used to determine the critical pyrolysate mass flux for ignition and this value is subsequently used to predict the ignition delay and the critical heat flux for ignition of the material. Surface temperature and piloted ignition delay calculations for Polymethylmethacrylate (PMMA) and a Polypropylene/Fiberglass (PP/GL) composite were conducted under both reduced and normal gravity conditions. It was found that ignition delay times are significantly shorter at velocities below those induced by natural convection.

Fernandez-Pello, A. C.

Flow Effects on the Flammability Diagrams of Solid Fuels: Microgravity Influence on Ignition Delay

The possibility of an accidental fire in space-based facilities is a primary concern of space exploration programs. Spacecraft environments generally present low velocity air currents produced by ventilation and heating systems (of the order of 0.1 m/s), and fluctuating oxygen concentrations around that of air due to CO2 removal systems. Recent experiments of flame spread in microgravity show the spread rate to be faster and the limiting oxygen concentration lower than in normal-gravity. To date, there is not a material flammability-testing protocol that specifically addresses issues related to microgravity conditions. The present project (FIST) aims to establish a testing methodology that is suitable for the specific conditions of reduced gravity. The concepts underlying the operation of the LIFT apparatus, ASTM-E 1321-93, have been used to develop the Forced-flow Ignition and flame-Spread Test (FIST). As in the LIFT, the FIST is used to obtain the flammability diagrams of the material, i.e., graphs of ignition delay time and flame spread rate as a function of the externally applied radiant flux, but under forced flow rather than natural convection conditions, and for different oxygen concentrations. Although the flammability diagrams are similar, the flammability properties obtained with the FIST are found to depend on the flow characteristics. A research program is currently underway with the purpose of implementing the FIST as a protocol to characterize the flammability performance of solid materials to be used in microgravity facilities. To this point, tests have been performed with the FIST apparatus in both normal-gravity and microgravity conditions to determine the effects of oxidizer flow characteristics on the flammability diagrams of polymethylmethacrylate (PMMA) fuel samples. The experiments are conducted at reduced gravity in a KC- 135 aircraft following a parabolic flight trajectory that provides up to 25 seconds of low gravity. The objective of the experiments is to obtain data of ignition delay and flame spread rate at low flow velocities (0.1 to 0.2 m/s), which cannot be obtained under normal gravity because of the natural convection induced flows (approx. 0.5 m/s). Due to the limited reduced gravity time, the data can only be obtained for high radiant fluxes, and are consequently limited in scope. These tests do, however, provide insight into the flammability diagram characteristics at low velocity and reduced gravity, and also into the implications of the flow-dependence of the flammability properties under environments similar to those encountered in space facilities.

Cordova, J. L.

Observations from the Microgravity Smoldering Combustion (MSC) Ultrasound Imaging System (UIS)

The Microgravity Smoldering Combustion (MSC) experiment is a study of the smolder characteristics of porous combustible materials in a microgravity environment. The objective of the study is to provide a better understanding of the controlling mechanisms of smolder, both in microgravity and normal earth gravity. Experiments have been conducted aboard the NASA Space Shuttle in the GAS-CAN, an apparatus requiring completely remote operation. Future GAS-CAN experiments will utilize an ultrasound imaging system (UIS). Thermocouples are currently used to measure temperature and reaction front velocities, but a less intrusive method is desirable, as smolder is affected by heat transfer along the thermocouple. It is expected that the UIS will eventually replace the existing array of thermocouples as a non-intrusive technique without compromising data acquisition. Smoldering is defined as a non-flaming, self-sustaining, propagating, exothermic, surface reaction, deriving its principal heat from heterogeneous oxidation of the fuel. Smolder of cable insulation is of particular concern in the space program; to date there have been a few minor incidents of overheated and charred cables and electrical components reported on Space Shuttle flights. Recently, the establishment of the International Space Station and other space facilities has increased interest in the study of smoldering in microgravity because of the need to preempt the possibility, and/or to minimize the effect of a smolder initiated fire during the operation of these facilities. The ignition and propagation of smolder are examined using both thermocouples and the UIS. The UIS has been implemented into the MSC flight hardware. The system provides information about local permeability variations within a smoldering sample, which can, in turn, be interpreted to track the propagation of the smolder reaction. The method utilizes the observation that transmission of an ultrasonic signal through a porous material increases with increasing permeability. Since a propagating smolder reaction leaves behind a char that is higher in permeability than the original (unburnt) material, ultrasonic transmission can be employed to monitor the progress of the primary reaction front, char evolution (i.e. material left by the smolder reaction), pyrolysis, and condensation fronts.

Walther, D.C.

Flow Effects on the Flammability Diagrams of Solid Fuels

A research program is currently underway with the final objective of developing a fundamental understanding of the controlling mechanisms underlying the flammability diagrams of solid combustible materials and their derived fire properties. Given that there is a high possibility of an accidental fire occurring in a space-based facility, understanding the fire properties of materials that will be used in such facilities is of critical importance. With this purpose, the flammability diagrams of the materials, as those produced by the Lateral Ignition and Flame Spread Test (LIFT) apparatus and by a new forced flow device, the Forced Flow Ignition and Flame Spread Test (FIST) apparatus, will be obtained. The specific objective of the program is to apply the new flammability apparatus, which will more accurately reflect the potential ambient conditions of space-based environments, to the characterization of the materials for space applications. This paper presents a parametric study of oxidizer flow effects on the ignition curve of the flammability diagrams of PMMA. The dependence of the ignition delay time on the external radiant flux and either the sample width (LIFT) or the flow velocity (FIST) has been studied. Although preliminary, the results indicate that natural and forced convection flow changes, affect the characteristics of the ignition curves of the flammability diagrams. The major effect on the ignition time appears to be due to convective transfer variations at the fuel surface. At high radiant fluxes or high flow velocities, however, it appears that gas phase processes become increasingly important, affecting the overall ignition delay time. A numerical analysis of the solid fuel heating and pyrolysis has also been developed. The theoretical predictions approximate the experiments well for conditions in which the gas phase induction time is negligible.

Cordova, J. L.

Experimental observations of the effect of gravity changes on smoldering combustion

An experimental study is conducted to determine the effect of gravity changes on the natural convection smolder characteristics of flexible polyurethane foam. Gravity, and consequently buoyancy, is expected to affect smoldering because it induces convective transport of mass and heat to and from the reaction zone. The overall objective of the work is to provide information about the potential onset of a smolder-initiated fire in a space-based facility. Experiments are conducted in an aircraft following parabolic trajectories that provide up to 25 s of low gravity (KC-135A) and up to 20 s (Learjet Model 25), with a pull-up and pull-out of approximately 2 g per parabola. Measurements are performed, during a series of parabolas, of the temperature histories of the polyurethane foam at several locations along the fuel sample interior, both for upward and downward propagation. The measurements show that gravity plays a significant role in the competition between the supply of oxidizer to, and the transfer of heat to and from, the reaction zone.

Torero, J. L.

Experimental Observations of the Effect of Gravity Changes on Smoldering Combustion

The effects of gravity changes on the natural convection smolder characteristics of flexible polyurethane foam were determined in order to provide information on the potential onset of a smolder-initiated fire in a space-based facility. Experiments were conducted in an aircraft following parabolic trajectories providing up to 25 seconds of low gravity. Temperature histories of polyurethane foam were measured at several locations along the fuel sample interior. Results are presented and discussed for both upward and downward smoldering. Results indicate that gravity significantly effects the competition between supply of oxidizer to, and the transfer of heat to and from the reaction zone. This competition determines the characteristics of the smolder reaction. Within the reaction zone the reduction in oxygen supply in low gravity is dominant and the reaction weakens. Away from the reaction zone the reduction in convective cooling at low gravity tends to increase the material temperature. The opposite was observed at high gravity.

Torero, J. L.

Gravitational Effects on Cellular Flame Structure

An experimental investigation has been conducted of the effect of gravity on the structure of downwardly propagating, cellular premixed propane-oxygen-nitrogen flames anchored on a water-cooled porous-plug burner. The flame is subjected to microgravity conditions in the NASA Lewis 2.2-second drop tower, and flame characteristics are recorded on high-speed film. These are compared to flames at normal gravity conditions with the same equivalence ratio, dilution index, mixture flow rate, and ambient pressure. The results show that the cellular instability band, which is located in the rich mixture region, changes little under the absence of gravity. Lifted normal-gravity flames near the cellular/lifted limits, however, are observed to become cellular when gravity is reduced. Observations of a transient cell growth period following ignition point to heat loss as being an important mechanism in the overall flame stability, dominating the stabilizing effect of buoyancy for these downwardly-propagating burner-anchored flames. The pulsations that are observed in the plume and diffusion flame generated downstream of the premixed flame in the fuel rich cases disappear in microgravity, verifying that these fluctuations are gravity related.

Dunsky, C. M.

Buoyancy effects on smoldering combustion

The effect of buoyancy on the rate of spread of a concurrent smolder reaction through a porous combustible material is investigated theoretically and experimentally. In the experiments, buoyant forces are controlled by varying the density difference, and the smolder rate spread through porous alpha cellulose (0.83 void fraction) is measured as a function of the ambient air pressure. The smolder velocity is found to increase with the ambient pressure; extinction occurs when the buoyancy forces cannot overcome the drag forces, indicating that diffusion by itself cannot support the spread of a smolder reaction. Theoretical predictions are found to be in good qualitative agreement with the experimental results.

Dosanjh, S.

A Fundamental Study of Smoldering with Emphasis on Experimental Design for Zero-G

The objective of this section of the microgravity project is to identify key sets of low-gravity experiments which would critically compliment a larger set of more easily performed normal-gravity experiments to explain the phenomena found in smoldering combustion. It is planned to follow through on the conceptual design of these experiments by participating in the future in the fabrication of the refined apparatus and in the data collection and interpretation. Low-gravity experiments are appropriate for smoldering combustion because of the complexity of smoldering which requires every means possible to discriminate among the many chemical and physical mechanisms active in most smoldering combustion scenarios. Efforts will be primarily analytical, attempting to identify appropriate approximations and dominant dimensionless groups based on existing data and state-of-the-art combustion modelling. Transient stability questions such as ignition, extinction and the choices among charring, tarring, or flaming modes will be included.

Pagni, P. J.