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Feng, Z.

Publications and source records attributed to Feng, Z..

9 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Electronegativity-Guided Site Differentiation in High-Entropy Alloy for pH-universal Hydrogen Evolution Reactions

Enhancing the intrinsic activity of transition metal catalysts for the hydrogen evolution reaction (HER) remains a critical challenge in sustainable energy conversion. Herein, we report an electronegativity-guided site differentiation strategy in a single-phase CoNiCuMoW high-entropy alloy (HEA) via electrodeposition by incorporating high-electronegativity 4d/5d orbital transition metals (Mo, W) into the face-centered cubic (fcc) matrix (CoNiCu). The as-synthesized HEA demonstrates exceptional HER performance in all pH conditions, delivering an outstanding overpotential of 65 mV (alkaline), 28 mV (acidic), and 155 mV (neutral) at a current density of 100 mA cm−2, showing performance comparable to commercial Pt/C and has excellent long-term stability at high current density (1 A cm−2, 1000 h). X-Ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations reveal that the incorporation of Mo/W simultaneously alters the local coordination environment and induces element-dependent charge redistribution, accompanied by a system-level d-band center downshift, thereby optimizing the hydrogen binding strength across multimetallic sites. Meanwhile, oxophilic Mo/W sites lower the water dissociation energy barrier. These synergistic effects collectively enable efficient and durable pH-universal HER performance.

Wu, Yutong↗
DOE OSTI2023

Using in-situ strain measurements to evaluate the accuracy of stress estimation procedures from fracture injection/shut-in tests

Fracture injection/shut-in tests are commonly used to measure the state of stress. Injection creates a hydraulic fracture (or in some cases, opens a preexisting fracture), and then the pressure after shut-in is monitored to identify fracture closure. Different interpretation procedures have been proposed for estimating closure, and the procedures sometimes yield significantly different results. In this study, direct, in-situ strain measurements are used to observe fracture reopening and closure. The tests were performed as part of the EGS Collab project, a mesoscale project performed at 1.25 and 1.5 km depth at the Sanford Underground Research Facility. The tests were instrumented with the SIMFIP tool, a double-packer probe with a high-resolution three-dimensional borehole displacement sensor. The measurements provide a direct observation of the fracture closure signature, enabling a high-fidelity estimate of the fracture closure stress (ie, the normal stress on the fracture). In two of the four tests, injection created an opening mode fracture, and so the closure stress can be interpreted as the minimum principal stress. In the other two tests, injection probably opened preexisting natural fractures, and so the closure stress can be interpreted as the normal stress on the fractures. The strain measurements are compared against different proposed methods for estimating closure stress from pressure transients. The shut-in transients are analyzed with two techniques that are widely used in the field of petroleum engineering – the ‘tangent’ method and the ‘compliance’ method. In three of the four tests, the tangent method significantly underestimates the closure stress. The compliance method is reasonably accurate in all four tests. Closure stress is also interpreted using two other commonly-used methods – ‘first deviation from linearity’ and the method of Hayashi and Haimson. In comparison with the SIMFIP data, these methods tend to overestimate the closure stress, evidently because they identify closure from early-time transient effects, such as near-wellbore tortuosity. In two of the tests, microseismic imaging provides an independent estimate of the size of the fracture created by injection. When combined with a simple mass balance calculation, the SIMFIP stress measurements yield predictions of fracture size that are reasonably consistent with the estimates from microseismic. In conclusion, the calculations imply an apparent fracture toughness 2-3x higher than typical laboratory-derived values.

58 GEOSCIENCES↗
DOE OSTI2021

Constraining maximum event magnitude during injection-triggered seismicity

Abstract Understanding mechanisms controlling fluid injection-triggered seismicity is key in defining strategies to ameliorate it. Recent triggered events (e.g. Pohang, Mw 5.5) have exceeded predictions of average energy release by a factor of >1000x, necessitating robust methodologies to both define critical antecedent conditions and to thereby constrain anticipated event size. We define maximum event magnitudes resulting from triggering as a function of pre-existing critical stresses and fluid injection volume. Fluid injection experiments on prestressed laboratory faults confirm these estimates of triggered moment magnitudes for varied boundary conditions and injection rates. In addition, observed ratios of shear slip to dilation rates on individual faults signal triggering and may serve as a measurable proxy for impending rupture. This new framework provides a robust method of constraining maximum event size for preloaded faults and unifies prior laboratory and field observations that span sixteen decades in injection volume and four decades in length scale.

58 GEOSCIENCES↗
DOE OSTI2020

The ongoing need for high-resolution regional climate models: Process understanding and stakeholder information

Regional climate modeling addresses our need to understand and simulate climatic processes and phenomena unresolved in global models. High resolution models are generally more skillful in simulating extremes, such as heavy precipitation, strong winds, and severe storms. In addition, research has shown that fine-scale features such as mountains, coastlines, lakes, irrigation, land use, and urban heat islands can substantially influence a region’s climate and its response to changing forcings. Regional climate simulations explicitly simulating convection are now being performed, providing an opportunity to illuminate new physical behavior that previously was represented by parameterizations with large uncertainties. Regional and global models are both advancing toward higher resolution, as computational capacity increases. However, the resolution and ensemble size necessary to produce a sufficient statistical sample of these processes in global models has proven too costly for contemporary supercomputing systems. Regional climate models are thus indispensable tools that complement global models for understanding regional climate variability and change, and are critical for supporting societal responses to changing climate.

Gutowski, William↗
NASA NTRS1985

The atmospheric heat budget over the western part of the Tibetan plateau during MONEX, 1979

The heat sources over the western part of the Tibetan Plateau for the period from May 19-August 31, 1979 are calculated. The use of the direct method to compute the total atmospheric heat source is examined. The values for the heat source over western, northwestern, and southwestern Tibet are presented. It is concluded that the atmospheric heat source is smaller during the summer than had been previously estimated; this difference is due to reduced drag coefficients. The northwestern and southwestern heat source values are compared, and it is observed that the northwestern heat source is independent on sensible heating and the southwestern heat source relates to the latent heat (LH). The calculated values correlate with the surface hydrology of these two regions. Time series analyses of the heat source components over the southwestern region reveal that LH is the primary modulator of the total atmospheric heat sources. The relation between the vertical heat distribution and Indian summer monsoons is studied.

Feng, Z.↗
NASA NTRS1985

The atmospheric heat source over the Tibetan plateau May-August 1979

Estimates of the time and space variability of the atmospheric heat source over Tibet are presented for the summer of 1979. These estimates rely on new data from the People's Republic of China allowing a better assessment of the surface heat fluxes, and on new satellite data from Nimbus-7 giving the radiation balance at the top of the atmosphere. The estimates of the atmospheric heat source turned out to be considerably smaller than those provided earlier in the literature, mainly because of different assumptions of the drag coefficient. The atmospheric heat source over Tibet is mainly modulated by the release of latent heat. Over the southeastern and southwestern plateau regions the heat source appears to be in phase with the precipitation yield of the Indian summer monsoon, whereas central Tibet reveals an out-of-phase behavior. Over western Tibet there appears to be hardly any net import of moisture from outside the region, whereas the maintenance of the hydrological cycle over eastern Tibet requires moisture flux convergence from outside the region of up to 40 percent of the mean rainfall, in agreement with what is known about the surface hydrology of Tibet.

Chen, L.↗
NASA NTRS1985

A rotating superconducting solenoid for 100 kWh energy storage

Two concentric superconducting solenoids, one rotating, the other stationary are analyzed for energy storage in space. Energy is transferred from the rotating mass through a shaft coupled to a motor-generator. The inner windings interact with the magnetic field of the outer solenoid to cancel the centrifugal and self-field forces of the flywheel rim. Current is induced in the inner solenoid thus requiring no separate power supply, while the current in the outer solenoid must vary with the angular velocity of the flywheel. The effect of the gap and scaling laws are developed. The efficiency in energy per unit mass is marginally attractive.

Waynert, J.↗