Halogentated species
Stratospheric measurements of halogen containing species are reviewed and compared with model predictions. Halocarbons, HCl, HF, ClONO2, and ClO are discussed.
Molina, M. J.↗
Engineering topics
Farmer, C. B.
Publications and source records attributed to Farmer, C. B..
Instrument intercomparisons and assessments
Over the past few years, several field campaigns were devoted to the goal of assessing instrument reliability, as opposed to solely obtaining data to answer a geophysical question. Some examples of the formal instrument intercomparisons that have occurred in the past decade and those that are planned for the very near future are listed chronologically. Balloon-borne techniques and instruments that address the height profiles of the trace species in the lower stratosphere are emphasized. Beginning with the most extensively studied trace constituent, the approach taken and the results obtained, are described. The current status of the measurement capabilities are summarized, and the needs for future intercomparisons and assessments are listed.
Albritton, D. L.↗
Effects of systematic errors on the mixing ratios of trace gases obtained from occultation spectra
The influence of systematic errors in the parameters of the models describing the geometry and the atmosphere on the profiles of trace gases retrieved from simulated solar occultation spectra, collected at satellite altitudes, is investigated. Because of smearing effects and other uncertainties, it may be preferable to calibrate the spectra internally by measuring absorption lines of an atmospheric gas such as CO2 whose vertical distribution is assumed rather than to rely on externally supplied information.
Shaffer, W. A.↗
Effects of systematic errors on the mixing ratios of trace gases obtained from occulation spectra
The influence of systematic errors in the parameters of the models describing the geometry and the atmosphere on the profiles of trace gases retrieved from simulated solar occultation spectra, collected at satellite altitudes, is investigated. Because of smearing effects and other uncertainties, it may be preferable to calibrate the spectra internally by measuring absorption lines of an atmospheric gas such as CO2 whose vertical distribution is assumed rather than to relay on externally supplied information.
Shaffer, W. A.↗
Atmospheric trace molecule spectroscopy
The Spacelab investigation entitled Atmospheric Trace Molecule Spectroscopy (ATMOS) is designed to obtain fundamental information related to the chemistry and physics of the Earth's upper atmosphere using the techniques of infrared absorption spectroscopy. There are two principal objectives to be met. The first is the determination, on a global scale, of the compositional structure of the upper atmosphere and its spatial variability. The establishment of this variability represents the first step toward determining the characteristic residence times for the upper atmospheric constituents; the magnitudes of their sources and sinks; and, ultimately, an understanding of their effects on the stability of the stratosphere. The second objective is to provide the high-resolution, calibrated spectral information which is essential for the detailed design of advanced instrumentation for subsequent global monitoring of specific species found to be critical to atmospheric stability. This information will be disseminated in the form of a three dimensional atlas of solar absorption spectra obtained over a range of latitudes, longitudes, and altitudes.
Farmer, C. B.↗
The seasonal and global behavior of water vapor in the Mars atmosphere - Complete global results of the Viking atmospheric water detector experiment
A key question regarding the evolution of Mars is related to the behavior of its volatiles. The present investigation is concerned with the global and seasonal abundances of water vapor in the Mars atmosphere as mapped by the Viking Mars Atmospheric Water Detector (MAWD) instrument for almost 1-1/2 Martian years from June 1976 to April 1979. Attention is given to the implications of the observed variations for determining the relative importance of those processes which may be controlling the vapor cycle on a seasonal basis. The processes considered include buffering of the atmosphere water by a surface or subsurface reservior of ground ice, physically adsorbed water, or chemically bound water. Other processes are related to the supply of water from the residual or seasonal north polar ice cap, the redistribution of the vapor resulting from atmospheric circulation, and control of the vapor holding capacity of the atmosphere by the local atmospheric temperatures.
Jakosky, B. M.↗
Stratospheric measurements of continuous absorption near 2400 per cm
Measurements of continuous absorption near 2400 per cm by N2 and CO2 over long path lengths in the lower stratosphere are presented. The continua were measured in a stratospheric solar spectrum obtained during sunset with a balloon-borne Michelson interferometer in the 2380-2500 per cm region, and transmittances were calculated by ratioing the amplitudes to those of a high-sun spectrum in order to eliminate the wavelength dependence of the measured flux. Comparison of the measured transmittances with those calculated for a multilayered atmospheric model using laboratory absorption measurements results in a fair agreement, and reveals the primary component of the absorption throughout most of the range to be N2, with the CO2 contribution equal to that of N2 only at the CO2 band head. In this region, the shape of the continuum is very sensitive to the sub-Lorentzian line shape assumed in the calculations, and so, if the shape of the N2 continuum at low temperatures can be determined through laboratory measurements, may be used to infer air-broadened far-wing CO2 line shape.
Rinsland, C. P.↗
Simultaneous spectroscopic measurements of stratospheric species - O3, CH4, CO, CO2, N2O, H2O, HCl, and HF at northern and southern mid-latitudes
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Farmer, C. B.↗
Near- and mid-infrared spectroscopy of the upper atmosphere
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Farmer, C. B.↗
Atmospheric Trace Molecule Spectroscopy (ATMOS)
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Farmer, C. B.↗
Global exchange of water vapor on Mars
Observations of the global distribution and seasonal variation of the Martian atmospheric water vapor have been made from the Viking orbiters for a continuous period covering more than half of a Martian year. The seasonal dependence of the latitude distribution of the column abundance of vapor is consistent with a model in which the vapor is in equilibrium with the regolith at polar and middle latitudes. The results indicate the existence of a permanent reservoir of water ice buried at a depth of 10 cm to 1 meter at all latitudes poleward of 40 deg. The behavior of the vapor in the summer hemisphere suggests an annual net transport of the vapor phase from the southern to the northern hemisphere, with deposition of ice of thickness on the order of a few milligrams per sq cm at northern polar latitudes. The hemispheric asymmetry is the result of the propagation of global dust storms originating in the south.
Farmer, C. B.↗
The HF:HCl ratio in the 14-38 km region of the stratosphere
A balloon-borne high resolution Michelson interferometer recorded near infrared absorption spectra of the 1-0 fundamental vibration bands of HF and HCl in the stratosphere over Australia in March 1977. The ratio of the number density of HF to that of HCl as a function of stratospheric height was deduced from the measurements. Within estimated experimental error, the ratio is constant, its mean value being 0.1.
Farmer, C. B.↗
The vertical distribution of HCl in the stratosphere
The vertical distribution of HCl in the stratosphere has been measured from infrared solar absorption spectra recorded with a balloon-borne interferometer. The flights were made in September, 1975, and May, 1976 at float altitudes of 40 km and 37 km, respectively, near Palestine, Texas. Concentration profiles derived from the data show an increase from 0.6 ppbv at 20 km to 1.7 plus or minus .5 ppbv in the region of 37 km. Above 37 km, the data permit only the total abundance to be determined; this value is found to be equivalent to 1.6 plus or minus .6 ppbv if the gas were uniformly mixed. The results from the two flights are closely similar, and no significant seasonal variation in the HCl concentrations can be discerned. The balloon data are consistent with the profile in the 14-21 km altitude region of the stratosphere reported earlier from U-2 observations.
Raper, O. F.↗
Mars: Water Vapor Observations from the Viking Orbiters
The global distribution of the water vapor has been mapped at low resolution throughout the period from the northern summer solstice to the following equinox. During this seasonal period the water vapor underwent a gradual redistribution, the latitude of maximum column abundance moving from the northern polar area to the equatorial latitudes. The total global vapor content remained approximately constant at the equivalent of about 1.3 cu km of ice. The various data obtained indicate that the residual polar caps are composed of water ice.
Farmer, C. B.↗
Behavior of volatiles in Mars' polar areas - A model incorporating new experimental data
A model has been developed to explain the north polar water vapor results obtained by the Viking orbiter Mars atmospheric water detector; it has also been used to compute the thickness of seasonally deposited CO2 frost, the variation of the total atmospheric pressure, and wind velocities due to mass motions associated with CO2 condensation. A north polar water ice thickness in excess of 1 m and an ice albedo a of 0.34(+0.06,-0.03) are inferred from a comparison of the model and experimental data. The model results confirm an earlier conclusion that the atmosphere over the ice is saturated. It is suggested that concentration of the atmospheric inert gases in the polar region, combined with local topography and arctic circulation patterns, could be responsible for the south remnant cap not being at the south pole
Davies, D. W.↗
Mars - Northern summer ice cap - Water vapor observations from Viking 2
Observations of the latitude dependence of water vapor made from the Viking 2 orbiter show peak abundances in the latitude band 70 to 80 deg N in the northern midsummer season (planetocentric longitude about 108 deg). Total column abundances in the polar regions require near-surface atmospheric temperatures in excess of 200 K and are incompatible with the survival of a frozen carbon dioxide cap at Martian pressures. The remnant (or residual) north polar cap and the outlying patches of ice at lower latitudes are thus predominantly water ice, whose thickness can be estimated to be between 1 meter and 1 kilometer.
Farmer, C. B.↗
Viking: Mars atmospheric water vapor mapping experiment - Preliminary report of results
Observations made from the Viking 1 orbiter show very little water vapor in the Mars atmosphere in the southern hemisphere (0 to 3 precipitable micrometers) with a gradual increase across the equator to northern latitudes. Maximum amounts between 20 and 30 micrometers have been observed in the short period covered by the observations to date. The season, northern midsummer, corresponds to the beginning of the water vapor cycle in that hemisphere. A strong repetitive diurnal cycling between the solid and vapor phase is observed at a site to the east of the Tharsis Ridge at 10 deg north latitude; the vapor lies close to the martian surface and is most probably in saturation equilibrium with a surface haze or fog throughout much of the day.
Farmer, C. B.↗
Spectroscopic detection and vertical distribution of HCl in the troposphere and stratosphere
HCl has been observed in both the troposphere and stratosphere from ground-based and airborne spectroscopic measurements of the 1-0 band at 3-micron wavelength. The results, which are specific to the HCl molecule in the gas phase, show a decreasing mixing ratio with altitude in the lower stratosphere. The stratospheric layer, which commences at about 15 km, reaches its maximum concentration at an altitude above 21 km (the limiting height of the observations to date). The local value for the volume mixing ratio at 21 km is 7 + or - 1 times 10 to the minus 10th. However, the zenith column abundance observed above 21 km implies that the mixing ratios at greater altitudes are unlikely to reach values much in excess of the local value at 21 km.
Farmer, C. B.↗