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Ewing, Sarah M.

Publications and source records attributed to Ewing, Sarah M..

Extracting Knowledge from Data through Catalysis Informatics

Catalysis informatics is a distinct sub-field that lies at the intersection of cheminformatics and materials informatics, but with unique challenges arising from the dynamic, surface-sensitive, multi-scale nature of heterogeneous catalysis. The ideas behind catalysis informatics can be traced back decades, but the field is only recently emerging due to advances in data infrastructure, statistics, machine learning, and computational methods. In this work we review the field from early works on expert systems and knowledge engines to more recent approaches utilizing machine-learning and uncertainty quantification. The data-information-knowledge hierarchy is introduced and used to classify various developments. The chemical master equation and micro-kinetic models are proposed as a quantitative representation of catalysis knowledge, which can be used to generate explanative and predictive hypotheses for the understanding and discovery of catalytic materials. We discuss future prospects for the field, including improved quantitative coupling of experiment/theory, advanced micro-kinetic models, and the development of open-source software tools. As a result, integration of existing chemical and physical models with emerging statistical and computational tools presents a promising route toward the automated design, discovery, and optimization of heterogeneous catalytic processes.

97 MATHEMATICS AND COMPUTING↗

Determination of a Generic Human Error Probability Distribution, Part 1: A Dynamic Formulation of SPAR-H

In almost all major nuclear power plants (NPP) events include a significant human error component. As an example, in Fukushima Daiichi (2011) nuclear meltdown, the human actions related to the high-pressure injection cooling strongly affected accident evolution. Furthermore, in the Three Mile Island accident (1979) (which was initiated by a stuck open valve and thus was triggered a loss of coolant accident) the unit operators made decisions based upon false assumptions that contributed negatively to the accident. Given these premises, the ability to accurately model human interactions with plant evolution and, in particular, dynamically calculate human error probability (HEP) plays a major role in a probabilistic risk analysis (PRA). Human reliability analysis (HRA) identifies and models the causes of human errors, and quantifies HEP by applying different methodologies. HRA methods identify errors and reflect on the understanding of error-prone people and systems. There are a number of HRA methods available that assist in identifying the vulnerabilities in the system and provide guidance in determining the HEP. HEP is the probability of a human failure event (HFE), and quantification of HEPs under various situations is utilized in PRA of large complex systems. One of the more prominent HRA methods is the Standardized Plant Analysis Risk-Human Reliability Analysis (SPAR-H) method that was developed to estimate HEPs for the use in the Standardized Plant Analysis Risk (SPAR) PRA models employed in U.S. NPPs. SPAR-H is implemented in U.S. NPPs by regulators at the U.S. Nuclear Regulatory Commission (NRC) to determine the HEP based on expert estimation through the use of calculation worksheets. In SPAR-H, the nominal HEPs (NHEPs) are multiplied by performance shaping factors (PSF) multiplier values to obtain the overall error probability. PSFs encompass the human components, individual characteristics, their environment, and aspects of the task. With PSFs, the goal is to capture all factors that can affect human performance. In SPAR-H there are eight PSFs used, each having respective levels corresponding to multipliers: Available Time, Stress/Stressors, Complexity, Experience/Training, Procedures, Ergonomics/Human Machine Interface, Fitness for Duty, and Work Processes. The PSF multipliers indicate enhanced, nominal, or degraded human performance. The SPAR-H method estimates the HEP through multiplying a NHEP with PSFs. Hence, SPAR-H is a traditional HRA method that assesses human performance at a fixed, or static, point in time. In a dynamic HRA framework, human performance is assessed on a continuous time basis. SPAR-H can be used within a dynamic PRA framework through the use of simulation and stochastic models. The goal of dynamic HRA is to build a more realistic model of the human-system interaction to enhance calculation of reliability, risk and safety analysis. The progression of events in dynamic SPAR-H considers that some PSFs may experience gradual change, while other change can be sudden due to individualistic differences or rapid plant status changes. The PSF changes are caused by contextual changes in the scenario. For example, as more time passes, the realization that a task should be completed sooner may cause the operator more stress. In another example, a sudden relay of information about sickness of a family member may alter the operator's general stress level and fitness for duty. Each PSF has a different dynamic nature; PSFs like stress and complexity change more quickly over the course of a task than experience and training. While the experience of an operator changes over the course of attaining the objective, the amount that this added experience changes the HEP is very minimal. In contrast, the stress, complexity, and procedures PSFs may change quite a bit over the course of task completion.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Determination of a Generic Human Error Probability Distribution, Part 2: A Dynamic SPAR-H Example Application

Humans are an integral part of a nuclear power plant (NPP) from its construction, to its everyday maintenance and operation. In the nuclear industry there are many approaches to quantifying component reliability, which is called probability risk assessment (PRA). In PRA there are two considerations given to the quantification, static and dynamic. Static is quantified before or after an operation; and dynamic is time dependent, in that the probability changes as real time data are provided. In PRA, the importance of the components is calculated, but what of the importance of the human component? There are several methods for human reliability analysis (HRA), which include but are not limited to: THERP, ATHEANA, CREAM, SPAR-H, ASEP, and SLIM. Each of these methods aims to provide a more accurate and objective human error probability (HEP) quantification. Of the methods listed above, ASEP, THERP, and SPAR-H are all inextricably linked. The Standardized Plant Analysis Risk-Human Reliability Analysis (SPAR-H) method was generated to better generalize the Technique for Human Error Rate Prediction (THERP) and Accident Sequence Precursor (ASEP). THERP is mapped to specific scenario templates, and ASEP is a simplified screening method, while SPAR-H employs generalizations to describe the spectrum of human behavior while maintaining the same theoretical underpinnings. SPAR-H is a well-known and accepted HRA method that uses performance shaping factors (PSFs) to classify inputs to the human component. PSFs capture a wide variety of input data, including plant status, crew dynamics, task description, and psychological aspects of the human operator. Current efforts have been focused to further generalize SPAR-H in to a dynamic framework. These methods can fit into dynamic NPP simulations such as RAVEN / RELAP-7. In order to do this, a dynamic methodology is applied to model the human as would be applied to the components. This method is applied in part one in the accompanying paper.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Quantification of functional impact classification on the current U.S. nuclear fleet

Currently, nuclear power generates only a small fraction of the world's electricity, though it does have the potential to meet the needs of the world as long as its production can compete with the alternative energy base load producers. In U.S the commercial nuclear fleet comprises of Light Water Reactors (LWRs), consisting of Pressurized Water Reactors (PWRs) and Boiling Water Reactors (BWRs). Many plants experience multiple events each year, which lead to reactor trips or scrams. This subsequently leads to plants being off the grid, which is not an economically favorable situation in the current energy markets. This study helps identify functional impact (FI) event categories for both PWR's and BWR's. Understanding that not all events and their causes can be anticipated, current industry best practices implement lessons learned to provide challenges and issues identification. In turn these are studied to achieve improved operational practices, and design modifications. This leads to overall enhanced resiliency. FI groups are the categories of initiating events (IE). IEs are unplanned events that occur while a nuclear plant is in critical operation, and requires that the plant be shut down to achieve a stable state. When a risk cannot be eliminated, IEs are identified and studied to reduce the risk and contribute to the identification of mitigations, safer designs and operational practices. Breaking IE events into groups' results in the classification of FI groups. A FI group is a risk-significant event category that could impact the ability of a NPP to remove decay heat from the reactor. Inability to remove decay heat from the reactor has the potential to lead to core damage. For an event to be considered a FI, it must be associated with a manual or automatic reactor trip, irrespective of the order of events. In addition, the plant must be at or above the point of adding heat and the event must happen before or shortly after a reactor trip. One or more FIs may be identified in any individual reactor trip sequence. The relationship between FI sequence, and/or frequency per a plant event is outside the scope of this paper. For example, the loss of offsite power (LOOP) can occur from eternal events (i.e. weather, human, wildlife etc.). This results in an event that requires a transfer of power to an emergency source, such as a generator, which produces a reactor trip and then a closure of main steam isolation valves (MSIVS). The FI applicable to this reactor trip sequence would be LOOP and closure of at least one MSIV in each main steam line. The results presented herein are focused on the analysis and evaluation of FI event categories. Only FI categories that can be found in IE studies, Initialing Events Spreadsheet and are recorded in a historical review of Licensee Event Reports (LERs) from 1988 through 2013. The results of this analysis can support plant decisions, design, procedures, and identify weakness.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

QUANTIFICATION OF FUNCTIONAL IMPACT CLASSIFICATION ON THE CURRENT US NUCLEAR FLEET

Many plants experience multiple failure events each year, and while none of these events result in core damage further consideration for nuclear power plant (NPP) type and its role in an event needs to be considered. Specifically herein initiating events (IE) are considered these are unplanned events that occur while a nuclear plant is in critical operation, and requires that the plant be shut down to achieve a stable state. Breaking IE failure events into groups results in the classification of functional impact (FI) groups. A FI group is a risk-significant event category that could impact the ability of a NPP to remove decay heat from the reactor. For an event to be considered a FI, it must be associated with a manual or automatic reactor trip, irrespective of the order of events. In addition, the plant must be at or above the point of adding heat and the event must happen before or shortly after a reactor trip. One or more FIs may be identified in any individual reactor trip sequence. An example of a FIs is the loss of offsite power (LOOP) from a bird interaction with the power lines. This results in a failure to transfer power to an emergency source, such as a generator, producing a turbine and reactor trip and then a closure of main steam isolation valves (MSIVS). The FI applicable to this reactor trip sequence would be loss of offsite power and closure of at least one MSIV in each main steam line. The results presented are focused on the analysis and evaluation of FI event categories that can be found in IE studies [1], [2] and the Initialing Events Spreadsheet [3] and is a historical review of Licensee.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗