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Evenson, K. M.

Publications and source records attributed to Evenson, K. M..

31 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

The microwave and far-infrared spectra of the SiH radical

Consideration of Si's cosmic abundance leads to the expectation that the related molecule SiH may be detected in extraterrestrial sources. A tabulation is presented of frequencies, wavelengths, and line strengths for SiH molecule transitions at microwave and far-IR wavelengths, on the basis of an analysis of its laser magnetic resonance spectrum. It is hoped that the frequencies presented will be useful to both laboratory spectroscopists and astrophysicists.

Brown, J. M.↗
NASA NTRS1984

Pressure effects on the frequency of continuous-wave optically pumped far-infrared lasers

The frequency of the 170.6-micron CW CH3OH optically pumped laser emission has been remeasured at different pressures without observing the pressure shift observed by Lawandy and Koepf (1980). The far-infrared frequency was synthesized with two stabilized CO2 lasers. No measurable pressure shift over the operating pressure range of the laser was observed, and the frequency was confirmed to be 1 757 526.3 MHz. However, competing lasing lines were found to produce spurious effects on the frequency. These effects may explain the apparent shifts.

Inguscio, M.↗
NASA NTRS1984

The far-infrared laser magnetic resonance spectrum of the SiH radical and determination of ground state parameters

The far-infrared laser magnetic resonance spectrum of the SiH radical in the v = O level of its X2Pi state has been recorded. The signals are rather weak. The molecules were generated in the reaction between fluorine atoms and SiH4. Rotational transitions have been detected in both 2Pi1/2 and 2Pi3/2 spin components but no fine structure transitions between the spin components were observed. Proton hyperfine splittings were resolved on some lines. The measurements have been analyzed, subjected to a least-squares fit using an effective Hamiltonian, and the appropriate molecular parameters determined. The weakness of the spectrum and the failure of attempts to power saturate favorable lines are both consistent with a small value for the electric dipole moment for SiH.

Brown, J. M.↗
NASA NTRS1984

Tunable far-infrared spectroscopy

Tunable, CW, far-infrared radiation has been generated by nonlinear mixing of radiation from two CO2 lasers in a metal-insulator-metal (MIM) diode. The FIR difference-frequency power radiated from the MIM diode antenna to a calibrated indium antimonide bolometer. Two-tenths of a microwatt of FIR power was generated by 250 mW from each of the CO2 lasers. The combination of lines from a waveguide CO2 laser, with its larger tuning range, with lines from CO2, N2O, and CO2 isotopic lasers promises complete coverage of the entire far-infrared band from 100 to 5000 GHz (3-200 per cm) with stepwise-tunable CW radiation. To demonstrate the usefulness of the technique, the J = 4-5 line of CO was observed at 567 GHz.

Evenson, K. M.↗
NASA NTRS1984

The direct measurement of the 3 3P0-3 3P1 fine-structure interval and the gJ-factor of atomic silicon by laser magnetic resonance

The J - 1 fine structure interval and the g-factor of the 3P1 state have been determined with high precision in the present laser magnetic resonance measurements of the ground 3p2 3P multiplet of atomic Si. Delta-E(3P1-3P0) = 2,311,755.6(7) MHz, and gJ(3P1) = 1.500830(70). Single-configuration calculations of gJ for 3P1 and 3P2 yield a value for the latter which, at 1.501095, is noted to differ by an unexpectedly large margin from the experimental value.

Evenson, K. M.↗
NASA NTRS1984

Far-infrared laser magnetic resonance of vibrationally excited CD2

The detection of 13 rotational transitions in the first excited bending state (010) of CD2 using the technique of far-infrared laser magnetic resonance spectroscopy is reported. Molecular parameters for this state are determined from these new data together with existing infrared observations of the v(2) band. Additional information on the ground vibrational state (000) is also provided by the observation of a new rotational transition, and this is combined with existing data to provide a refined set of molecular parameters for the CD2 ground state. One spectrum has been observed that is assigned as a rotational transition within the first excited symmetric stretching state (100) of CD2. These data will be of use in refining the structure and the potential function of the methylene radical.

Evenson, K. M.↗
NASA NTRS1984

Infrared and far-infrared transition frequencies for the CH2 radical

A list of frequencies and intensities for transitions of CH2 in the middle and far infrared regions is presented which should aid in the detection of CH2 and provide valuable information on the local physical and chemical environment. Results are presented for frequency, vacuum wavelength, and line strength for rotational transition frequencies and for the transition frequencies of the v(2) band.

Sears, T. J.↗
NASA NTRS1983

The microwave and far-infrared spectra of the CH radical

The frequencies, wavelengths, and line strengths for transitions of the CH molecule at microwave and far-infrared wavelengths have been calculated from an analysis of the laser magnetic resonance spectrum. The low-frequency transitions are between lambda-type doublets, while the higher frequency transitions are between different spin-rotation levels.

Brown, J. M.↗
NASA NTRS1982

The far-infrared spectrum of the OH radical

It is thought likely that the study of spectral lines in the far-infrared might provide at least as much information about the physics and chemistry of the interstellar environment as radioastronomy. However, by comparison with the microwave region, the far-infrared is largely unexplored. There is a pressing need for good laboratory data to aid searches and assignments of spectra from the interstellar clouds and nebulae. Brown et al. (1981) have conducted a study of the laser magnetic resonance (LMR) spectrum of the OH radical in its ground state at far-infrared wavelengths. The present investigation is concerned with the computation of the frequencies of individual hyperfine transitions involving all rotational levels up to J = 4 1/2. The results of the calculation are presented in a table. The results are summarized in a diagram which shows the low-lying energy levels of OH. The frequencies of transitions between levels studied directly in the LMR spectrum are quite reliable.

Brown, J. M.↗