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Evans, W. F. J.

Publications and source records attributed to Evans, W. F. J..

The measurement of ultraviolet radiation and sunburn time over southern Ontario

Studies of the depletion of ozone which have been conducted from the TOMS instrument on the NIMBUS 7 satellite indicate that total ozone has declined by 5 percent over the last 12 years at most mid-latitudes in the Northern Hemisphere typical of southern Ontario. The measurement of the actual resultant increases in UVB is now important. A monitoring program of UVB (biologically active solar ultraviolet radiation) has been conducted for the last 24 months at a site near Bolton, Ontario. The sunburn time varies from less than 17 minutes in late July, to over 4 hours in December on clear days. The levels depend on solar insolation and total ozone column. The ultraviolet levels are strongly affected by cloud and sky conditions. The implications of present and future depletion on the sunburn time are discussed.

Evans, W. F. J.↗

The ground-based measurement of ozone in the 9.6 micron band

Stratospheric ozone has been measured using infrared emission spectroscopy of the 9.6 micron band. Thermal emission spectra of the zenith sky were measured from the ground. The spectra show the presence of the 1020 cm(exp -1) spectral feature of ozone on clear days. The spectra were measured with a BOMEM model 100 emission interferometer with a resolution of 4 cm(exp -1). The feature corresponds to a mixing ratio of 5 ppmv if the ozone is assumed to be uniformly distributed in the stratosphere from 25 to 35 km. The development of an inversion algorithm to derive the altitude distribution of the ozone in 3 layers is described. These measurements have been conducted from Peterborough, Ontario since June 1991; further investigations are planned to study the comparisons with Dobson and LIDAR ozone measurements.

Evans, W. F. J.↗

Longitudinal structure in atomic oxygen concentrations observed with WINDII on UARS

WINDII, the Wind Imaging Interferometer on the Upper Atmosphere Research Satellite, began atmospheric observations on September 28, 1991 and since then has been collecting data on winds, temperatures and emissions rates from atomic, molecular and ionized oxygen species, as well as hydroxyl. The validation of winds and temperatures is not yet complete, and scientific interpretation has barely begun, but the dominant characteristic of these data so far is the remarkable structure in the emission rate from the excited species produced by the recombination of atomic oxygen. The latitudinal and temporal variability has been noted before by many others. In this preliminary report on WINDII results we draw attention to the dramatic longitudinal variations of planetary wave character in atomic oxygen concentration, as reflected in the OI 557.7 nm emission, and to similar variations seen in the Meine1 hydroxyl band emission.

Shepherd, G. G.↗

CANOZE measurements of the Arctic ozone hole

In CANOZE 1 (Canadian Ozone Experiment), a series of 20 ozone profile measurements were made in April, 1986 from Alert at 82.5 N. CANOZE is the Canadian program for study of the Arctic winter ozone layer. In CANOZE 2, ozone profile measurements were made at Saskatoon, Edmonton, Churchill and Resolute during February and March, 1987 with ECC ozonesondes. Ground based measurements of column ozone, nitrogen dioxide and hydrochloric acid were conducted at Saskatoon. Two STRATOPROBE balloon flights were conducted on February 26 and March 19, 1987. Two aerosol flights were conducted by the University of Wyoming. The overall results of this study will be reported and compared with the NOZE findings. The results from CANOZE 3 in 1988, are also discussed. In 1988, as part of CANOZE 3, STRATOPROBE balloon flights were conducted from Saskatchewan on January 27 and February 13. A new lightweight infrared instrument was developed and test flown. A science flight was successfully conducted from Alert (82.5 N) on March 9, 1988 when the vortex was close to Alert; a good measurement of the profile of nitric acid was obtained. Overall, the Arctic spring ozone layer exhibits many of the features of the Antarctic ozone phenomenon, although there is obviously not a hole present every year. The Arctic ozone field in March, 1986 demonstrated many similarities to the Antarctic ozone hole. The TOMS imagery showed a crater structure in the ozone field similar to the Antarctic crater in October. Depleted layers of ozone were found in the profiles around 15 km, very similar to those reported from McMurdo. Enhanced levels of nitric acid were measured in air which had earlier been in the vortex. The TOMS imagery for March 1987 did not show an ozone crater, but will be examined for an ozone crater in February and March, 1988, the target date for the CANOZE 3 project.

Evans, W. F. J.↗

Brewer spectrophotometer measurements in the Canadian Arctic

In the winters of 1987 and 1988 measurements were conducted with the Brewer Spectrophotometer at Alert (82.5 N) and Resolute (74.5 N). The measurements were conducted as part of our Canadian Program to search for an Arctic Ozone Hole (CANOZE). Ozone measurements were conducted in the months of December, January and February using the moon as a light source. The total ozone measurements will be compared with ozonesonde profiles, from ECC sondes, flown once per week from Alert and Resolute. A modified Brewer Spectrophotometer was used in a special study to search for chlorine dioxide at Alert in March 1987. Ground based observations at Saskatoon in February and at Alert in March 1987 failed to detect any measureable chlorine dioxide. Interference from another absorbing gas, which we speculate may be nitrous acid, prevented the measurements at the low levels of chlorine dioxide detected in the Southern Hemisphere by Solomon et al.

Kerr, J. B.↗

Latitude survey of aerosol optical thickness of the El Chichon eruption cloud in May 1983

The results of measurements of the latitudinal distribution of the El Chichon eruption cloud in May 1983 for the latitude range between 71 deg N and 56 deg S are presented. Aerosol optical thicknesses are calculated from solar spectral extinction measurements made with a sunphotometer on board the NASA Convair 990 aircraft. It is shown that the thicknesses vary in the range between 0.12 and 0.01, that a maximum of about 0.12 is found at middle latitudes, and that distinct minima of 0.01-0.02 are observed at 25-deg latitude in both hemispheres. The median radius of particles is found to be between 0.16 micron and 0.18 micron in the northern hemisphere and between 0.11 micron and 0.15 micron in the southern hemisphere. Rough estimates of aerosol mass indicate that about 1.5 megatonnes of aerosol still persisted in the stratosphere between the equator and 25-deg N one year after the eruption.

Shah, G. M.↗

Hydrogen species

Measurements of the members of the HO(x) family (OH, HO2, and H2O2) and their major source gases, H2O, and CH4 are discussed. Emphasis is placed on measurements which were made since the 1982 World Meteorologic Organization (WMO) report. Measurement techniques, available data, an assessment of data reliability, and a comparison of the data with theoretical distributions of stratospheric HO(x) species predicted from one and two dimensional photochemical models are discussed.

Schiff, H. I.↗

Aircraft lattitude survey measurements of the El Chichon eruption cloud

Solar spectral extinction measurements made with a solar photometer aboard a NASA research aircraft, whose flights were conducted during May, July, and December 1982 over a range of latitudes, are presently used to derive aerosol optical thicknesses. The large thickness increases over background levels found at all latitudes studied for the stratosphere are attributed to the El Chichon eruption cloud. The spectral dependence of the aerosol optical thickness, which is different on one side of 30 deg N latitude from the other side, suggests that the two portions of the cloud have different aerosol size distributions.

Shah, G. M.↗

Validation of nitrogen dioxide results measured by the limb infrared monitor of the stratosphere (LIMS) experiment on NIMBUS 7

The validation of results from the nitrogen dioxide channel and the quality of the data are examined in connection with the LIMS experiment which ran from late October 1978 to late May 1979. Factors studied include: channel characteristics, experiment errors due to instrument and spacecraft effects, predicted and measured precision, predicted accuracy, and comparisons with correlative measurements made in a series of balloon underflights. Features such as profile shape and slope of the mixing ratio altitude distribution are in good agreement. The LIMS data also fall within the range of previous mixing ratio measurements and are consistent with model estimates. The calculated on-orbit precision is about 0.3 ppbv and the estimated accuracy from simulations is about 2 ppbv over the 3-10-mbar range. Accuracy is less at higher and lower pressure levels. These results provide the first day-night set of nitrogen dioxide measurements from space.

Russell, J. M., III↗

Validation of water vapor results measured by the Limb Infrared Monitor of the Stratosphere experiment on Nimbus 7

In the LIMS experiment using thermal IR limb scanning to sound the composition and structure of the upper atmosphere, one of the LIMS channels was spectrally centered at 6.9 micrometers to measure the vertical profile and global distribution of stratospheric water vapor. This channel's characteristics, the data from it, and the steps taken to validate results are described. The mean difference between the LIMS measurements and data from 13 balloon underflights is about 0.6 ppmv with LIMS mixing ratios biased high; this difference is of about the same order as estimated LIMS accuracy and less than the sum of the errors for LIMS and the balloon techniques. In-orbit precision is 0.2-0.3 ppmv and accuracy is estimated at 20-30 percent from 50 mbar to the stratopause. An unexplained diurnal variation exists in the vertical profile data which is largest at the 1-mbar level and virtually nonexistent at 10 mbar; day values are higher than night. More confidence is placed in zonal mean distributions averaged over several days than in single profiles. A zonal mean pressure-latitude cross section is described for January 5-9, 1979.

Russell, J. M., III↗

High resolution atmospheric transmission calculations down to 28.7 km in the 200-243-nm spectral range

Decrease in stratospheric ozone absorption and increase in oxygen absorption with decreasing wavelength combine to produce a window of maximum atmospheric transmission near 210 nm. Since solar radiation in this spectral region dissociates molecular oxygen, the deep atmospheric penetration at this wavelength is of particular aeronomical interest. High resolution calculations of the transmittance down to 28.65 km were made for the 200-243-nm spectral range in this window region, in support of a stratospheric balloon flight from Fort Churchill in July 1974. The calculations were made by dividing the atmosphere into layers which were chosen so that each could be assumed homogeneous; optical depths were calculated separately for each of these layers and then summed to obtain the over-all transmittance of the atmosphere. Absorption by molecular oxygen (line and continuum) and by ozone was included, as well as extinction through Rayleigh scattering by air molecules. The calculated transmittances were combined with high altitude (above 100-km) rocket measurements of the sun-center spectrum and center-to-limb variations to give residual high resolution solar spectral flux for several altitudes and solar zenith angles.

Cann, M. W. P.↗