Phosphate in Angra dos Reis - Structure and composition of the Ca3/PO4/2 minerals
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Engineering topics
Publications and source records attributed to Dowty, E..
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We present evidence to support the hypothesis that the fine-grained, basaltic-textured portions of rocks 60618 and 65785 were produced by impact melting of the coarse-grained spinel-olivine anorthosite (60618) and spinel troctolite (65785) portions, coupled with admixture of approximately 33% and 63%, respectively, material of alkalic high-alumina basalt (KREEP) composition. The abundance of impact-modified rocks at the Apollo 16 site with compositional similarities to the impact melts reported here, suggests that the relations observed in these rocks are indicative of widespread impact mixing with KREEP in rocks of the lunar highlands.
Eight of eleven Apollo 16 rake-sample anorthosites are very similar to each other, to hand-specimen Apollo 16 anorthosites, and to Apollo 15 anorthosites. They have feldspar An-96.6, both high- and low-Ca pyroxene with a restricted range of (low-magnesium) composition, minor olivine, traces of ilmenite and chromite, and originally coarse-grained, but now cataclastic texture. Such ferroan anorthosite is evidently a coherent, distinctive and widespread lunar rock type of cumulate origin which may not necessarily be very closely related genetically to other highland rock types.
Plagioclases in different types of lunar highland rocks (all highly feldspathic) are twinned according to different laws and in different styles. Carlsbad and Carlsbad-albite twins, presumed to be growth twins, occur mainly in rocks which show igneous texture, and which have not been severely brecciated. These two twin laws appear to be absent from cataclastic rocks, including cataclastic anorthosite, possibly because the original twins were preferentially broken up in cataclasis (the composition plane being a plane of weakness). Pericline and lamellar albite twins, presumed to be deformation twins (except for some albite growth twins) occur in all types of rocks, and obvious deformation features, such as bending of lamellae, are well shown in many cataclastic rocks. Surprisingly, some Carlsbad and Carlsbad-albite twins are found in rocks with granoblastic texture, which presumably recrystallized in the solid state.
Results are reported for a study of seven holocrystalline feldspathic rocks (including a spinel troctolite and six melt rocks) and one mare basalt clast from the Apollo-16 rake samples. The composition and grain structure of each rock is described in detail. Only the spinel troctolite is considered a good candidate for a primary igneous cumulate formed during the original differentiation of the lunar crust. It is shown that the melt rocks probably resulted from shock melting followed by rapid crystallization of heterogeneous highland material and that compositional variations are probably due to mixing of various amounts of heterogeneous cumulates and KREEP components. It is suggested that the mare basalt clast may have been derived from Mare Fecunditatis, although the nearest mare to the Apollo-16 site is Nectaris.
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One hundred seventy-six oxide mineral grains in the Luna 20 samples were analyzed by electron microprobe. Spinel is the most abundant oxide, occurring in troctolite fragments. Next most abundant is ilmenite, which occurs in all rock types except those containing spinel. Chromite also occurs in all rock types except those containing spinel. Minor amounts of ulvospinel, armalcolite, zirkelite, baddeleyite and an unidentified TiO2-rich phase were also found. Spinel grains are predominantly spinel-hercynite solid solutions, commonly with very minor chromite. The Fe/(Fe + Mg) ratio is generally lower than in spinel from Apollo 14 rocks. Chromites in non-mare rocks are similar to those from mare rocks. Ilmenite of mare origin is Mg-poor and Zr-rich compared to non-mare ilmenite; these elements may therefore be useful in determining the origin of ilmenite grains. Phase equilibria considerations suggest that spinel troctolite crystallized from a melt high in alumina; a likely candidate is the high-alumina basalt of Prinz et al. (1973).
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Review of the examination results on two Apollo 16 rocks recovered from the lunar highlands which probably represent contrasting types of 'primitive' lunar cumulates. One is a microbreccia containing a large lithic fragment of spinel troctolite, while the other is a shock-brecciated anorthosite. The reviewed results suggest that, if the two rock groups formed from the same parent magma type, the spinel troctolite must have formed early in the differentiation sequence as the result of crystal settling in the melt, whereas the anorthosite must have formed as a later cumulate, possibly by flotation.
The bulk analyses (determined with the broad beam electron microprobe technique) of lithic fragments are given in weight percentages and are arranged according to the rock classification. Within each rock group the analyses are arranged in order of increasing FeO content. Thin section and lithic fragment numbers are given at the top of each column of analysis and correspond to the numbers recorded on photo mosaics on file in the Institute of Meteoritics. CIPW molecular norms are given for each analysis. Electron microprobe mineral analyses (given in oxide weight percentages), structural formulae and molecular end member values are presented for plagioclase, olivine, pyroxene and K-feldspar. The minerals are selected mostly from lithic fragments that were also analyzed for bulk composition. Within each mineral group the analyses are presented according to the section number and lithic fragment number. Within each lithic fragment the mineral analyses are arranged as follows: Plagioclase in order of increasing CaO; olivine and pyroexene in order of increasing FeO; and K-feldspar in order of increasing K2O. The mineral grains are identified at the top of each column of analysis by grain number and lithic fragment number.
Twenty-eight mare basalts from three Apollo 15 rake sample sections are divided into five rock groups which are considered to represent at least five rock units. Three of these groups (pyroxene-phyric basalt, olivine-phyric basalt, and olivine microgabbro) are from the mare area and are probably near-surface local mare rock units. The remaining groups (feldspathic peridotite and feldspathic microgabbro) are found outside the mare, in Spur Crater at the foot of the Apennines; they may come from deeper levels of the local mare or from a more distant source.
Analysis of all samples returned by lunar missions before Apollo 15 has shown green glasses of ultramafic composition in soil and microbreccia samples. Ultramafic glasses in Apollos 11 and 14 and Luna 16 samples are rare and similar to each other in composition but different from any of the rocks collected at these sites. Details of work regarding Apollo 15 ultramafic green glasses are discussed together with questions of the origin of all green glasses.
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Quantitative electron microprobe data of Apollo 15 nonmare rake samples are presented. Bulk analyses of lithic fragments in the nomare rocks (expressed in oxide weight-percent) and the corresponding CIPW molecular norms are given. The mineralogy of the rocks and lithic fragments are also given; structural formulae for complete analyses and molecular end-members for all mineral analyses are included. The mineral analyses include pyroxene, olivine, plagioclase, barian K-feldspar, spinel and ilmenite, cobaltian metallic nickel-iron as well as SiO2-K2O-rich residual glass. Electron micropobe analyses (oxide weight percent) of glasses in loose fines and microbreccia samples and their CIPW molecular norms are presented along with electron microprobe data on bulk, mineral, and matrix glass from chondrules.