Engineering topics

Douglass, A. R.

Publications and source records attributed to Douglass, A. R..

78 records · Page 5

NASA NTRS1985

Parameterization of the photochemistry of stratospheric ozone including catalytic loss processes

A parameterization has been developed which accurately describes the photochemical response of odd oxygen to dynamically induced perturbations in odd oxygen and temperature. The temperature and odd oxygen dependencies of the loss processes for odd oxygen through catalytic cycles involving odd nitrogen, odd chlorine, and odd hydrogen have been specifically included. The assumption that a linear perturbation equation may be used to describe the response of odd oxygen to perturbations in odd oxygen and temperature has been tested and found to be acceptable for a physically reasonable range of perturbations, i.e., up to approximately 50 percent in odd oxygen mixing ratio and approximately 10 K in temperature. The scheme should prove useful for analyzing the feedback between ozone chemistry and ozone transport and also for analysis of ozone and temperature data.

Stolarski, R. S.↗

NASA NTRS1985

Interpretation of ozone temperature correlations. I - Theory

Correlations between ozone and temperature are commonly used to investigate the photochemical and dynamical aspects of satellite-derived ozone data. In this paper, the dynamical contributions to the ozone temperature correlations are examined using simple analytic and numerical models. It is shown that the phase differences between ozone and temperature waves caused by dynamical forcing can mimic the phase relationships predicted for photochemical equilibrium. Furthermore, the dynamical contribution to the phase relationship between ozone and temperature waves is routinely significant for chemistry time scales of approximately 0.5 days and is potentially important for time scales as short as 2 hours during stratospheric warmings. The model results are highly relevant to the analysis of the limb infrared monitor of the stratosphere and solar backscatter ultraviolet data taken during the winter of 1979.

Rood, R. B.↗

NASA NTRS1984

An analysis of the annual cycle in upper stratospheric ozone

The mid-latitude upper stratospheric ozone profiles obtained by the solar backscatter ultraviolet instrument on the Nimbus 7 satellite show a clear annual cycle both in the absolute ozone amounts between 0.98 and 15.6 mbar and in the magnitude of disturbances that reveal themselves as longitudinal structure. At the lowest pressure analyzed a winter maximum in ozone exists, but as one progresses downward in altitude a shift in the temporal phase of the annual cycle occurs in the vicinity of 3 to 4 mbar. Comparison of the observed behavior with the predictions of a one-dimensional photochemical model shows a systematic tendency for calculated ozone amount to be 20-27 percent below the data for pressures less than 7.8 mbar. The chemical model successfully predicts the change in phase of the annual cycle, although at a pressure greater than observed. Diagnosis of model results shows the observed shift to be closely coupled to the magnitude of the ozone column density near 3-4 mbar. The wavelength-dependent attenuation of the solar radiation field by ozone alters the relative magnitude of the molecular oxygen and ozone dissociation rates, leading to a change in the temporal phase of the annual cycle.

Frederick, J. E.↗

NASA NTRS1983

Nitric oxide in the upper stratosphere - Measurements and geophysical interpretation

A rocket-borne parachute-deployed chemiluminescence instrument has obtained seven new measurements of atmospheric nitric oxide for altitudes between 30 and 50 km at mid-latitudes. These results, when combined with profiles measured by an earlier version of the instrument, cover all four seasons and provide a more comprehensive picture of upper stratospheric nitric oxide than has been available previously. At the highest altitudes studied, the vertical gradient in mixing ratio displays positive and negative values during different observations, with the largest values tending to appear at the greatest heights in summer. Examination of the differences among the profiles, which exceed a factor of 3 near the stratopause, suggests that they arise from the action of transport processes which carry air into the mid-latitude upper stratosphere from regions of the atmosphere that contain widely different odd-nitrogen abundances.

Harvath, J. J.↗

NASA NTRS1983

Atmospheric temperatures near the tropical tropopause Temporal variations, zonal asymmetry and implications for stratospheric water vapor

Analysis of temperature measurements obtained over an eight-year period in the vicinity of the low-latitude tropopause confirms the existence of longitude regions which are consistently colder by approximately 2-3 K than elsewhere in the tropics. These temperature differences, however, are confined to a layer of thickness 3-5 km centered on the tropopause. The lowest monthly mean temperatures observed at the colder stations yield saturation mixing ratios that are consistent with the range of measured stratospheric water vapor. Examination of the daily variations in temperature at a given station reveals a more complex pattern than indicated by the monthly averages. On many days temperatures at the colder longitudes correspond to water vapor abundances that are less than observed in the stratosphere despite the favorable comparison of the monthly means. The results point to the need for a series of water vapor soundings at selected longitudes and times in order to define the extent to which the tropical tropopause controls the stratospheric water vapor abundance.

Frederick, J. E.↗

NASA NTRS1983

The distribution and annual cycle of ozone in the upper stratosphere

Study of the global distribution of upper stratospheric ozone derived from backscatter ultraviolet (BUV/SBUV) instruments on the Nimbus 4 and 7 satellites reveals the following characteristics for the period June 1970 May 1972 plus portions of 1978 and 1979. At pressures less than 5 mbar a local midlatitude maximum in the ozone mixing ratio develops in autumn and persists through the winter season in both hemispheres. However, by a pressure of 10 mbar the seasonal trend has reversed, with midlatitude summer values exceeding those in winter. The largest ozone mixing ratios in a global sense occur at tropical latitudes between pressures of 7 and 9 mbar. The general character of this pattern repeats from year to year, although differences in detail exist, especially in winter. This interannual variability in ozone increases the difficulty in extracting small long-term trends from the available data base. The overall seasonal pattern revealed by the measurements is in accord with photochemical model predictions which include the annual variation in temperature and solar illumination.

Frederick, J. E.↗