Engineering topics

Donn, B.

Publications and source records attributed to Donn, B..

At least 19 records

NASA NTRS1992

Columbus proto-planetesimal dust aggregation experiment

A microgravity experiment to study the growth of dust particles which has been proposed to be flown on one of the Columbus precursor flights is described. The microgravity environment will allow for low collision velocities (of order of mm/s) of the dust grains and for a large Knudsen number of the embedding gas; conditions expected in the early solar nebula. The outcome of the experiment will yield estimates of the sticking efficiency and the critical velocity for agglomeration. The values of these two parameters will provide substantial improvements in the constraints for models of the formation of planetesimals. In particular, the questions related to growth rate and mode of the aggregation process will be answered. The range of material type, collision velocities, properties of the environment in which growth takes place, and other factors permit a natural extension of this experiment to take advantage of the capabilities of the Space Station Columbus. Other astrophysical applications, such as processes in Saturnian rings, with somewhat different regimes could also be investigated.

Keller, H. U.↗

NASA NTRS1992

Comments on 'Gas release from comets' and related trapped-gas experiments

The numerous variables influencing trapped-gas experiment results based on cometary ice analogs are presently discussed in view of the Notesco et al. (1991) data on Kr-trapping and release by H2O ice. Attention is drawn to the questionable tennability of a linear relation proposed between the thickness of the ice and the gas retained beyond the amorphous-to-cubic phase change of H2O. Exacting care is required in the application of laboratory results to cometary phenomena, rendering definitive conclusions extremely elusive.

Hudson, R. L.↗

NASA NTRS1991

An experimental study of the sublimation of water ice and the release of trapped gases

The release of the more volatile component of the Ar/H2O, CO/H2O, and CO2/H2O mixtures presently studied during sublimation is found to occur in several discrete temperature regions; gas release correlates with IR spectrum changes of the solid ice. Relative peak intensities during warming are noted to depend on the initial gas/H2O ratio. The irradiation of CO- or CO2-containing ices respectively led to the release of CO2 and CO, as well as the initial species. The implications of these results for cometary behavior are discussed.

Hudson, R. L.↗

NASA NTRS1991

Studies of proton irradiated H2O + CO2 and H2O + CO ices and analysis of synthesized molecules

Infrared spectra of H2O + CO2 and H2O + CO ices before and after proton irradiation showed that a major reaction in both mixtures was the interconversion of CO2 yields CO. Radiation synthesized organic compounds such as carbonic acid were identified in the H2O + CO2 ice. Different chemical pathways dominate in the H2O + CO ice in which formaldehyde, methanol, ethanol, and methane were identified. Sublimed material was also analyzed using a mass spectrometer. Implications of these results are discussed in reference to comets.

Moore, M. H.↗

NASA NTRS1991

Primordial comet mantle - Irradiation production of a stable, organic crust

The thickness and survivability of a cosmic ray-generated primordial comet refractory mantle, or 'crust', are presently predicted by laboratory data and corrected estimates of cosmic ray dose to be capable of surviving a new comet's entry into the inner solar system over numerous revolutions. It is suggested that, since this mantle may be as much as several meters deep, the probe apparatus of the projected CRAF and Rosetta spacecraft will have to be extended in order to reach the desired, unprocessed cometary material. As things stand, there is a high probability that these missions will sample cometary matter than has been heavily irradiated and reprocessed in the Oort cloud.

Strazzulla, G.↗

NASA NTRS1991

From C/Mrkos to P/Halley: 30 years of cometary spectroscopy

An Atlas of Cometary Spectra was compiled, as a sequel to the well-known Atlas published by Swings and Haser in 1956. The new atlas comprises some 400 reproductions of cometary spectra secured in the world's largest observatories during the three decades or so from the passage of comet Mrkos 1957 V, for which the very first high-dispersion spectrum was obtained, to the return of Halley's comet. The illustrations refer to 40 different comet apparitions; they are grouped into a set of 186 loose 11 x 14 in. plates, while the texts, comments, and relevant data are given in a separate booklet. The main purpose of this atlas is to show in detail the tremendous progress which was achieved in cometary spectroscopy during the period covered, essentially thanks to the use of high-resolution coude spectrographs and large telescopes, the considerable extension of the observed wavelength range, and the advent of electronic detectors. It is divided into two parts. Part 1, which contains about two-thirds of the selected material, presents photographic spectra, while electronically recorded spectra covering the vacuum ultraviolet, through the optical, infrared, and radio regions appear in Part 2.

Arpigny, C.↗

NASA NTRS1990

FT-IR spectroscopic studies of polycyclic aromatic hydrocarbons

Proper assessment of the hypothesis which correlates polycyclic aromatic hydrocarbons (PAHs) with the unidentified infrared emission bands requires additional experimental laboratory data. In order to address this need, thermal infrared emission studies were performed on a subset of PAHs suggested to be of astrophysical importance. It was proposed that infrared emission from interstellar PAHs occurs following absorption of an ultraviolet photon. Since energy transfer to the ground electronic state can be rapid for a species in which intersystem crossing is negligible, the emission spectrum may be viewed as resulting from an equilibrium vibrational temperature (Leger and d'Hendecourt, 1987). This has been the basis for using infrared absorption spectra to calculate the corresponding emission spectra at various temperatures. These calculations were made using room temperature infrared absorption coefficients instead of those at the temperature of interest because of the latter's unavailability. The present studies are designed to address the differences between the calculated and experimental thermal emission spectra and to provide information which will be useful in future ultraviolet induced infrared fluorescence studies. The emission spectra have been obtained for temperatures up to 825K using an emission cell designed to mount against an external port of an FT-IR spectrometer. These spectra provide information concerning relative band intensities and peak positions which is unavailable from previous calculations.

Salisbury, D. W.↗

NASA NTRS1989

Oxygen isotopic fractionation in the condensation of refractory smokes

This paper reports preliminary measurements of the oxygen isotopic fractionation that occurs during the condensation of refractory metal oxide smokes. Fractionation occurred at temperatures in excess of 500 K during and/or subsequent to reaction of SiH4, Fe(CO)5, Al(CH3)3, and O2 in a H2 carrier gas. Observed isotopic fractionation was as high as -15 per mil/amu. The magnitude of the isotopic fractionation suggests that the process is kinetically controlled since the effect is greatly in excess of that expected for equilibrium isotopic exchange.

Nelson, R.↗

NASA NTRS1989

Collisions of macroscopic fluffy aggregates in the primordial solar nebula and the formation of planetesimals

The characteristics of submicron-size grains lead to the conclusion that, with relative velocities under tens of meters per second deduced for the early stages of accretion in the solar nebula, bodies of meter dimension, were low-density, compressible aggregates. The collision mechanism appropriate to such objects is explored here. The results of representative collisions are summarized which show that the penetration is only a fraction of the radius of the impacting body. Hence, all but near-grazing collisions lead to merger of the two bodies. Aggregate growth occurs without substantially increasing the mean density, but small region with densities about 60 percent of the bulk density will occur in a collision.

Donn, B.↗

NASA NTRS1988

Aerodynamic properties of fractal grains - Implications for the primordial solar nebula

Gas-grain and grain-grain interactions have a significant role in the evolution of the primordial solar nebula. There is also compelling evidence for larger grains in dense interstellar clouds than in the diffuse interstellar medium. In the usual treatments of grain collisions, where it is assumed that collisions produce compact bodies with a constant density, the gas drag decreases rapidly with size. The first step toward a quantitative analysis of the aerodynamic behavior of fractal aggregates is reported here, and it is shown that for fractals drag decreases very slowly.

Meakin, P.↗

NASA NTRS1988

Vaporization of ices containing S2 - Implications for comets

An effort is made to ascertain whether the S2 detected in Comet IRAS-Araki-Alcock 1983d can be stored in ices during warming, and is released during the vaporization of its water ice matrix, in view of data on the UV spectrum of S2 in Ar and Kr matrices and water ice in which the ratio of matrix or molecular ice to S2 is of the order of 500:1. The results obtained support the hypothesis that the S2:H2O ratio in the solid phase may not be a predictor of the gas phase ratio. It is concluded that similar vaporization from a cometary nucleus would not release most of the S2 contained in the ice.

Moore, M. H.↗

NASA NTRS1988

On PAHs as interstellar grains - Infrared absorption coefficients

Consideration is given to the proposal that PAHs are the source of IR continuum and emission features and the visible diffuse bands. Absolute IR cross-sections have been obtained for eight PAHs. The results show that a thermal continuum is not consistent with the spectra obtained, and that an array of normal molecules shows a spectrum that is more complex than the observed spectrum. The cross-sections of the UV spectra are 2-3 orders of magnitude larger than those of the IR spectra. It is suggested that, to account for these observations, structure must be produced in the UV extinction curve.

Salisbury, D. W.↗

NASA NTRS1988

Experimental studies of circumstellar, interstellar and interplanetary refractory grain analogs

Experimental techniques for studying the processes which occur during the life cycle of a refractory grain are reviewed. Consideration is given to the construction of a differentially-pumped beam-mass spectrometer which is expected to determine the relative stability of small clusters in the Fe-Mg-Si-O and Ca-Ti-Al-O systems as a function of temperature and pressure. Also, a smoke generator has been constructed to produce gram quantities of amorphous grains for use in thermal annealing and hydrous alteration studies of smokes containing Fe-Mg-Al-Ti-Ca-Si-O and Cl. Topics of the studies include the properties of grains produced in a flow condensation apparatus, the sorption efficiency of Si2O3 smokes for AR gas, the processing of ices containing refractory precursors such as SiH4 or Fe(CO)5 plus water, and the residue from 1 MeV bombardment and warming of an amorphous Fe-SiO smoke.

Nuth, J. A.↗

NASA NTRS1987

The fading of R Coronae Borealis

Using the International Ultraviolet Explorer (IUE) low-resolution spectra were obtained of R CrB, the prototype of its class of variable stars, shortly after the beginning of its 1983-84 minimum and during its rise to maximum again. The behavior of the spectra during the rise to maximum is similar to the behavior of the spectra of RY Sgr during a similar phase in 1979-80. The extinction data have been analyzed using Mie theory and are consistent with the stellar photosphere being obscured by 20-nm glassy carbon particles. The observations during the decline to minimum show substantial spectral variations which cannot be explained in terms of simple continuum absorption. An interpretation of the observed behavior in terms of a model incorporating an occulting cloud and circumstellar emission is offered.

Holm, A. V.↗

NASA NTRS1986

Atlas of Comet Halley 1910 II

An Atlas of Comet Halley 1910 II photographs and spectra is being prepared. The major section consists of 838 photographic observations from fifteen observatories around the world. Multiple images of many photographs are reproduced to bring out detail in the near nucleus region, in the coma and in the tail. The Atlas contains a total of 1209 photographic images of the 1910 apparition. In addition there are sections showing drawings from 1935 and 1910. A short section compares 1910 drawings and photographs. The final two sections display digitally processed images from 1910 and 1910 spectra. A three part appendix contains diagrams of various data associated with the 1910 apparition, a set of tables of all 1910 images and a bibliography.

Brandt, J. C.↗

NASA NTRS1986

Experimental studies of the vapor phase nucleation of refractory compounds. III - The condensation of silver

Measurements are reported of the critical supersaturation necessary to initiate the vapor phase nucleation of silver over the ambient temperature range 500-950 K at total pressures of 250 and 500 torr of hydrogen. The results are compared with the predictions of both classical nucleation theory and the theory of a physical spinodal developed by Rasmussen (1982), neither of which adequately describes the present observations. The nucleation of silver appears to be dependent on the total pressure of the system in a manner which suggests that three-body reactions are necessary in order to form the initial silver cluster (e.g., dimers) from the monoatomic vapor.

Nuth, J. A.↗

NASA NTRS1986

Hydrous alteration of amorphous silicate smokes - First results

Results of the initial studies of the hydrous alteration of amorphous Mg-SiO smokes indicate that, although these materials readily adsorb water, the silicate structure is much more stable at 360 K than expected. Drastic changes in the relative absorption strengths of the 10- and 20-micron 'silicate' features that appear quite rapidly at 750 K were observed; these observations might have important implications for the interpretation of cometary dust spectra. Observations of the development of 3.4-3.5 micron features possibly due to hydrocarbons in the spectra of processed Mg-SiO smokes have raised the exciting possibility that these amorphous condensates could act as Fischer-Tropsch type catalysts to produce hydrocarbons in the primitive solar nebula.

Nuth, J. A.↗

NASA NTRS1986

Experimental investigations relating to the properties and formation of cosmic grains

The interpretation of observations or theoretical analyses of interstellar processes requires a sound knowledge of relevant data. In many instances this can only be obtained by experiments carried out under appropriate conditions. The availability of such data applicable to the subject and the techniques for obtaining the data are surveyed.

Donn, B.↗