Engineering topics
Publications and source records attributed to Donahue, T. M..
The deuterium-hydrogen abundance ratio in the Venus atmosphere was measured while the inlets to the Pioneer Venus large probe mass spectrometer were coated with sulfuric acid from Venus' clouds. The ratio is 0.016 + or - 0.002. The hundredfold enrichment of deuterium means that at least 0.3 percent of a terrestrial ocean was outgassed on Venus, but is consistent with a much greater production.
Combined analysis of helium (584 A) airglow and the atmospheric occultations of the star delta Scorpii imply a vertical mixing parameter in Saturn's upper atmosphere of K (eddy diffusion coefficient) of approximately 8 x 10 to the 7th sq cm per second, an order of magnitude more vigorous than mixing in Jupiter's upper atmosphere. Atmospheric H2 band absorption of starlight yields a preliminary temperature of 400 K in the exosphere and a temperature near the homopause of 200 K. Certain auroral emissions can be fully explained in terms of electron impact on H2, and auroral morphology suggests a link between the aurora and the Saturn kilometric radiation. Absolute optical depths have been determined for the entire C ring and parts of the A and B rings. A new eccentric ringlet has been detected in the C ring. The extreme ultraviolet reflectance of the rings is fairly uniform at 3.5 to 5 percent. Collisions may control the distribution of H in Titan's H torus, which has a total vertical extent of about 14 Saturn radii normal to the orbit plane.
A simple model for the rapid escape of a hydrogen thermosphere is presented in order to establish the energy-limited flux of escaping particles. The model assumes that the atmosphere is tightly bound by gravity at the lower boundary, that all the EUV is absorbed in a narrow region where the optical depth is unity, and that the main source of heating is solar EUV. The flux is limited by the amount of EUV energy absorbed, which is in turn controlled by the radial extent of the thermosphere. It is found that, regardless of the amount of hydrogen in the thermosphere, the low temperatures which accompany rapid escape limit its extent and thus constrain the flux. The results are applied to the earth and Venus, showing that the escape of hydrogen from these planets would have been energy-limiting if their primordial atmospheres contained total hydrogen mixing ratios exceeding only a few percent. This conclusion places a constraint on the theory of the origin and evolution of the planets.
The observations of a number of objects by the Voyager EUV instruments are summarized. The summary is considered to demonstrate the wide ranging application of the EUV spectroscopy. It also marks an important step forward in spectrography and emphasizes the continuing importance of the search and discovery nature of spectroscopic techniques.
During the occultation of the star Regulus (B7 type) by Jupiter as seen from the Voyager 2 spacecraft on July 9, 1979, two absorbing regions were detected. Between 911 and 1200 A, H2 was absorbing over a 600 km altitude range. Above 1300 A, the rapid increase of the absorption by the hydrocarbons was observed over an altitude interval of approximately 100 km with a height resolution of 3 km. The analysis of these absorption features has provided the height profiles of molecular hydrogen, methane, ethane, and acetylene, as well as the thermal profile in the upper atmosphere of Jupiter. Combining the Voyager ultraviolet spectrometer results with other data, such as those obtained by the Voyager infrared and radioscience instruments, has yielded a comprehensive model of the composition and structure of the atmosphere of Jupiter.
The Voyager ultraviolet stellar occultation data yield a temperature of 200 + or - 50 K at about 400 km, and the solar occultation data give 1100 + or - 200 K at 1450 km above the ammonia cloud tops. The temperature gradient between 400 and 1450 km is approximately 1 K/km. The mesospheric temperature structure gives no strong indication of an earth-like mesopause. The heating of the upper atmosphere appears to result from a combination of magnetospheric charged particle precipitation, ion drag, inertia gravity waves, and solar EUV. The volume mixing ratios of CH4 and C2H6 at 325 km are measured to be 2.5(+3, -2) x 10 to the -5th and 2.5(+2.0, -1.5) x 10 to the -6th, respectively, which are lower than in the stratosphere. The C2H2 volume mixing ratio is not greater than 5 x 10 to the -6th at 300 km. The homopause value of the equatorial eddy diffusion coefficient is found to be 1-2 x 10 to the -6th sq cm/s.
The paper reports a determination by the Pioneer Venus large probe neutral mass spectrometer of upper limits to the concentration of krypton and xenon along with most of their isotopes in the atmosphere of Venus. The upper limit to the krypton mixing ratio is estimated at 47 ppb, with a very conservative estimate at 69 ppb. The probable upper limit to the sum of the mixing ratios of the isotopes Xe-128, Xe-129, Xe-130, Xe-131, and Xe-132 is 40 ppb by volume, with a very conservative upper limit three times this large.
The thermal structure of the upper atmosphere of Jupiter, the composition of the atmosphere and the strength of mechanical mixing, and sources and sinks of ionization in the Jupiter ionosphere are described from Voyager UV spectrometer, radio, IR, and imaging data. A topside ionospheric temperature of 1300 K was observed, along with an energy equilibrium between the plasma and neutral gas in the upper atmosphere. A composite thermal structure is provided, noting a close similarity to earth conditions at upper levels, and enhanced thermal behavior has been detected between the times of solar minimum and maximum activity. Ammonia photochemistry is examined, and measured concentrations of H2, CH4, C2H6, and C2H2 as a function of height are outlined. Eddy diffusion coefficient calculations are carried out, yielding a highest Ly-alpha intensity of 100 million sq cm/sec. The increased exospheric temperature between 1973 and 1980 is stressed to have no known satisfactory explanation.
An array of 5 autonomous spectrometers, the imaging spectrometric observatory covers a broad wavelength range (approximately 200 to 12,000 A), has a resolution selectable down to approximately 0.5 A, and a dynamic range of approximately 10 to the 7th power and is designed to select experiment measurement sequences by software control. Because current models of thermospheric ionic processes produce too much N2(+) ionization, the N2(+) reaction with O and the chemistry of metastable (N(+) ions and of O2(+) ions are objects of study on Spacelab 1.
Photochemical calculations based on recent data on the Saturn temperature structure and Lyman-alpha albedo indicate that detectable amounts of gaseous ammonia may exist between 20 and 35 km above the cloud tops. An instrument that might be able to observe this gas is the spectrometer on board the International Ultraviolet Explorer satellite. The calculations also yield a maximum nitrogen mixing ratio at the cloud tops between 1.8 x 10 to the -10th to 6 x 10 to the -8th by volume, depending upon the degree of supersaturation of ammonia and hydrazine. Even the lower limit could produce intense emissions if electrical discharges such as those observed on Jupiter by Voyager are also present on Saturn, or if high energy particles penetrate to the Saturnian troposphere.
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The extensive Voyager 2 EUV spectral observations of the Jovian planetary system have produced a number of significant results. The positions of the auroral zones have been defined with the aid of support imaging to the extent that the aurora is now known to correspond to the location of the planetary magnetic field lines intersecting the Io plasma torus. The observations do not preclude the possibility of a simultaneous magnetotail aurora, but if present it must not be a dominant component. Emission in molecular hydrogen has been detected from the equatorial regions of Jupiter, which indicates planetwide electron precipitation. Hydrogen Lyman alpha from the dark side of the planet has been measured at an intensity of about 1 kilorayleigh. Occultation of Alpha Leonis by Jupiter has been observed, and the data are being analyzed in detail.
A measurement of the neutral temperature in the exosphere of Jupiter is reported. The observations were carried out by the Voyager 1 Ultraviolet Spectrometer during the solar occultation phase beginning 4.5 hours after the Jupiter encounter. The range of the exospheric temperature is found to be 1450 (+300, -250) K. The uncertainty in the determination of the temperature appears to be largely a consequence of the lack of knowledge of the brightness distribution on the solar disk at the time of the observations. The high exospheric temperature appears to result from a combination of upward-propagating inertia gravity waves, magnetospheric soft electrons, and auroral electrons, including those from the Io-plasma torus.
Nitric oxide may be produced in the atmosphere of Venus by lightning storms in the clouds. The paper suggests that the odd nitrogen thus formed may play an important part in the chemistry of the clouds. Specifically, production rates for NO2 in the limiting case of high NO concentrations are estimated. If the NO density is high, it is suggested that NO2 may catalyse the production of sulfuric acid aerosol from sulfur dioxide and water vapor, and may also form nitrogen-sulfur compounds such as nitrosyl sulfuric acid, NOHSO4. The large partricles seen by the Pioneer Venus sounder probe may contain considerable quantities of NOHSO4. If this is the case, odd nitrogen must be present in the atmosphere in at least a parts-per-million mixing ratio.
Electron-density profiles measured for the daytime and nighttime Jovian ionosphere by the Voyager 1 radio-science experiment are analyzed. It is found that the measured profiles can be reproduced by using a model appropriate for an exospheric temperature of 1300 K with temperature varying above the homopause and with an eddy diffusion coefficient of 100,000 to 300,000 sq cm/s at the homopause. An overall rate constant of 4.3 x 10 to the -16th cu cm/s is estimated for the reaction H(+) + H2 (v-prime at least 4) yields H2(+) + H.
The composition of the Venusian atmosphere was studied using a mass spectrometer on the Pioneer Venus sounder probe. The single-focusing magnetic-sector spectrometer scanned the mass range from hydrogen through mercury with a dynamic range of six decades. Data taken by the mass spectrometer were compared with those of a gas chromatograph, resulting in slight discrepancies due to the use of a sputter ion pump acting as a sink for entry of rare gases through the inlet leak. A surprisingly large concentration of primordial Ar-36 and Ar-38 was discovered in a ratio of 5 to 1. It was concluded that the large excess of primordial argon was a valid result and that the mixing of HCl in the lower Venusian atmosphere was less than a few parts per million. Arguments against the sun as the source for excess primordial gases on Venus were presented. Concentrations of other elements such as Ne, Kr, He, S, and O were discussed. Although the mass peaks in the spectrum were real, it was not clear whether all of the chemical reactions (i.e., COS production) actually occurred in the atmosphere. Until further analysis can be made, it will be uncertain how the inlet system, which is at atmospheric temperature, affected the results.
Preliminary observations of day-night variations in the ion composition of the ionosphere of Venus, obtained by the Pioneer Venus Orbiter ion mass spectrometer experiment, are reported. A remarkable abundance and extent of ionization in the deep regions of the nightside ionosphere was observed, in spite of the long Venus night. A comparison of dayside and nightside ion distributions reveals a nightside composition similar in several respects to that of the dayside, with the ions O(+) and O2(+) forming the nightside F 2 and F 1 regions, respectively, as in the dayside. Important differences include a greater abundance of low-latitude ionization in the nightside, a significant increase of H(+) and NO(+) ions with increasing solar zenith angle, and extreme dynamic variability of the nightside region above 160 km. Ion composition data support the view that the nightside ionosphere can be maintained by the transport of ionization from the dayside.
The major photochemical sources and sinks for ten of the ions measured by the ion mass spectrometer on the Pioneer Venus bus and orbiter spacecraft that are consistent with the neutral gas composition measured on the same spacecraft are identified. The neutral gas temperature (as a function of solar zenith angle) derived from measured ion distributions in photochemical equilibrium is given. Above 200 kilometers, the altitude behavior of ions is generally controlled by plasma diffusion, with important modifications for minor ions due to thermal diffusion resulting from the observed gradients of plasma temperatures. The dayside equilibrium distributions of ions are sometimes perturbed by plasma convection, while lateral transport of ions from the dayside seems to be a major source of the nightside ionosphere.