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Dezafra, R.

Publications and source records attributed to Dezafra, R..

Hydrogen species

Measurements of the members of the HO(x) family (OH, HO2, and H2O2) and their major source gases, H2O, and CH4 are discussed. Emphasis is placed on measurements which were made since the 1982 World Meteorologic Organization (WMO) report. Measurement techniques, available data, an assessment of data reliability, and a comparison of the data with theoretical distributions of stratospheric HO(x) species predicted from one and two dimensional photochemical models are discussed.

Schiff, H. I.↗

Halogentated species

Stratospheric measurements of halogen containing species are reviewed and compared with model predictions. Halocarbons, HCl, HF, ClONO2, and ClO are discussed.

Molina, M. J.↗

Ground-based mm-wave emission spectroscopy for the detection and monitoring of stratospheric ozone

The molecular rotational spectrum of ozone is quite rich in the mm-wave region from 50 to 300 GHz. An apparatus, which was developed primarily for detection and measurement of stratospheric ClO and other trace molecules, is found to be well suited also for the observation of ozone lines. The collecting antenna of the apparatus is a simple mm-waveguide feedhorn. The detector is a superheterodyne mixer using a special high frequency Schottky diode and a klystron local oscillator. The spectrometer is a 256 channel filter bank with 1 MHz resolution per channel. The apparatus is believed to be the first ground-based mm-wave instrument having the capability of obtaining data of sufficient quality to make use of the inversion technique. The ground based radio technique is most sensitive to changes in vertical distribution in the region above 25 km, a region which is difficult to sample by other techniques.

Parrish, A.↗

Ground-based detection of stratospheric ClO and average column density measurement over 17 days of observation

A very sensitive mm-wave heterodyne receiver of a type originally developed for radio astronomy is used in combination with a broadband filter bank spectrometer to detect and measure the 204-GHz rotational transition of stratospheric ClO. Data is acquired in the form of a dimensionless ratio and is converted to units expressing signal intensity. Computed line shapes are matched against the data for a comparison with theoretical stratospheric models and previous measurements. The ClO distribution in the stratosphere measured at 42 deg N latitude in early spring is significantly different from that expected based on existing theoretical models. There is much less ClO at latitudes below about 36 km than predicted, and average ClO column density found for 42 deg N is 20-30% less than that from existing balloon flight measurements at 32 deg N.

Dezafra, R.↗