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Depaolo, D. J.

Publications and source records attributed to Depaolo, D. J..

Construction of mass-age curves for the continental crust: An empirical model and an example from the western US

The methodology of determining crustal mass-age curves is discussed. Problems in doing this include determination of model ages and accounting for mixing of materials of different ages during crust forming processes. These difficulties can be overcome with some reasonable assumptions and estimates of rock volumes based on areal proportions. This technique was used to construct a reasonably well constrained mass-age curve for the southwestern U.S. based on isotopic measurements on over 100 samples. The results imply that the crust in this area grew episodically at 2.8, 1.8, and 0.1 Ga. It is estimated that it would take on the order of 10000 to 100000 individual Sm-Nd isotopic measurements to carry out a similar exercise for continental crust world wide.

Depaolo, D. J.

The isotopic and chemical evolution of planets: Mars as a missing link

The study of planetary bodies has advanced to a stage where it is possible to contemplate general models for the chemical and physical evolution of planetary interiors, which might be referred to as UMPES (Unified Models of Planetary Evolution and Structure). UMPES would be able to predict the internal evolution and structure of a planet given certain input parameters such as mass, distance from the sun, and a time scale for accretion. Such models are highly dependent on natural observations because the basic material properties of planetary interiors, and the processes that take place during the evolution of planets are imperfectly understood. The idea of UMPES was particularly unrealistic when the only information available was from the earth. However, advances have been made in the understanding of the general aspects of planetary evolution now that there is geochemical and petrological data available for the moon and for meteorites.

Depaolo, D. J.

Sm-Nd isotope study of early Archean rocks, Qianan, Hebei Province, China

The geochronology of amphibolitic and gneiss rocks in the Qianan region in China is examined. Sm-Nd isotopic measurements were performed to determine if the rocks existed in the early Archean age. The average age for the amphibolite samples is 3.50 + or - 0.08 billion years with an initial epsilon(Nd) value of 3.3 + or - 0.3, and for the gneiss samples the average age is also 3.5 billion years. The high initial epsilon(Nd) value indicates that the mantle magma source is depleted of magmaphile elements and the geochemistry of the early Archean mantle is similar to the modern upper mantle.

Huang, X.

Isotopic constraints on planetary evolution

Direct observations are considered that have been made on terrestrial and lunar materials in the search for answers to questions such as: when did the major structural elements (core, mantle, and crust) come into being and evolved. Measurements of isotope ratios of Pb, Sr, Nd, Hf, Ar, and other elements provide information about the internal evolution of the earth and moon since their formation 4.5 Gyr ago. The existing evidence indicates the core formed more than 4.4 Gyr ago, possibly while the earth was still accreting. Though the moon crust is similarly very old, the moon ceased to differentiate after about 1 Gyr whereas earth differentiation has continued to the present. Cataclysmic episodes have occurred, the largest 2.8 Gyr ago, when about half of the present continental mass formed.

Depaolo, D. J.

Rb-Sr, Sm-Nd, K-Ca, O, and H isotopic study of Cretaceous-Tertiary boundary sediments, Caravaca, Spain Evidence for an oceanic impact site

The results of isotopic and trace-element-abundance analyses of Ir-enriched Cretaceous-Tertiary-boundary clay sediments from Caravaca, Spain, and of adjacent carbonate and marl layers, are presented. Acetic-acid and HCl leachates and residues were analyzed by isotope dilution to determine K, Rb, Sr, Sm, and Nd concentrations and Sr-87/Sr-86 and Nd-143/Nd-144 ratios. The stable isotope ratios delta-D, delta-(C-13), and delta-(0-18) were also determined. The results are presented in tables and graphs and compared with published data on the Caravaca sediments and on samples from other locations. The boundary clay is found to be distinguished from the adjacent layers by its isotopic ratios and to be of mainly terrestrial, lithospheric (deeper than 3-km) origin. Although submarine-weathering effects are evident and difficult to quantify, the degree of variation in Ni, Ir, Sr, and REE concentrations is considered too large to be attributed to postdepositional processes alone. These findings are seen as evidence for the ocean impact of a large single asteroid producing a worldwide blanket of ejecta, a large injection of water vapor into the atmosphere, and perhaps a gigantic tsunami, at the end of the Cretaceous period.

Depaolo, D. J.

Petrology, chemistry, age and irradiation history of Luna 24 samples

The results of petrological, chemical, isotopic age determination and irradiation studies of sample 24170 from the 170 cm depth of the regolith core returned from Mare Crisium by Luna 24 are presented. The sample is found to be comprised of fragments from a single igneous rock, with mineralogical evidence indicating it to be a mare basalt. The crystallization age is determined by Sm-Nd and Ar(40)-Ar(39) ages to be 3.30 AE, establishing the presence of relatively young flows. All soil samples show low trace element compositions with minimum contamination by KREEPUTh-rich materials. Rb-Sr and Sm-Nd relations reflect the absence of significant fractionation at ages younger than 4.5 AE. One soil sample shows extremely large neutron capture effects, imposing a new lower limit to the neutron production rate in the regolith and requiring the addition of irradiated materials from depth.

Wasserburg, G. J.

Rb-Sr and Sm-Nd chronology and genealogy of mare basalts from the Sea of Tranquility

Rb-Sr and Sm-Nd ages of two Apollo 11 mare basalts, high-K basalt 10072 and low-K basalt 10062, are reported. Rb-Sr, Sm-Nd, and Ar-40-Ar-39 ages are in good agreement and indicate an extensive time interval for filling of the Sea of Tranquility, presumably by thin lava flows, in agreement with similar observations for the Ocean of Storms. Initial Sr and Nd isotopic compositions on Apollo 11 basalts reveal at least two parent sources producing basalts. The Sm-Nd isotopic data demonstrate that low-K and high-Ti basalts from Apollo 11 and 17 derived from distinct reservoirs, while low-Ti Apollo 15 mare basalt sources have Sm/Nd similar to the sources of Apollo 11 basalts. Groupings of mare basalt based on Ti content and on isotopic data do not coincide.

Papanastassiou, D. A.

Inferences about magma sources and mantle structure from variations of Nd-143/Nd-144

Continental flood basalts and mid-ocean ridge (MOR) tholeiitic basalts have distinctly different Nd-143/Nd-144 which may permit a priori distinction between continental and oceanic igneous rocks. Initial Nd-143/Nd-144 of continental igneous rocks through time fall on a Sm/Nd evolution curve with chondritic REE abundance ratio. These observations indicate that many continental igneous rocks are derived from a reservoir with chondritic REE pattern which may represent primary material remaining since the formation of the earth. Oceanic igneous rocks are derived from a different ancient reservoir which has Sm/Nd higher than chondritic. Initial Nd-143/Nd-144 and Sr-87/Sr-86 in young basalts from both oceans and continents show a strong correlation suggesting that Sm-Nd and Rb-Sr fractionation events in the mantle may be correlative and caused by the same process. From this correlation Rb/Sr for the earth is inferred to be 0.029.

Depaolo, D. J.

Nd isotopic variations and petrogenetic models

The isotopic composition of Nd in selected terrestrial rocks is investigated to gain information about its implications for petrogenesis and the history of the earth's crust and mantle. Chemical and mass-spectrometric measurements of the Nd-143/Nd-144 ratio in terrestrial rocks of different ages show that the Sm/Nd ratio and the rare-earth-element (REE) abundance pattern are equal within a few per cent to those of chondritic meteorites. Variations in the Nd isotopic ratio in young basalts are found to permit the identification of distinctive mantle sources and to indicate the preservation of significant heterogeneities in the mantle for times of 1 to 4 billion years ago. The isotopic data also show that mantle source regions with a Sm/Nd ratio which differs from the chondritic value by a factor of two are not preserved for more than a few hundred million years. The average continental crust material is found to have a much lower isotopic ratio than the mantle, reflecting the crust's low Sm/Nd ratio resulting from REE fractionation during crust formation from the mantle.

Depaolo, D. J.