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Cunnington, G. R.

Publications and source records attributed to Cunnington, G. R..

At least 19 records

Chemical vapor deposition coatings for oxidation protection of titanium alloys

Results of an experimental investigation of the oxidation protection afforded to Ti-14Al-21Nb and Ti-14Al-23Nb-2V titanium aluminides and Ti-17Mo-3Al-3Nb titanium alloy by aluminum-boron-silicon and boron-silicon coatings are presented. These coatings are applied by a combination of physical vapor deposition (PVD) and chemical vapor deposition (CVD) processes. The former is for the application of aluminum, and the latter is for codeposition of boron and silicon. Coating thickness is in the range of 2 to 7 microns, and coating weights are 0.6 to 2.0 mg/sq cm. Oxidation testing was performed in air at temperatures to 1255 K in both static and hypersonic flow environments. The degree of oxidation protection provided by the coatings is determined from weight change measurements made during the testing and post test compositional analyses. Temperature-dependent total normal emittance data are also presented for four coating/substrate combinations. Both types of coatings provided excellent oxidation protection for the exposure conditions of this investigation. Total normal emittances were greater than 0.80 in all cases.

Cunnington, G. R.

Non-catalytic coatings for hypersonic vehicle applications

CVD coatings of boron-oxygen-silicon and aluminum-boron-oxygen and silicon compositions were applied to alpha 2 and gamma titanium-aluminide alloys, and tested under simulated earth reentry conditions to evaluate oxidation protection, recombination effifiency and total emittance under cyclic exposures between temperatures of 300 and 1255 K. The degree of oxidation protection afforded to the alloys was evaluated from the amount of specimen weight gain after a 100 hour exposure to air at atmospheric pressure and at a temperature of 1255 K. Data are presented for two types of coatings, a monolithic and a multilayer, which have recombination efficiencies from 0.005 to 0.020 after ten one-half hour long simulated reentry cycles. Total normal emittance was 0.80 or greater and weight gain was less than 10 g/sq m both coating types. Compositional and morphological changes resulting from the exposures are discussed in relation to time-dependent variations in recombination efficiency.

Cunnington, G. R.

Radiative properties of advanced spacecraft heat shield materials

Experimental results are presented to show the effects of simulated reentry exposure by convective heating and by radiant heating on spectral and total emittance of statically oxidized Inconel 617 and Haynes HS188 superalloys to 1260 K and a silicide coatea (R512E) columbium 752 alloy to 1590 K. Convective heating exposures were conducted in a supersonic arc plasma wind tunnel using a wedge-shaped specimen configuration. Radiant tests were conducted at a pressure of .003 atmospheres of dry air at a flow velocity of several meters per second. Convective heating specimens were subjected to 8, 20, and 38 15-min heating cycles, and radiant heating specimens were tested for 10, 20, 50, and 100 30-min heating cycles. Changes in radiative properties are explained in terms of changes in composition resulting from simulated reentry tests. The methods used to evaluate morphological, compositional and crystallographic changes include: Auger electron spectroscopy; scanning electron microscopy; X-ray diffraction analysis; and electron microprobe analysis.

Cunnington, G. R.

Radiative properties of a nickel based superalloy: Inconel 617 - After simulated earth reentry

Experimental results are presented to show the effect of environmental simulation exposures of convective heating and of radiant heating on the spectral (1.0 to 14 micrometers) and total emittance of oxidized Inconel 617. Convective heating exposures were conducted in an arc heated supersonic wind tunnel using a wedge-shaped specimen configuration. Radiant tests were conducted in dry air at a flow velocity of several meters per second. Convective heating specimens were subjected to 8, 20 and 38 heating cycles of 15-minutes duration and radiant heating specimens were tested for 10, 20, 50 and 100 one-half hour heating cycles. Changes in radiative properties are discussed in terms of changes in composition and morphology resulting from the exposure tests. Total normal emittance did not significantly change from the statically oxidized condition after either type of exposure, and it remained above 0.80 at 1260K for all cases. Although spectral changes were observed on post exposure specimens at wavelengths less than 2.0 micrometers and greater than 15 micrometers, these changes have no influence on total emittance at 1260K.

Cunnington, G. R.

Conceptual design and analysis of orbital cryogenic liquid storage and supply systems

A wide variety of orbital cryogenic liquid storage and supply systems are defined in NASA and DOD long-range plans. These systems include small cooling applications, large chemical and electrical orbit transfer vehicles and supply tankers. All have the common requirements of low-g fluid management to accomplish gas-free liquid expulsion and efficient thermal control to manage heat leak and tank pressure. A preliminary design study was performed to evaluate tanks ranging from 0.6 to 37.4 cu m (22 to 1320 cu ft). Liquids of interest were hydrogen, oxygen, methane, argon and helium. Conceptual designs were generated for each tank system and fluid dynamic, thermal and structural analyses were performed for Shuttle compatible operations. Design trades considered the paradox of conservative support structure and minimum thermal input. Orbital performance and weight data were developed, and a technology evaluation was completed.

Eberhardt, R. N.

Evacuated load-bearing high performance insulation study

A light weight, vacuum jacketed, load bearing cryogenic insulation system was developed and tested on a 1.17-m (46-in.) spherical test tank. The vacuum jacket consists of 0.08 mm (0.003 in.) thick 321 stainless steel formed into a wedge design that allows elastic jacket movements as the tank shrinks (cools) or expands (warms up or is pressurized). Hollow glass spheres, approximately 80 micrometers in diameter with a bulk density of 0.069 g/cc (4.3 lb cubic foot), provide the insulating qualities and one atmosphere load bearing capability required. The design, fabrication, and test effort developed the manufacturing methods and engineering data needed to scale the system to other tank sizes, shapes, and applications. The program demonstrated that thin wall jackets can be formed and welded to maintain the required vacuum level of .013 Pa yet flex elastically for multiple reuses. No significant shifting or breakage of the microspheres occurred after 13 simulated Space Tug flight cycles on the test tank and a hundred 1 atmosphere load cycles in a flat plate calorimeter. The test data were then scaled to the Space Tug LO2 and LH2 tanks, and weight, thermal performance, payload performance, and costs were compared with a helium purged multilayer insulation system.

Parmley, R. T.

Thermal performance of multilayer insulations

Experimental and analytical studies were conducted in order to extend previous knowledge of the thermal performance and gas evacuation characteristics of three selected multilayer insulation (MLI) composites. Flat plate calorimeter heat flux measurements were obtained for 20- and 80- shield specimens using three representative layer densities over boundary temperatures ranging from 39 K (70 R) to 389 K (700 R). Laboratory gas evacuation tests were performed on representative specimens of each MLI composite after initially purging them with helium, nitrogen, or argon gases. In these tests, the specimens were maintained at temperatures between 128 K (230 R) and 300 K (540 R). Based on the results of the laboratory-scale tests, a composite MLI system consisting of 112 unperforated, double-aluminized Mylar reflective shields and 113 water preconditioned silk net spacer pairs was fabricated and installed on a 1.22-m-(4-ft-) diameter calorimeter tank.

Keller, C. W.

Development of techniques and associated instrumentation for high temperature emissivity measurements

Studies were made to develop a test apparatus for the measurement of total emittance of materials under repeated exposure to simulated earth entry conditions. As no existing test facility met the emittance measurement and entry simulation goals, a new apparatus was designed, fabricated and checked out. This apparatus has the capability of performing total and spectral emittance measurements during cyclic temperature and pressure exposure under sonic and supersonic flow conditions. Emittance measurements were performed on a series of oxidized superalloys, silicide coated columbium alloys and ceramic coatings.

Cunnington, G. R.

Development of techniques and associated instrumentation for high temperature emissivity measurements

The calibrating and testing procedures for the radiometric emittance measurement apparatus are described. Test results are given for the NBS platinum-rhodium standard (SRM No. 1409), the NBS oxidized Kanthal standard, and the oxidized Rene 41 materials. Results indicate that with the platinum-rhodium standard the measurement system compared with the NBS data to within 0.02 for both total and spectral normal emitttance. Data from the Kanthal strip was consistently higher than NBS values. For oxidized Rene 41, no significant changes in as prepared emittance was observed. The emittance was stable for temperatures up to 1150 K.

Cunnington, G. R.

Development of techniques and associated instrumentation for high temperature emissivity measurements

The progress during the sixth quarterly period is reported on construction and assembly of a test facility to determine the high temperature emittance properties of candidate thermal protection system materials for the space shuttle. This facility will provide simulation of such reentry environment parameters as temperature, pressure, and gas flow rate to permit studies of the effects of these parameters on the emittance stability of the materials. Also reported are the completed results for emittance tests on a set of eight Rene 41 samples and one anodized titanium alloy sample which were tested at temperatures up to 1600 F in vacuum. The data includes calorimetric determinations of total hemispherical emittance, radiometric determinations of total and spectral normal emittance, and pre- and post-test room temperature reflectance measurements.

Cunnington, G. R.

Infrared radiation of thin plastic films.

A combined analytical and experimental study is presented for infrared radiation characteristics of thin plastic films with and without a metal substrate. On the basis of the thin-film analysis, a simple analytical technique is developed for determining band-averaged optical constants of thin plastic films from spectral normal transmittance data for two different film thicknesses. Specifically, the band-averaged optical constants of polyethylene terephthalate and polyimide were obtained from transmittance measurements of films with thicknesses in the range of 0.25 to 3 mil. The spectral normal reflectance and total normal emittance of the film side of singly aluminized films are calculated by use of optical constants; the results compare favorably with measured values.

Tien, C. L.