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Cornish, T.

Publications and source records attributed to Cornish, T..

10 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

Two-Step Resonance-Enhanced Desorption Laser Mass Spectrometry for In Situ Analysis of Organic-Rich Environments

A wide diversity of planetary surfaces in the solar system represent high priority targets for in situ compositional and contextual analysis as part of future missions. The planned mission portfolio will inform our knowledge of the chemistry at play on Mars, icy moons, comets, and primitive asteroids, which can lead to advances in our understanding of the interplay between inorganic and organic building blocks that led to the evolution of habitable environments on Earth and beyond. In many of these environments, the presence of water or aqueously altered mineralogy is an important indicator of habitable environments that are present or may have been present in the past. As a result, the search for complex organic chemistry that may imply the presence of a feedstock, if not an inventory of biosignatures, is naturally aligned with targeted analyses of water-rich surface materials. Here we describe the two-step laser mass spectrometry (L2MS) analytical technique that has seen broad application in the study of organics in meteoritic samples, now demonstrated to be compatible with an in situ investigation with technique improvements to target high priority planetary environments as part of a future scientific payload. An ultraviolet (UV) pulsed laser is used in previous and current embodiments of laser desorption/ionization mass spectrometry (LDMS) to produce ionized species traceable to the mineral and organic composition of a planetary surface sample. L2MS, an advanced technique in laser mass spectrometry, is selective to the aromatic organic fraction of a complex sample, which can provide additional sensitivity and confidence in the detection of specific compound structures. Use of a compact two-step laser mass spectrometer prototype has been previously reported to provide specificity to key aromatic species, such as PAHs, nucleobases, and certain amino acids. Recent improvements in this technique have focused on the interaction between the mineral matrix and the organic analyte. The majority of planetary targets of astrobiological interest are characterized by the presence of water or hydrated mineral phases. Water signatures can indicate a history of available liquid water that may have played an important role in the chemical environment of these planetary surfaces and subsurfaces. The studies we report here investigate the influence of water content on the detectability of organics by L2MS in planetary analog samples.

primitive asteroids↗
NASA NTRS2014

Development of a Linear Ion Trap Mass Spectrometer (LITMS) Investigation for Future Planetary Surface Missions

Future surface missions to Mars and other planetary bodies will benefit from continued advances in miniature sensor and sample handling technologies that enable high-performance chemical analyses of natural samples. Fine-scale (approx.1 mm and below) analyses of rock surfaces and interiors, such as exposed on a drill core, will permit (1) the detection of habitability markers including complex organics in association with their original depositional environment, and (2) the characterization of successive layers and gradients that can reveal the time-evolution of those environments. In particular, if broad-based and highly-sensitive mass spectrometry techniques could be brought to such scales, the resulting planetary science capability would be truly powerful. The Linear Ion Trap Mass Spectrometer (LITMS) investigation is designed to conduct fine-scale organic and inorganic analyses of short (approx.5-10 cm) rock cores such as could be acquired by a planetary lander or rover arm-based drill. LITMS combines both pyrolysis/gas chromatograph mass spectrometry (GCMS) of sub-sampled core fines, and laser desorption mass spectrometry (LDMS) of the intact core surface, using a common mass analyzer, enhanced from the design used in the Mars Organic Molecule Analyzer (MOMA) instrument on the 2018 ExoMars rover. LITMS additionally features developments based on the Sample Analysis at Mars (SAM) investigation on MSL and recent NASA-funded prototype efforts in laser mass spectrometry, pyrolysis, and precision subsampling. LITMS brings these combined capabilities to achieve its four measurement objectives: (1) Organics: Broad Survey Detect organic molecules over a wide range of molecular weight, volatility, electronegativity, concentration, and host mineralogy. (2) Organic: Molecular Structure Characterize internal molecular structure to identify individual compounds, and reveal functionalization and processing. (3) Inorganic Host Environment Assess the local chemical/mineralogical makeup of organic host phases to help determine deposition and preservation factors. (4) Chemical Stratigraphy Analyze the fine spatial distribution and variation of key species with depth.

Mars↗
NASA NTRS2012

Laser Time-of-Flight Mass Spectrometry for Future In Situ Planetary Missions

Laser desorption/ionization time-of-flight mass spectrometry (LD-TOF-MS) is a versatile, low-complexity instrument class that holds significant promise for future landed in situ planetary missions that emphasize compositional analysis of surface materials. Here we describe a 5kg-class instrument that is capable of detecting and analyzing a variety of analytes directly from rock or ice samples. Through laboratory studies of a suite of representative samples, we show that detection and analysis of key mineral composition, small organics, and particularly, higher molecular weight organics are well suited to this instrument design. A mass range exceeding 100,000 Da has recently been demonstrated. We describe recent efforts in instrument prototype development and future directions that will enhance our analytical capabilities targeting organic mixtures on primitive and icy bodies. We present results on a series of standards, simulated mixtures, and meteoritic samples.

Getty, S. A.↗
NASA NTRS2012

A Miniature Laser Desorption/Ionization Time-of-Flight Mass Spectrometer for in Situ Analysis of Mars Surface Composition and Identification of Hazard in Advance of Future Manned Exploration

Future landed missions to Mars will be guided by two strategic directions: (1) sample return to Earth, for comprehensive compositional analyses, as recommended by the 2011 NRC Planetary Decadal Survey; and (2) preparation for human exploration in the 2030s and beyond, as laid out by US space policy. The resultant mission architecture will likely require high-fidelity in situ chemical/organic sample analyses within an extremely constrained resource envelope. Both science goals (e.g., MEPAG Goal 1, return sample selection, etc.) as well as identification of any potential toxic and biological hazards to humans, must be addressed. Over the past several years of instrument development, we have found that the adaptable, compact, and highly capable technique of laser desorption/ionization time-of-flight mass spectrometry (LD-TOF-MS) has significant potential to contribute substantially to these dual objectives. This concept thus addresses Challenge Area 1: instrumentation and Investigation Approaches.

Getty, S. A.↗
NASA NTRS2011

Planetary Radar Imaging with the Deep-Space Network's 34 Meter Uplink Array

A coherent Uplink Array consisting of two or three 34-meter antennas of NASA's Deep Space Network has been developed for the primary purpose of increasing EIRP at the spacecraft. Greater EIRP ensures greater reach, higher uplink data rates for command and configuration control, as well as improved search and recovery capabilities during spacecraft emergencies. It has been conjectured that Doppler-delay radar imaging of lunar targets can be extended to planetary imaging, where the long baseline of the uplink array can provide greater resolution than a single antenna, as well as potentially higher EIRP. However, due to the well known R4 loss in radar links, imaging of distant planets is a very challenging endeavor, requiring accurate phasing of the Uplink Array antennas, cryogenically cooled low-noise receiver amplifiers, and sophisticated processing of the received data to extract the weak echoes characteristic of planetary radar. This article describes experiments currently under way to image the planets Mercury and Venus, highlights improvements in equipment and techniques, and presents planetary images obtained to date with two 34 meter antennas configured as a coherently phased Uplink Array.

uplink array↗
NASA NTRS2011

Planetary Radar Imaging with the Deep-Space Network's 34 Meter Uplink Array

A coherent uplink array consisting of up to three 34-meter antennas of NASA's Deep Space Network has been developed for the primary purpose of increasing EIRP at the spacecraft. Greater EIRP ensures greater reach, higher uplink data rates for command and configuration control, as well as improved search and recovery capabilities during spacecraft emergencies. It has been conjectured that Doppler-delay radar imaging of lunar targets can be extended to planetary imaging, where the long baseline of the uplink array can provide greater resolution than a single antenna, as well as potentially higher EIRP. However, due to the well known R-4 loss in radar links, imaging of distant planets is a very challenging endeavor, requiring accurate phasing of the Uplink Array antennas, cryogenically cooled low-noise receiver amplifiers, and sophisticated processing of the received data to extract the weak echoes characteristic of planetary radar. This article describes experiments currently under way to image the planets Mercury and Venus, highlights improvements in equipment and techniques, and presents planetary images obtained to date with two 34 meter antennas configured as a coherently phased Uplink Array.

imaging↗
NASA NTRS2008

Uplink Array Concept Demonstration with the EPOXI Spacecraft

Uplink array technology is currently being developed for NASA's Deep Space Network (DSN) to provide greater range and data throughput for future NASA missions, including manned missions to Mars and exploratory missions to the outer planets, the Kuiper belt, and beyond. Here we describe a novel technique for generating the frequency predicts that are used to compensate for relative Doppler, derived from interpolated earth position and spacecraft ephemerides. The method described here guarantees velocity and range estimates that are consistent with each other, hence one can always be recovered from the other. Experimental results have recently proven that these frequency predicts are accurate enough to maintain the phase of a three element array at the EPOXI spacecraft for three hours. Previous methods derive frequency predicts directly from interpolated relative velocities. However, these velocities were found to be inconsistent with the corresponding spacecraft range, meaning that range could not always be recovered accurately from the velocity predicts, and vice versa. Nevertheless, velocity-based predicts are also capable of maintaining uplink array phase calibration for extended periods, as demonstrated with the EPOXI spacecraft, however with these predicts important range and phase information may be lost. A comparison of the steering-vector method with velocity-based techniques for generating precise frequency predicts specifically for uplink array applications is provided in the following sections.

spacecraft uplink commands↗