Engineering topics

Chen, Yang

Publications and source records attributed to Chen, Yang.

141 records · Page 8

DOE OSTI2014

Shedding Light on the Photochemistry of Coinage-Metal Phosphorescent Materials: A Time-Resolved Laue Diffraction Study of an Ag I -Cu I Tetranuclear Complex

The triplet excited state of a new crystalline form of a tetranuclear coordination d 10 –d 10 -type complex, Ag 2 Cu 2 L 4 (L = 2-diphenylphosphino-3-methylindole ligand), containing Ag I and Cu I metal centers has been explored using the Laue pump–probe technique with ≈80 ps time resolution. The relatively short lifetime of 1 μs is accompanied by significant photoinduced structural changes, as large as the Ag1···Cu2 distance shortening by 0.59(3) Å. The results show a pronounced strengthening of the argentophilic interactions and formation of new Ag···Cu bonds on excitation. Theoretical calculations indicate that the structural changes are due to a ligand-to-metal charge transfer (LMCT) strengthening the Ag···Ag interaction, mainly occurring from the methylindole ligands to the silver metal centers. QM/MM optimizations of the ground and excited states of the complex support the experimental results. Comparison with isolated molecule optimizations demonstrates the restricting effect of the crystalline matrix on photoinduced distortions. The work represents the first time-resolved Laue diffraction study of a heteronuclear coordination complex and provides new information on the nature of photoresponse of coinage metal complexes, which have been the subject of extensive studies.

Jarzembska, Katarzyna N.↗

DOE OSTI2014

Global Validation of a Process-Based Model on Vegetation Gross Primary Production Using Eddy Covariance Observations

Gross Primary Production (GPP) is the largest flux in the global carbon cycle. However, large uncertainties in current global estimations persist. In this study, we examined the performance of a process-based model (Integrated BIosphere Simulator, IBIS) at 62 eddy covariance sites around the world. Our results indicated that the IBIS model explained 60% of the observed variation in daily GPP at all validation sites. Comparison with a satellite-based vegetation model (Eddy Covariance-Light Use Efficiency, EC-LUE) revealed that the IBIS simulations yielded comparable GPP results as the EC-LUE model. Global mean GPP estimated by the IBIS model was 107.50±1.37 Pg C year-1 (mean value ± standard deviation) across the vegetated area for the period 2000–2006, consistent with the results of the EC-LUE model (109.39±1.48 Pg C year-1). To evaluate the uncertainty introduced by the parameter Vcmax, which represents the maximum photosynthetic capacity, we inversed Vcmax using Markov Chain-Monte Carlo (MCMC) procedures. Using the inversed Vcmax values, the simulated global GPP increased by 16.5 Pg C year-1, indicating that IBIS model is sensitive to Vcmax, and large uncertainty exists in model parameterization.

Science & Technology - Other Topics↗

DOE OSTI2014

FY2014 FES (Fusion Energy Sciences) Theory & Simulation Performance Target, Final Report

We report here the work done for the FY14 OFES Theory Performance Target as given below: "Understanding alpha particle confinement in ITER, the world's first burning plasma experiment, is a key priority for the fusion program. In FY 2014, determine linear instability trends and thresholds of energetic particle-driven shear Alfven eigenmodes in ITER for a range of parameters and profiles using a set of complementary simulation models (gyrokinetic, hybrid, and gyrofluid). Carry out initial nonlinear simulations to assess the effects of the unstable modes on energetic particle transport". In the past year (FY14), a systematic study of the alpha-driven Alfven modes in ITER has been carried out jointly by researchers from six institutions involving seven codes including the transport simulation code TRANSP (R. Budny and F. Poli, PPPL), three gyrokinetic codes: GEM (Y. Chen, Univ. of Colorado), GTC (J. McClenaghan, Z. Lin, UCI), and GYRO (E. Bass, R. Waltz, UCSD/GA), the hybrid code M3D-K (G.Y. Fu, PPPL), the gyro-fluid code TAEFL (D. Spong, ORNL), and the linear kinetic stability code NOVA-K (N. Gorelenkov, PPPL). A range of ITER parameters and profiles are specified by TRANSP simulation of a hybrid scenario case and a steady-state scenario case. Based on the specified ITER equilibria linear stability calculations are done to determine the stability boundary of alpha-driven high-n TAEs using the five initial value codes (GEM, GTC, GYRO, M3D-K, and TAEFL) and the kinetic stability code (NOVA-K). Both the effects of alpha particles and beam ions have been considered. Finally, the effects of the unstable modes on energetic particle transport have been explored using GEM and M3D-K.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2014

Physical nature of the [S II]-bright shell nebulae N70 and N185

N70 and N185 are two large (≥100 pc in diameter) shell nebulae in the Large Magellanic Cloud (LMC). Their high [S II]/Hα ratios rival those of supernova remnants (SNRs), but they are not confirmed as SNRs. To study their physical nature, we have obtained XMM-Newton X-ray observations and high-dispersion long-slit echelle spectroscopic observations of these two nebulae. The X-ray spectra of both nebulae can be well interpreted with an optically thin thermal (∼0.2 keV) plasma with the average LMC abundance in a collisional ionization equilibrium. N70 encompasses the OB association LH114. Although N70 has a modest expansion velocity and essentially thermal radio emission, its diffuse X-ray luminosity (∼6.1 × 10{sup 35} erg s{sup –1}) is higher than that from a quiescent superbubble with N70's density, size, and expansion velocity; thus, N70 is most likely a superbubble that is recently energized by an interior SNR. N185 does not contain any known OB association, and its X-ray luminosity is an order of magnitude lower than expected if it is a quiescent superbubble. N185 has nonthermal radio emission and has high-velocity material expanding at nearly 200 km s{sup –1}, similar to many known SNRs in the LMC. Its X-ray luminosity (∼1.9 × 10{sup 35} erg s{sup –1}) is also consistent with that of an evolved SNR. We therefore suggest that N185 is energized by a recent supernova.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

An XMM-Newton study of the mixed-morphology supernova remnant W28 (G6.4–0.1)

We have performed an XMM-Newton imaging and spectroscopic study of supernova remnant (SNR) W28, a prototype mixed-morphology or thermal composite SNR believed to be interacting with a molecular cloud. The observed hot X-ray emitting plasma is characterized by low metal abundances, showing no evidence of ejecta. The X-rays arising from the deformed northeastern shell consist of a thermal component with a temperature of ∼0.3 keV plus a hard component of either thermal (temperature ∼0.6 keV) or non-thermal (photon index = 0.9-2.4) origin. The X-ray emission in the SNR interior is blobby and the corresponding spectra are best described as the emission from a cold (∼0.4 keV) plasma in non-equilibrium ionization with an ionization timescale of ∼4.3 × 10{sup 11} cm{sup –3} s plus a hot (∼0.8 keV) gas in collisional ionization equilibrium. Applying the two-temperature model to the smaller central regions, we find non-uniform interstellar absorption, temperature, and density distribution, which indicates that the remnant is evolving in a non-uniform environment with denser material in the east and north. The cloudlet evaporation mechanism can essentially explain the properties of the X-ray emission in the center, and thermal conduction may also play a role for length scales comparable to the remnant radius. A recombining plasma model with an electron temperature of ∼0.6 keV is also feasible for describing the hot central gas with the recombination age of the gas estimated at ∼2.9 × 10{sup 4} yr.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

Molecular environment of the supernova remnant IC 443: Discovery of the molecular shells surrounding the remnant

We have carried out {sup 12}CO, {sup 13}CO, and C{sup 18}O observations toward the mixed morphology supernova remnant (SNR) IC 443. The observations cover a 1.°5 × 1.°5 area and allow us to investigate the overall molecular environment of the remnant. Some northern and northeastern partial shell structure of CO gas is around the remnant. One of the partial shells, about 5' extending beyond the northeastern border of the remnant's bright radio shell, seems to just confine the faint radio halo. On the other hand, some faint CO clumps can be discerned along the eastern boundary of the faint remnant's radio halo. Connecting the eastern CO clumps, the northeastern partial shell structures, and the northern CO partial shell, we can see that a half molecular ring structure appears to surround the remnant. The LSR velocity of the half-ring structure is in the range of –5 km s{sup –1} to –2 km s{sup –1}, which is consistent with that of the –4 km s{sup –1} molecular clouds. We suggest that the half-ring structure of the CO emission at V {sub LSR} ∼ –4 km s{sup –1} is associated with the SNR. The structures are possibly swept up by the stellar winds of SNR IC 443's massive progenitor. Based on the Wide-field Infrared Survey Explorer and the Two Micron All Sky Survey near-IR database, 62 young stellar object (YSO) candidates are selected within the radio halo of the remnant. These YSO candidates concentrated along the boundary of the remnant's bright radio shell are likely to be triggered by the stellar winds from the massive progenitor of SNR IC 443.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

STRUCTURE AND MORPHOLOGY OF X-RAY-SELECTED ACTIVE GALACTIC NUCLEUS HOSTS AT 1 < z < 3 IN THE CANDELS-COSMOS FIELD

We analyze morphologies of the host galaxies of 35 X-ray-selected active galactic nuclei (AGNs) at z ∼ 2 in the Cosmic Evolution Survey field using Hubble Space Telescope/WFC3 imaging taken from the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey. We build a control sample of 350 galaxies in total by selecting 10 non-active galaxies drawn from the same field with a similar stellar mass and redshift for each AGN host. By performing two-dimensional fitting with GALFIT on the surface brightness profile, we find that the distribution of the Sérsic index (n) of AGN hosts does not show a statistical difference from that of the control sample. We measure the nonparametric morphological parameters (the asymmetry index A, the Gini coefficient G, the concentration index C, and the M {sub 20} index) based on point-source-subtracted images. All the distributions of these morphological parameters of AGN hosts are consistent with those of the control sample. We finally investigate the fraction of distorted morphologies in both samples by visual classification. Only ∼15% of the AGN hosts have highly distorted morphologies, possibly due to a major merger or interaction. We find there is no significant difference in the distortion fractions between the AGN host sample and control sample. We conclude that the morphologies of X-ray-selected AGN hosts are similar to those of non-active galaxies and most AGN activity is not triggered by a major merger.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

Selection and mid-infrared spectroscopy of ultraluminous star-forming galaxies at z ∼ 2

Starting from a sample of 24 μm sources in the Extended Groth Strip, we use 3.6-8 μm color criteria to select ultraluminous infrared galaxies (ULIRGs) at z ∼ 2. Spectroscopy from 20-38 μm of 14 objects verifies their nature and gives their redshifts. Multi-wavelength data for these objects imply stellar masses >10{sup 11} M {sub ☉} and star formation rates ≥410 M {sub ☉} yr{sup –1}. Four objects of this sample observed at 1.6 μm (rest-frame visible) with Hubble Space Telescope/WFC3 show diverse morphologies, suggesting that multiple formation processes create ULIRGs. Of the 14 objects, 4 show signs of active galactic nuclei, but the luminosity appears to be dominated by star formation in all cases.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

The likely Fermi detection of the supernova remnant RCW 103

We report on the results from our γ-ray analysis of the supernova remnant (SNR) RCW 103 region. The data were taken with the Large Area Telescope on board the Fermi Gamma-ray Space Telescope. An extended source is found at a position consistent with that of RCW 103 and its emission was only detected above 1 GeV (10σ significance), with a power-law spectrum with a photon index of 2.0 ± 0.1. We obtain its 1-300 GeV spectrum and the total flux gives a luminosity of 8.3 × 10{sup 33} erg s{sup –1} at a source distance of 3.3 kpc. Given the positional coincidence and property similarities of this source with other SNRs, we identify it as the likely Fermi γ-ray counterpart to RCW 103. Including radio measurements of RCW 103, the spectral energy distribution (SED) is modeled by considering emission mechanisms based on both hadronic and leptonic scenarios. We find that models in the two scenarios can reproduce the observed SED, while in the hadronic scenario the existence of SNR-molecular cloud interactions is suggested as a high density of the target protons is required.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

DISCOVERY OF THE TRANSIENT MAGNETAR 3XMM J185246.6+003317 NEAR SUPERNOVA REMNANT KESTEVEN 79 WITH XMM-NEWTON

We report the serendipitous discovery with XMM-Newton that 3XMM J185246.6+003317 is an 11.56 s X-ray pulsar located 1' away from the southern boundary of supernova remnant Kes 79. The spin-down rate of 3XMM J185246.6+003317 is <1.1 × 10{sup –13} s s{sup –1}, which, together with the long period P = 11.5587126(4) s, indicates a dipolar surface magnetic field of <3.6 × 10{sup 13} G, a characteristic age of >1.7 Myr, and a spin-down luminosity of <2.8 × 10{sup 30} erg s{sup –1}. Its X-ray spectrum is best-fitted with a resonant Compton scattering model and also can be adequately described by a blackbody model. The observations covering a seven-month span from 2008 to 2009 show variations in the spectral properties of the source, with the luminosity decreasing from 2.7 × 10{sup 34} erg s{sup –1} to 4.6 × 10{sup 33} erg s{sup –1}, along with a decrease of the blackbody temperature from kT ≈ 0.8 keV to ≈0.6 keV. The X-ray luminosity of the source is higher than its spin-down luminosity, ruling out rotation as a power source. The combined timing and spectral properties, the non-detection of any optical or infrared counterpart, together with the lack of detection of the source in archival X-ray data prior to the 2008 XMM-Newton observation, point to 3XMM J185246.6+003317 being a newly discovered transient low-B magnetar undergoing an outburst decay during the XMM-Newton observations. The non-detection by Chandra in 2001 sets an upper limit of 4 × 10{sup 32} erg s{sup –1} to the quiescent luminosity of 3XMM J185246.6+003317. Its period is the longest among currently known transient magnetars. The foreground absorption toward 3XMM J185246.6+003317 is similar to that of Kes 79, suggesting a similar distance of ∼7.1 kpc.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2013

A second-order semi-implicit δf method for hybrid simulation

A second-order accurate semi-implicit Lorentz force ions, fluid electrons δf hybrid model has been developed using a “current closure” scheme. The model assumes quasi-neutrality and is fully electromagnetic. The implicit field solver improves numerical accuracy by separating the equilibrium terms in the presence of small perturbations. The equilibrium part of the generalized Ohm’s law is solved by direct matrix inversion along the direction of gradients for every Fourier mode in the other two directions, while the nonlinear part is solved iteratively. The simulation has been benchmarked on Alfvén waves, ion sound waves and whistler waves against analytical dispersion relation in a slab. In particular, the first-order and second-order schemes are compared by studying the numerical damping of whistler waves. The full evolution of the resistive tearing mode using the Harris sheet equilibrium is also investigated. The linear growth rate and mode structure are compared with the resistive MHD theory. Important tearing mode nonlinear phenomena such as the Rutherford regime and saturation are demonstrated. We also presented systematic study of Rutherford growth rates and saturation island width, which is consistent with previous MHD studies.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2013

Global gyrokinetic simulations of the H-mode tokamak edge pedestal

Global gyrokinetic simulations of DIII-D H-mode edge pedestal show two types of instabilities may exist approaching the onset of edge localized modes: an intermediate-n, high frequency mode which we identify as the “kinetic peeling ballooning mode (KPBM),” and a high-n, low frequency mode. Our previous study [W. Wan et al., Phys. Rev. Lett. 109, 185004 (2012)] has shown that when the safety factor profile is flattened around the steep pressure gradient region, the high-n mode is clearly kinetic ballooning mode and becomes the dominant instability. Otherwise, the KPBM dominates. Here, the properties of the two instabilities are studied by varying the density and temperature profiles. It is found that the KPBM is destabilized by density and ion temperature gradient, and the high-n mode is mostly destabilized by electron temperature gradient. Nonlinear simulations with the KPBM saturate at high levels. The equilibrium radial electric field (E{sub r}) reduces the transport. The effect of the parallel equilibrium current is found to be weak.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS2013

El Nino and Health Risks from Landscape Fire Emissions in Southeast Asia

Emissions from landscape fires affect both climate and air quality. Here, we combine satellite-derived fire estimates and atmospheric modelling to quantify health effects from fire emissions in southeast Asia from 1997 to 2006. This region has large interannual variability in fire activity owing to coupling between El Nino-induced droughts and anthropogenic land-use change. We show that during strong El Nino years, fires contribute up to 200 micrograms per cubic meter and 50 ppb in annual average fine particulate matter (PM2.5) and ozone surface concentrations near fire sources, respectively. This corresponds to a fire contribution of 200 additional days per year that exceed the World Health Organization 50 micrograms per cubic metre 24-hr PM(sub 2.5) interim target and an estimated 10,800 (6,800-14,300)-person (approximately 2 percent) annual increase in regional adult cardiovascular mortality. Our results indicate that reducing regional deforestation and degradation fires would improve public health along with widely established benefits from reducing carbon emissions, preserving biodiversity and maintaining ecosystem services.

fires↗

NASA NTRS2011

Forecasting Fire Season Severity in South America Using Sea Surface Temperature Anomalies

Fires in South America cause forest degradation and contribute to carbon emissions associated with land use change. We investigated the relationship between year-to-year changes in fire activity in South America and sea surface temperatures. We found that the Oceanic Ni o Index was correlated with interannual fire activity in the eastern Amazon, whereas the Atlantic Multidecadal Oscillation index was more closely linked with fires in the southern and southwestern Amazon. Combining these two climate indices, we developed an empirical model to forecast regional fire season severity with lead times of 3 to 5 months. Our approach may contribute to the development of an early warning system for anticipating the vulnerability of Amazon forests to fires, thus enabling more effective management with benefits for climate and air quality.

Chen, Yang↗

NASA NTRS2011

Predicting Fire Season Severity in South America Using Sea Surface Temperature Anomalies

Fires in South America cause forest degradation and contribute to carbon emissions associated with land use change. Here we investigated the relationship between year-to-year changes in satellite-derived estimates of fire activity in South America and sea surface temperature (SST) anomalies. We found that the Oceanic Ni o Index (ONI) was correlated with interannual fire activity in the eastern Amazon whereas the Atlantic Multidecadal Oscillation (AMO) index was more closely linked with fires in the southern and southwestern Amazon. Combining these two climate indices, we developed an empirical model that predicted regional annual fire season severity (FSS) with 3-5 month lead times. Our approach provides the foundation for an early warning system for forecasting the vulnerability of Amazon forests to fires, thus enabling more effective management with benefits for mitigation of greenhouse gas and air pollutant emissions.

Chen, Yang↗