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Chen, Ping

Publications and source records attributed to Chen, Ping.

14 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Effect of 60 Co Irradiation on Boehmite Dissolution in Caustic Solutions

Here, in this work, we examine how radiation impacts the dissolution behavior of boehmite by subjecting dry nanoparticles of different sizes to 60 Co γ radiation and subsequently analyzing their dissolution behavior in caustic solutions as a function of temperature. The measured kinetics show that irradiation with an amount 228.24 Mrad significantly slows the dissolution rate, particularly for smaller sizes at lower temperatures. Specifically, the temperature-dependent dissolution rates of irradiated 20 nm boehmite versus pristine material in 3 M NaOH solutions were several times lower (e.g., rate constant of 0.026 vs 0.075 h –1 at 60 °C), with an apparent activation energy 40 kJ mol –1 higher. Although various imaging techniques and X-ray diffraction measurements consistently revealed no obvious differences between pristine and irradiated samples, after irradiation significant binding energy shifts were detected in the X-ray photoelectron Spectroscopy peaks of Al 2p and O 1s, and a change in their relative intensities indicated a lower O/Al ratio. This suggests that γ-irradiation may stabilize boehmite particle surfaces by driving their chemistry and structure toward more stable aluminum oxide forms. This finding may help explain slower dissolution rates of boehmite in nuclear waste and may be useful for the development of more robust predictive models and effective strategies for waste processing.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2024

Global rare earth element resources: A concise review

Deposits enriched in rare earth elements (REEs) are abundant and diverse in mineralogy, but those of current economic value have extremely limited geographic distribution. Due to rapidly increasing demand and concerns about supply chain security, new and improved methods of prospecting, beneficiation, separation, purification, and recycling are needed. By overviewing the types and geographic distribution of REE reserves globally, their petrogenesis and major mineralogic assemblages, this review aims to provide a foundation for posing new directions for research and development in these areas. In conclusion, our review also seeks to provide a concise summary of important background information that is accessible to researchers from a variety of disciplines who are seeking to engage in this rapidly expanding field.

58 GEOSCIENCES↗
NASA NTRS1995

A quasi-permeable barrier in the equatorial lower stratosphere

Analyses of global isentropic maps of potential vorticity from the United Kingdom Meteorological Office (UKMO) data assimilation system reveal that there is a region of strong meridional potential vorticity (PV) gradients in the equatorial lower stratosphere. A semi-Lagrangian tracer transport model is used to show that this region of strong PV gradients acts as a quasipermeable barrier to cross-equator mass exchange on isentropic surfaces.

Chen, Ping↗
NASA NTRS1994

Mixing by barotropic instability in a nonlinear model

A global, nonlinear, equivalent barotropic model is used to study the isentropic mixing of passive tracers by barotropic instability. Basic states are analytical zonal-mean jets representative of the zonal-mean flow in the upper stratosphere, where the observed 4-day wave is thought to be a result of barotropic, and possibly baroclinic, instability. As is known from previous studies, the phase speed and growth rate of the unstable waves is fairly sensitive to the shape of the zonal-mean jet; and the dominant wave mode at saturation is not necessarily the fastest growing mode; but the unstable modes share many features of the observed 4-day wave. Lagrangian trajectories computed from model winds are used to characterize the mixing by the flow. For profiles with both midlatitude and polar modes, mixing is stronger in midlatitude than inside the vortex; but there is little exchange of air across the vortex boundary. There is a minimum in the Lyapunov exponents of the flow and the particle dispersion at the jet maximum. For profiles with only polar unstable modes, there is weak mixing inside the vortex, no mixing outside the vortex, and no exchange of air across the vortex boundary. These results support the theoretical arguments that, whether wave disturbances are generated by local instability or propagate from other regions, the mixing properties of the total flow are determined by the locations of the wave critical lines and that strong gradients of potential vorticity are very resistant to mixing.

Bowman, Kenneth P.↗
NASA NTRS1994

The permeability of the Antarctic vortex edge

Mixing and cross-vortex mass transport along isentropic surfaces in the lower stratosphere are investigated with a 'contour advection' technique and a semi-Lagrangian transport model for the Antarctic winter of 1993 using analyzed winds from the United Kingdom Meteorological Office data assimilation system. Results from the 'contour advection' technique show that at the vortex edge there exists a potential vorticity (PV) contour that has the smallest lengthening rate. This PV contour is referred to as the 'line of separation' because it essentially separates the inner and outer vortex. The average e-folding time for the lengthening of the 'line of separation' increases monotonically with altitude, ranging from about 7 days on the 350 K isentropic surface to about 105 days on the 500 K isentropic surface. The results also suggest the existence of a transition layer around the 400 K isentropic surface, above which the vortex is nearly completely isolated from the midlatitudes and below which the vortex is less isolated. Results from a semi-Lagrangian transport model with an idealized tracer initially inside the inner vortex show that at 425 K and above virtually no tracer is transported out of the vortex during a 40-day integration starting from July 21, 1993. At 400 K and below a small amount of the tracer is transported out of the vortex while the bulk of the tracer remains confined within the inner vortex.

Chen, Ping↗
NASA NTRS1994

Isentropic mass exchange between the Tropics and extratropics in the stratosphere

The isentropic mass exchange between the Tropics and extratropics in the stratosphere is investigated with a semi-Lagrangian transport model for the periods from 1 June to 31 October 1992 and from 1 December 1992 to 30 April 1993 using winds from the U.K. Meteorological Office data assimilation system. Calculations with an idealized, initially zonally symmetric tracer show that in the middle and upper stratosphere the bulk of tropical air is transported into the midlatitudes of the winter hemisphere although there exist quasi-permeable barriers in the subtropics. The transport takes place in the form of planetary-scale 'tongues' of material that are drawn poleward in association with the episodic amplification of planetary-scale waves in high latitudes of the winter hemisphere. Once air of tropical origin is transported to the midlatitudes it is irreversibly mixed with the midlatitude air in the 'surf zone.' Air of tropical origin can, however, hardly penetrate into the interior of the winter polar vortex until the breakdown of the vortex. Transport of tropical air into the midlatitudes of the summer hemisphere is strongly inhibited. In the lower stratosphere, tropical air is transported into the northern and southern midlatitudes. During the period from 1 June to 31 October 1992, the amount of tropical air transported into the Northern Hemisphere is, however, much smaller than that transported into the Southern Hemisphere, and there exist strong gradients in the tracer field in the equatorial region, indicating that there is a quasi-permeable barrier to cross-equator mass exchange. During the period from 1 December 1992 to 30 April 1993, on the other hand, roughly the same amounts of tropical air are transported into the Southern Hemisphere, and there exist strong gradients in the tracer field in the equatorial region, indicating that there is a quasi-permeable barrier to cross-equator mass exchange. During the period from 1 December 1992 to 30 April 1993, on the other hand, roughly the same amounts of tropical air are transported into the northern midlatitudes and into the southern midlatitudes, and there exist no significant transport barriers in the equatorial area.

Chen, Ping↗
NASA NTRS1994

Turbulent mixing noise from supersonic jets

There is now a substantial body of theoretical and experimental evidence that the dominant part of the turbulent noise of supersonic jets is generated directly by the large turbulence structures/instability waves of the jet flow. Earlier, Tam and Burton provided a description of the physical mechanism by which supersonically traveling instability waves can generate sound efficiently. They used the method of matched asymptotic expansions to construct an instability wave solution which is valid in the far field. The present work is an extension of the theory of Tam and Burton. It is argued that the instability wave spectrum of the jet may be regarded as generated by stochastic white noise excitation at the nozzle lip region. The reason why the excitation has white noise characteristics is that near the nozzle lip region the flow in the jet mixing layer has no intrinsic length and time scales. The present stochastic wave model theory of supersonic jet noise contains a single unknown multiplicative constant. Comparisons between the calculated noise directivities at selected Strouhal numbers and experimental measurements of a Mach 2 jet at different jet temperatures have been carried out. Favorable agreements are found.

Tam, Christopher K. W.↗
NASA NTRS1994

Quasi-horizontal transport and mixing in the Antarctic stratosphre

The quasi-horizontal transport and mixing properties of the Antarctic stratosphere are investigated with a simi-Lagrangian transport model and a 'contour advection' technique for the winter and spring of 1992 using analyzed winds from the United Kingdom Meteorological Office data assimiliation system. Transport calculations show that passive tracers are well mixed inside the polar vortex as well as in the midlatitude 'surf zone.' A the vortex edge, strong radial gradients in the tracer fields are well preserved, and their evolutions follow that of the potential vorticity until some time after the breakdown of the polar vortex. In the middle stratosphere there is little tracer exchange across the vortex edge in August and September. Some vortex air is eroded into the surf zone in filamentary form in October, and very strong exchange of air occurs between high and middle latitudes in November. In the lower stratosphere the vortex is not so isolated from the midlatitudes as in the middle stratosphere, and there is more mass exchange across the vortex edge. Calculations of the lengthening of material contours using the contour advection technique show that in the middle stratosphere, strong stirring (i.e., stretching and folding of material elements) occurs in the inner vortex, while the strongest stirring occurs in the midlatitude surf zone and the weakest occurs at the vortex edge. In the lower strtosphere, strong stirring occurs in the inner vortex. Stirring is moderate at the vortex edge and in the midlatitudes.

Chen, Ping↗
NASA NTRS1993

The barotropic normal modes in certain shear flows and the traveling waves in the atmosphere

It is shown analytically and numerically that in certain shear flows the linearized nondivergent barotropic vorticity equation has a limited number of neutral normal modes. The latitudinal structures of these shear flows can be expressed as polynomials of the sine of latitude. The first few such shear flows resemble the gross features of the zonal winds in the atmosphere of the earth at different times and altitudes. The spatial structures of the neutral normal modes in these shear flows are spherical harmonics, and, as a consequence, these modes are also the exact solutions of the fully nonlinear equation because the nonlinear interaction term vanishes identically. The spatial structures of the observed 5-, 4-, 2-, and 16-day free traveling waves in the atmosphere are often identified with the spherical harmonics with indices of (m, n) = ( 1, 2), (2, 3), (3, 3), and ( 1, 4), which are known previously as the neutral normal modes of the nondivergent barotropic vorticity equation in a motionless background state. Our results could explain why these free traveling waves can survive the shearing effects of zonal flows that are far different from rest because these spherical harmonics are also normal modes in certain shear flows that resemble the observations of the atmosphere.

Chen, Ping↗
NASA NTRS1992

Propagation of planetary waves between the troposphere and stratosphere

The propagation of planetary waves between the troposphere and stratosphere is investigated using a linear, time-dependent, primitive equation model. It is found that the tropopause acts like a valve for the propagation of planetary waves. The key parameters controlling the valve are the vertical gradient of buoyancy frequency and the vertical shear of the zonal winds at the tropopause. For a given wind profile smaller gradient of buoyancy frequency enhances the propagation of planetary waves. For a given profile of buoyancy frequency the larger the shear, the more the wave activity is trapped in the troposphere, and therefore, there is less left to propagate into the stratosphere. The transmission across the tropopause is, however, not sensitive to zonal winds in the upper stratosphere. The propagation of planetary waves is very sensitive to transience. More transient waves propagate more vertically within the troposphere, and for more transient waves, more wave activity is transferred into the stratosphere from the troposphere.

Chen, Ping↗
NASA NTRS1992

The coupling of the troposphere and stratosphere

A linear, time-dependent, primitive-equation, 3D numerical model is used to investigate the dynamical coupling between the troposphere and stratosphere through the vertical propagation of planetry waves. Attention is given to the roles of the tropopause in affecting the propagation of planetary waves and to the extent to which the stratosphere can determine its own wave driving, i.e., the sensitivity of the generation of the wave activity in the troposphere to the change of zonal wind in the stratosphere. Two maxima in Eliassen-Palm (EP) flux convergence are found for wave 1 in high latitudes, one in the upper stratosphere and the other in the upper troposphere. For wave 2 there is a third maximum north of the zero wind line in the tropical stratosphere. The formation of the maximum in EP-flux convergence in the upper troposphere is related to the dissipation of non-WKBJ waves near a local maximum of the refractive index. The existence of the local maximum in refractive index at the tropopause is a result of the great gradient of the buoyancy frequency as well as the vertical shear of the zonal flow there.

Chen, Ping↗
NASA NTRS1991

The effects of transience on the propagation of stratospheric planetary waves

The propagation of planetary-scale Rossby waves in the stratosphere is investigated in a linear, time-dependent, primitive equation model. Two distinct maxima in the convergence of the Eliassen-Palm flux (EP flux) are found for steady and for transient waves in a variety of realistic northern hemisphere, winter season, zonal flows; one below the stratospheric polar jet and the other north of the zero wind line. These maxima appear at higher altitudes for wave 1 than for wave 2, especially in low latitudes. Different mechanisms cause the formation of these two maxima. The confinement of wave activity in high latitudes is mainly due to the dissipation of waves in that region under non-WKBJ conditions. The maximum in lower latitudes is related to the absorption of Rossby waves near their critical lines. For wave 2, the intensity of the high latitude maximum is sensitive to the transience of the wave forcing at the tropopause, while for wave 1 this sensitivity is reduced. For both waves the low latitude maximum shifts northward with increasing transience.

Chen, Ping↗
NASA NTRS1991

Relationship between the instability waves and noise of high-speed jets

The relationship between the instability waves and noise of hot jets at moderate supersonic Mach number is investigated. The relative importance of the Kelvin-Helmholtz instability waves and the supersonic instability waves as sources of noise is considered. The results show that, for the range of Mach number and jet-to-ambient temperature ratio considered, the Kelvin-Helmholtz instability waves have much higher total amplification and higher phase speed.

Tam, Christopher K. W.↗