Engineering topics

Chen, Bo

Publications and source records attributed to Chen, Bo.

58 records · Page 4

DOE OSTI2021

Evoking ordered vacancies in metallic nanostructures toward a vacated Barlow packing for high-performance hydrogen evolution

Metallic nanostructures are commonly densely packed into a few packing variants with slightly different atomic packing factors. The structural aspects and physicochemical properties related with the vacancies in such nanostructures are rarely explored because of lack of an effective way to control the introduction of vacancy sites. Highly voided metallic nanostructures with ordered vacancies are however energetically high lying and very difficult to synthesize. Here, we report a chemical method for synthesis of hierarchical Rh nanostructures (Rh NSs) composed of ultrathin nanosheets, composed of hexagonal close-packed structure embedded with nanodomains that adopt a vacated Barlow packing with ordered vacancies. The obtained Rh NSs exhibit remarkably enhanced electrocatalytic activity and stability toward the hydrogen evolution reaction (HER) in alkaline media. Theoretical calculations reveal that the exceptional electrocatalytic performance of Rh NSs originates from their unique vacancy structures, which facilitate the adsorption and dissociation of H 2 O in the HER.

36 MATERIALS SCIENCE↗

NASA NTRS2016

Determination of the Earth's Plasmapause Location from the CE-3 EUVC Images

The Moon-based Extreme Ultraviolet Camera (EUVC) aboard China's Chang'e-3 (CE-3) mission has successfully imaged the entire Earth's plasmasphere for the first time from the side views on lunar surface. An EUVC image on 21 April 2014 is used in this study to demonstrate the characteristics and configurations of the Moon-based EUV imaging and to illustrate the determination algorithm of the plasmapause locations on the magnetic equator. The plasmapause locations determined from all the available EUVC images with the Minimum L Algorithm are quantitatively compared with those extracted from insitu observations (Defense Meteorological Satellite Program, Time History of Events and Macroscale Interactions during Substorms, and Radiation Belt Storm Probes). Excellent agreement between the determined plasmapauses seen by EUVC and the extracted ones from other satellites indicates the reliability of the Moon-based EUVC images as well as the determination algorithm. This preliminary study provides an important basis for future investigation of the dynamics of the plasmasphere with the Moon-based EUVC imaging.

He, Fei↗

NASA NTRS2012

Methods of Attaching or Grafting Carbon Nanotubes to Silicon Surfaces and Composite Structures Derived Therefrom

The present invention is directed toward methods of attaching or grafting carbon nanotubes (CNTs) to silicon surfaces. In some embodiments, such attaching or grafting occurs via functional groups on either or both of the CNTs and silicon surface. In some embodiments, the methods of the present invention include: (1) reacting a silicon surface with a functionalizing agent (such as oligo(phenylene ethynylene)) to form a functionalized silicon surface; (2) dispersing a quantity of CNTs in a solvent to form dispersed CNTs; and (3) reacting the functionalized silicon surface with the dispersed CNTs. The present invention is also directed to the novel compositions produced by such methods.

Tour, James M.↗

NASA NTRS2012

Use of Functionalized Carbon Nanotubes for Covalent Attachment of Nanotubes to Silicon

The purpose of the invention is to covalently attach functionalized carbon nanotubes to silicon. This step allows for the introduction of carbon nanotubes onto all manner of silicon surfaces, and thereby introduction of carbon nano - tubes covalently into silicon-based devices, onto silicon particles, and onto silicon surfaces. Single-walled carbon nanotubes (SWNTs) dispersed as individuals in surfactant were functionalized. The nano - tube was first treated with 4-t-butylbenzenediazonium tetrafluoroborate to give increased solubility to the carbon nanotube; the second group attached to the sidewall of the nanotube has a silyl-protected terminal alkyne that is de-protected in situ. This gives a soluble carbon nanotube that has functional groups appended to the sidewall that can be attached covalently to silicon. This reaction was monitored by UV/vis/NJR to assure direct covalent functionalization.

Tour, James M.↗