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Carlson, Barbara E.

Publications and source records attributed to Carlson, Barbara E..

Reducing Multisensor Satellite Monthly Mean Aerosol Optical Depth Uncertainty: 1. Objective Assessment of Current AERONET Locations

Various space-based sensors have been designed and corresponding algorithms developed to retrieve aerosol optical depth (AOD), the very basic aerosol optical property, yet considerable disagreement still exists across these different satellite data sets. Surface-based observations aim to provide ground truth for validating satellite data; hence, their deployment locations should preferably contain as much spatial information as possible, i.e., high spatial representativeness. Using a novel Ensemble Kalman Filter (EnKF)- based approach, we objectively evaluate the spatial representativeness of current Aerosol Robotic Network (AERONET) sites. Multisensor monthly mean AOD data sets from Moderate Resolution Imaging Spectroradiometer, Multiangle Imaging Spectroradiometer, Sea-viewing Wide Field-of-view Sensor, Ozone Monitoring Instrument, and Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar are combined into a 605-member ensemble, and AERONET data are considered as the observations to be assimilated into this ensemble using the EnKF. The assessment is made by comparing the analysis error variance (that has been constrained by ground-based measurements), with the background error variance (based on satellite data alone). Results show that the total uncertainty is reduced by approximately 27% on average and could reach above 50% over certain places. The uncertainty reduction pattern also has distinct seasonal patterns, corresponding to the spatial distribution of seasonally varying aerosol types, such as dust in the spring for Northern Hemisphere and biomass burning in the fall for Southern Hemisphere. Dust and biomass burning sites have the highest spatial representativeness, rural and oceanic sites can also represent moderate spatial information, whereas the representativeness of urban sites is relatively localized. A spatial score ranging from 1 to 3 is assigned to each AERONET site based on the uncertainty reduction, indicating its representativeness level.

aerosol optical depth

Using Single-Scattering Albedo Spectral Curvature to Characterize East Asian Aerosol Mixtures

Spectral dependence of aerosol single-scattering albedo (SSA) has been used to infer aerosol composition. In particular, aerosol mixtures dominated by dust absorption will have monotonically increasing SSA with wavelength while that dominated by black carbon absorption has monotonically decreasing SSA spectra. However, by analyzing SSA measured at four wavelengths, 440, 675, 870, and 1020 nm from the Aerosol Robotic Network data set, we find that the SSA spectra over East Asia are frequently peaked at 675 nm. In these cases, we suggest that SSA spectral curvature, defined as the negative of the second derivative of SSA as a function of wavelength, can provide additional information on the composition of these aerosol mixtures. Aerosol SSA spectral curvatures for East Asia during fall and winter are considerably larger than those found in places primarily dominated by biomass burning or dust aerosols. SSA curvature is found to increase as the SSA magnitude decreases. The curvature increases with coarse mode fraction (CMF) to a CMF value of about 0.4, then slightly decreases or remains constant at larger CMF. Mie calculations further verify that the strongest SSA curvature occurs at approx. 40% dust fraction, with 10% scattering aerosol fraction. The nonmonotonic SSA spectral dependence is likely associated with enhanced absorption in the shortwave by dust, absorption by black carbon at longer wavelengths, and also the flattened absorption optical depth spectral dependence due to the increased particle size.

curvature

Application of Spectral Analysis Techniques in the Intercomparison of Aerosol Data: Part III. Using Combined PCA to Compare Spatiotemporal Variability of MODIS, MISR and OMI Aerosol Optical Depth

Satellite measurements of global aerosol properties are very useful in constraining aerosol parameterization in climate models. The reliability of different data sets in representing global and regional aerosol variability becomes an essential question. In this study, we present the results of a comparison using combined principal component analysis (CPCA), applied to monthly mean, mapped (Level 3) aerosol optical depth (AOD) product from Moderate Resolution Imaging Spectroradiometer (MODIS), Multiangle Imaging Spectroradiometer (MISR), and Ozone Monitoring Instrument (OMI). This technique effectively finds the common space-time variability in the multiple data sets by decomposing the combined AOD field. The results suggest that all of the sensors capture the globally important aerosol regimes, including dust, biomass burning, pollution, and mixed aerosol types. Nonetheless, differences are also noted. Specifically, compared with MISR and OMI, MODIS variability is significantly higher over South America, India, and the Sahel. MODIS deep blue AOD has a lower seasonal variability in North Africa, accompanied by a decreasing trend that is not found in either MISR or OMI AOD data. The narrow swath of MISR results in an underestimation of dust variability over the Taklamakan Desert. The MISR AOD data also exhibit overall lower variability in South America and the Sahel. OMI does not capture the Russian wild fire in 2010 nor the phase shift in biomass burning over East South America compared to Central South America, likely due to cloud contamination and the OMI row anomaly. OMI also indicates a much stronger (boreal) winter peak in South Africa compared with MODIS and MISR.

satellite observation

Revisiting AVHRR Tropospheric Aerosol Trends Using Principal Component Analysis

The advanced very high resolution radiometer (AVHRR) satellite instruments provide a nearly 25 year continuous record of global aerosol properties over the ocean. It offers valuable insights into the long-term change in global aerosol loading. However, the AVHRR data record is heavily influenced by two volcanic eruptions, El Chichon on March 1982 and Mount Pinatubo on June 1991. The gradual decay of volcanic aerosols may last years after the eruption, which potentially masks the estimation of aerosol trends in the lower troposphere, especially those of anthropogenic origin. In this study, we show that a principal component analysis approach effectively captures the bulk of the spatial and temporal variability of volcanic aerosols into a single mode. The spatial pattern and time series of this mode provide a good match to the global distribution and decay of volcanic aerosols. We further reconstruct the data set by removing the volcanic aerosol component and reestimate the global and regional aerosol trends. Globally, the reconstructed data set reveals an increase of aerosol optical depth from 1985 to 1990 and decreasing trend from 1994 to 2006. Regionally, in the 1980s, positive trends are observed over the North Atlantic and North Arabian Sea, while negative tendencies are present off the West African coast and North Pacific. During the 1994 to 2006 period, the Gulf of Mexico, North Atlantic close to Europe, and North Africa exhibit negative trends, while the coastal regions of East and South Asia, the Sahel region, and South America show positive trends.

volcanoes

Application of Spectral Analysis Techniques in the Intercomparison of Aerosol Data. Part II: Using Maximum Covariance Analysis to Effectively Compare Spatiotemporal Variability of Satellite and AERONET Measured Aerosol Optical Depth

Moderate Resolution Imaging SpectroRadiometer (MODIS) and Multi-angle Imaging Spectroradiomater (MISR) provide regular aerosol observations with global coverage. It is essential to examine the coherency between space- and ground-measured aerosol parameters in representing aerosol spatial and temporal variability, especially in the climate forcing and model validation context. In this paper, we introduce Maximum Covariance Analysis (MCA), also known as Singular Value Decomposition analysis as an effective way to compare correlated aerosol spatial and temporal patterns between satellite measurements and AERONET data. This technique not only successfully extracts the variability of major aerosol regimes but also allows the simultaneous examination of the aerosol variability both spatially and temporally. More importantly, it well accommodates the sparsely distributed AERONET data, for which other spectral decomposition methods, such as Principal Component Analysis, do not yield satisfactory results. The comparison shows overall good agreement between MODIS/MISR and AERONET AOD variability. The correlations between the first three modes of MCA results for both MODIS/AERONET and MISR/ AERONET are above 0.8 for the full data set and above 0.75 for the AOD anomaly data. The correlations between MODIS and MISR modes are also quite high (greater than 0.9). We also examine the extent of spatial agreement between satellite and AERONET AOD data at the selected stations. Some sites with disagreements in the MCA results, such as Kanpur, also have low spatial coherency. This should be associated partly with high AOD spatial variability and partly with uncertainties in satellite retrievals due to the seasonally varying aerosol types and surface properties.

aerosols

Evidence of a Weakly Absorbing Intermediate Mode of Aerosols in AERONET Data from Saharan and Sahelian Sites

Accurate retrievals of aerosol size distribution are necessary to estimate aerosols' impact on climate and human health. The inversions of the Aerosol Robotic Network (AERONET) usually retrieve bimodal distributions. However, when the inversion is applied to Saharan and Sahelian dust, an additional mode of intermediate size between the coarse and fine modes is sometimes seen. This mode explains peculiarities in the behavior of the Angstrom exponent, along with the fine mode fraction retrieved using the spectral deconvolution algorithm, observed in a March 2006 dust storm. For this study, 15 AERONET sites in northern Africa and on the Atlantic are examined to determine the frequency and properties of the intermediate mode. The mode is observed most frequently at Ilorin in Nigeria. It is also observed at Capo Verde and multiple sites located within the Sahel but much less frequently at sites in the northern Sahara and the Canary Islands. The presence of the intermediate mode coincides with increases in Angstrom exponent, fine mode fraction, single-scattering albedo, and to a lesser extent percent sphericity. The Angstrom exponent decreases with increasing optical depth at most sites when the intermediate mode is present, but the fine mode fraction does not. Single-scattering albedo does not steadily decrease with fine mode fraction when the intermediate mode is present, as it does in typical mixtures of dust and biomass-burning aerosols. Continued investigation is needed to further define the intermediate mode's properties, determine why it differs from most Saharan dust, and identify its climate and health effects.

inversions

Application of Spectral Analysis Techniques in the Intercomparison of Aerosol Data: 1. an EOF Approach to the Spatial-Temporal Variability of Aerosol Optical Depth Using Multiple Remote Sensing Data Sets

Many remote sensing techniques and passive sensors have been developed to measure global aerosol properties. While instantaneous comparisons between pixel-level data often reveal quantitative differences, here we use Empirical Orthogonal Function (EOF) analysis, also known as Principal Component Analysis, to demonstrate that satellite-derived aerosol optical depth (AOD) data sets exhibit essentially the same spatial and temporal variability and are thus suitable for large-scale studies. Analysis results show that the first four EOF modes of AOD account for the bulk of the variance and agree well across the four data sets used in this study (i.e., Aqua MODIS, Terra MODIS, MISR, and SeaWiFS). Only SeaWiFS data over land have slightly different EOF patterns. Globally, the first two EOF modes show annual cycles and are mainly related to Sahara dust in the northern hemisphere and biomass burning in the southern hemisphere, respectively. After removing the mean seasonal cycle from the data, major aerosol sources, including biomass burning in South America and dust in West Africa, are revealed in the dominant modes due to the different interannual variability of aerosol emissions. The enhancement of biomass burning associated with El Niño over Indonesia and central South America is also captured with the EOF technique.

variability

El Nino-Southern Oscillation Correlated Aerosol Angstrom Exponent Anomaly Over the Tropical Pacific Discovered in Satellite Measurements

El Nino.Southern Oscillation (ENSO) is the dominant mode of interannual variability in the tropical atmosphere. ENSO could potentially impact local and global aerosol properties through atmospheric circulation anomalies and teleconnections. By analyzing aerosol properties, including aerosol optical depth (AOD) and Angstrom exponent (AE; often used as a qualitative indicator of aerosol particle size) from the Moderate Resolution Imaging Spectrometer, the Multiangle Imaging Spectroradiometer and the Sea ]viewing Wide Field ]of ]view Sensor for the period 2000.2011, we find a strong correlation between the AE data and the multivariate ENSO index (MEI) over the tropical Pacific. Over the western tropical Pacific (WTP), AE increases during El Nino events and decreases during La Nina events, while the opposite is true over the eastern tropical Pacific (ETP). The difference between AE anomalies in the WTP and ETP has a higher correlation coefficient (>0.7) with the MEI than the individual time series and could be considered another type of ENSO index. As no significant ENSO correlation is found in AOD over the same region, the change in AE (and hence aerosol size) is likely to be associated with aerosol composition changes due to anomalous meteorological conditions induced by the ENSO. Several physical parameters or mechanisms that might be responsible for the correlation are discussed. Preliminary analysis indicates surface wind anomaly might be the major contributor, as it reduces sea ]salt production and aerosol transport during El Nino events. Precipitation and cloud fraction are also found to be correlated with tropical Pacific AE. Possible mechanisms, including wet removal and cloud shielding effects, are considered. Variations in relative humidity, tropospheric ozone concentration, and ocean color during El Nino have been ruled out. Further investigation is needed to fully understand this AE ]ENSO covariability and the underlying physical processes responsible for it.

Li, Jing

The Spatiotemporal Structure of 20th Century Climate Variations in Observations and Reanalyses: Pacific Pan-Decadal Variability - Part 2

The dominant interannual El Nino-Southern Oscillation phenomenon (ENSO) and the short length of climate observation records make it difficult to study long-term climate variations in the spatiotemporal domain. Based on the fact that the ENS0 signal spreads to remote regions and induces delayed climate variation through atmospheric teleconnections, we develop an ENSO-removal method through which the ENS0 signal can be approximately removed at the grid box level from the spatiotemporal field of a climate parameter. After this signal is removed, long-term climate variations, namely, the global warming trend (GW) and the Pacific pan-decadal variability (PDV), are isolated at middle and low latitudes in the climate parameter fields from observed and reanalyses datasets. In this study, we show that one of several PDV interdecadal regime shifts occurred during the 1990s. This significant change in the Pacific basin is comparable but opposite in phase to the 1976 climate regime shift, which results persisting warming in the central-eastern Pacific, and cooling in the North and South Pacific. The 1990s PDV regime shift is consistent with observed changes in ocean biosphere and ocean circulation. A comprehensive picture of PDV as manifested in the troposphere and at the surface is described. In general, the PDV spatial patterns in different parameter fields share some similarities with the patterns associated with ENSO, but important differences exist. First, the PDV atmospheric circulation pattern is shifted westward by about 20deg and its zonal extent is limited to approx.60deg compared to approx.110deg for ENS0 pattern. The westward shift of the PDV wave train produces a different, more west-east oriented, North American teleconnection pattern. The lack of a strong PDV surface temperature (ST) signal in the western equatorial Pacific and the relatively strong ST signal in the subtropical regions are consistent with an atmospheric overturning circulation response that differs from the one associated with ENSO.

Chen, Junye

Multi-Spectral Cloud Property Retrieval

Despite numerous studies to retrieve cloud properties using infrared measurements the information content of the data has not yet been fully exploited. In an effort to more fully utilize the information content of infrared measurements, we have developed a multi-spectral technique for retrieving effective cloud particle size, optical depth and effective cloud temperature. While applicable to all cloud types, we begin by validating our retrieval technique through analysis of MS spectral radiances obtained during the SUCCESS field campaign over the ARM SGP CART facility, and compare our retrieval product with lidar and MODIS Airborne Simulator (MAS) measurement results. The technique is then applied to the Nimbus-4 MS infrared spectral measurements to obtain global cloud information.

Carlson, Barbara E.

Belt-zone variations in the Jovian cloud structure

Voyager Infrared Interferometer Spectrometer (IRIS) observations of Jupiter in the far infrared (180-1200/cm) are sensitive to emission originating from pressures less than 2 bars, while the 5-micrometer (1800-2300/cm) observations are primarily sensitive to emission originating from pressures greater than 2 bars. We use these differences in the location of the peak emission level to constrain the properties of the upper tropospheric cloud structure from the far-infrared observations and then use the 5-micrometer observations, with the upper tropospheric cloud structure fixed, to constrain the deep cloud structure. The relationship between observed 45- and 5-micrometer brightness temperatures reveals three distinct regions between +/- 25 deg latitude: North Equatorial Belt hot spots, which are 'hot' at both 45 and 5 micrometers; Equatorial Zone spectra, which are 'warm' at 45 micrometers and 'cold' at 5 micrometers; and North Tropical Zone spectra, which are 'cold' at both 45 and 5 micrometers. We find that the hot extreme spectral ensemble is unique to belts, and the cold extreme spectral ensembles are unique to zones, but that all other intermediate spectral ensembles are common to both regions. Analyses of these spectra using an anisotropic multiple scattering radiative transfer model reveal that the primary difference between belts and zones is the increased opacity and vertical extent of clouds in zones relative to their belt counterparts. In addition, we find a shift in the location of the para hydrogen gradient toward lower pressures in zones, with an increase in the 'equilibrated' cloud-top para fraction. We suggest that all of the variations in gas abundance profiles, temperature, and cloud structure are consistent with the effects of a simple mean circulation and large-scale wave motions.

Carlson, Barbara E.

Tropospheric gas composition and cloud structure of the Jovian North Equatorial Belt

Voyager IRIS observations of the NEB reveal longitudinal variability of 5-micron brightness temperatures of order 100 C. An anisotropic multiple scattering radiative transfer model is used to calculate synthetic spectra for comparison with the IRIS observations. Mie theory is used to model the spectral dependence of cloud extinction from 180 to 2300/cm. Cloud base locations within the model vary with assumed gas abundances according to thermochemical equilibrium. It is found that spatial variations in the abundance profiles of the condensible species, parahydrogen profiles and cloud optical depths can be used as tracers of the local and large-scale dynamics. The variation of cloud opacity is strongly correlated with the variation of relative humidity, which suggests that dynamic depletion of water vapor above the cloud forming level is the most plausible model to explain the spatial variation in the water profile within the NEB.

Carlson, Barbara E.

On the inclusion of the hydrogen dimer in the analysis of Voyager IRIS spectra

Empirical formulas are fitted to existing theoretical absorption spectra of H2-H2 pairs in the far-infrared allowing the inclusion of dimer absorption, parameterized with the height dependence of the para-hydrogen profile, in the calculations. Comparison between synthetic and Voyager IRIS spectra shows that once the dimer absorption is included it is now possible to reproduce the hydrogen portion of the IRIS spectrum to within the precision of the measurements.

Carlson, Barbara E.

Ortho-para-hydrogen equilibration on Jupiter

Voyager IRIS observations reveal that the Jovian para-hydrogen fraction is not in thermodynamic equilibrium near the NH3 cloud top, implying that a vertical gradient exists between the high-temperature equilibrium value of 0.25 at depth and the cloud top values. The height-dependent para-hydrogen profile is obtained using an anisotropic multiple-scattering radiative transfer model. A vertical correlation is found to exist between the location of the para-hydrogen gradient and the NH3 cloud, strongly suggesting that paramagnetic conversion on NH3 cloud particle surfaces is the dominant equilibration mechanism. Below the NH3 cloud layer, the para fraction is constant with depth and equal to the high-temperature equilibrium value of 0.25. The degree of cloud-top equilibration appears to depend on the optical depth of the NH3 cloud layer. Belt-zone variations in the para-hydrogen profile seem to be due to differences in the strength of the vertical mixing.

Carlson, Barbara E.

The abundance and distribution of water vapor in the Jovian troposphere as inferred from Voyager IRIS observations

The Voyager IRIS spectra of the Jovian North Equatorial Belt (NEB) hot spots are reanalyzed using a radiative transfer model which includes the full effects of anisotropic multiple scattering by clouds. The atmospheric model includes the three thermochemically predicted cloud layers, NH3, NH4SH, and H2O. Spectrally dependent cloud extinction is modeled using Mie theory and the refractive indices of NH3 ice, NH4SH ice, water, and H2O ice. The upper tropospheric temperature profile, gas abundances, height-dependent parahydrogen profile, and vertical distribution of NH3 cloud opacity are retrieved from an analysis of the far-infrared (180-1200/cm) IRIS observations. With these properties constrained, the 5-micron (1800-2300/cm) observations are analyzed to determine the atmospheric and cloud structure of the deeper atmosphere (P of greater than 1.5 bars). The results show that the abundance of water is at least 1.5 times solar with 2 times solar (0.00276 mixing ratio relative to H2) providing the best-fit to the Voyager IRIS hot spot observations.

Carlson, Barbara E.

Cloud microphysics of the giant planets

The characteristic time constants for the atmospheres of the giant planets were compared for the purpose of finding analogs for clouds in the atmospheres of these planets among the several types of cloud systems found on earth. The NH3 clouds on Jupiter and Saturn were found to be weakly precipitating systems, similar to the thicker cirrus clouds on earth, while the H2O clouds were found to be much more massive than the water clouds on earth. The CH4 and H2O clouds on Uranus and Neptune are completely unlike any cloud on earth, being 10 to 100 times more massive than the densest water clouds on earth. It is concluded that, while the microphysical characteristics of the clouds on Jupiter and Saturn are comparable to those of terrestrial stratus and cumulus clouds, the massive clouds on Uranus and Neptune reach conditions unlike anything on earth.

Carlson, Barbara E.

Cloud chemistry on Jupiter

Chemical equilibrium models used currently to interpret observations of Jupiter are reexamined using new data defining thermal profiles, which are substantially different from those used in the previous models. A model is developed for the chemical reactions controlling the composition of the upper troposphere on Jupiter, specifically the cloud-forming region from 10 bar to 0.1 bar, which includes, for the first time, the effects of aqueous chemistry on the composition and the vertical distribution of many measurable species in the atmosphere, identifying the factors influencing their abundances above the H2O cloud. The thermodynamic data for potential condensates on Jupiter, i.e., NH3(s), NH4SH(s), (NH4)2S(s), and H2S(s), are reexamined, recognizing the lack of data on sulfides for the temperature range of interest on Jupiter. Vertical profiles of mixing ratios for CO2, H2S, NH3, and H2, obtained for several assumed bulk abundances with respect to solar, are presented.

Carlson, Barbara E.

The role of aqueous chemistry in determining the composition and cloud structure of the upper troposphere on Uranus

Aqueous chemistry on Uranus affects the atmospheric abundances of NH3 and H2S below the methane cloud base. Here a complete thermochemical equilibrium model for the H2O-NH3-H2S system is presented. Inclusion of H2S increases the aqueous removal of NH3 to 20-30 percent, but aqueous chemistry alone cannot account for the depletion of NH3 in the 150-200-K region of the atmosphere required to fit microwave observations. Formation of NH4SH clouds can account for the observed depletion provided the H2S/NH3 ratio is enhanced by a factor of 4 relative to solar. Perturbations to the chemical balance between N and S, for example by the general circulation on Uranus, would then produce regions with either NH3 or H2S aloft.

Carlson, Barbara E.