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Capone, L. A.

Publications and source records attributed to Capone, L. A..

32 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Effect of the reaction HO2 + O3 yields OH + 2O2 on stratospheric ozone

It is noted that recent measurements of large values of the rate coefficient for the reaction NO + HO2 yields NO2 + OH lead to model predictions of excessive amounts of stratospheric ozone. This letter shows that a recent measurement of the rate coefficient (k2) for the reaction HO2 + O3 yields OH + 2O2 largely resolves these problems of excessive stratospheric ozone in models. A two-dimensional model of stratospheric trace constituents is used to calculate the concentrations of 35 constituents; the results are compared with experimental measurements of ozone column densities. It is found that the model predictions of excess ozone abundances diminish significantly when the measured value of k2 is employed.

Whitten, R. C.↗
NASA NTRS1978

An assessment of the effect of supersonic aircraft operations on the stratospheric ozone content

An assessment of the potential effect on stratospheric ozone of an advanced supersonic transport operations is presented. This assessment, which was undertaken because of NASA's desire for an up-to-date evaluation to guide programs for the development of supersonic technology and improved aircraft engine designs, uses the most recent chemical reaction rate data. From the results of the present assessment it would appear that realistic fleet sizes should not cause concern with regard to the depletion of the total ozone overburden. For example, the NOx emission of one type designed to cruise at 20 km altitude will cause the ozone overburden to increase by 0.03% to 0.12%, depending upon which vertical transport is used. These ozone changes can be compared with the predictions of a 1.74% ozone decrease (for 100 Large SST's flying at 20 km) made in 1974 by the FAA's Climatic Impact Assessment Program.

Poppoff, I. G.↗
NASA NTRS1977

The NASA Ames Research Center one- and two-dimensional stratospheric models. Part 2: The two-dimensional model

The two-dimensional model of stratospheric constituents is presented in detail. The derivation of pertinent transport parameters and the numerical solution of the species continuity equations, including a technique for treating the stiff differential equations that represent the chemical kinetic terms, and appropriate methods for simulating the diurnal variations of the solar zenith angle and species concentrations are discussed. Predicted distributions of tracer constituents (ozone, carbon 14, nitric acid) are compared with observed distributions.

Whitten, R. C.↗
NASA NTRS1977

The ionospheres of Saturn, Uranus, and Neptune

Models of the ionospheres of Saturn, Uranus, and Neptune are presented. It is postulated that galactic cosmic-ray ionization is an important component of these ionospheres. For example, in the case of Neptune, the level of ionization caused by cosmic rays is comparable with that due to solar extreme-ultraviolet (EUV) radiation. The existence of cosmic-ray, as well as solar EUV-produced ionization, could be a valuable diagnostic tool for investigating the atmospheric thermal structure of those planets.

Capone, L. A.↗
NASA NTRS1977

The upper ionosphere of Titan

Photoionization of the upper atmosphere of Titan by sunlight is expected to produce a substantial ionospheric layer. One-dimensional forms of the mass, momentum, and energy conservation equations for ions and electrons have been solved along with electron number densities of about 1000/cu cm, using various model atmospheres. The significant ions in a CH4-H2 atmosphere are H(+), H3(+), CH5(+), CH3(+), and C2H5(+). Electron temperatures may be as high as 1000 K, depending on the abundance of hydrogen in the high atmosphere. Interaction of the solar wind with the ionosphere is also discussed.

Whitten, R. C.↗
NASA NTRS1976

Model predictions of latitude-dependent ozone depletion due to supersonic transport operations

Results are presented from a two-dimensional model of the stratosphere that simulates the seasonal movement of ozone by both wind and eddy transport, and contains all the chemistry known to be important. The calculated reductions in ozone due to NO2 injection from a fleet of supersonic transports are compared with the zonally averaged results of a three-dimensional model for a similar episode of injection. The agreement is good in the northern hemisphere, but is not as good in the southern hemisphere. Both sets of calculations show a strong corridor effect in that the predicted ozone depletions are largest to the north of the flight corridor for aircraft operating in the northern hemisphere.

Borucki, W. J.↗
NASA NTRS1976

The photochemistry of ammonia in the Jovian atmosphere

A reinvestigation of the ammonia photochemistry in the Jovian lower atmosphere above the cloud tops is conducted in connection with certain questions concerning the model proposed by Strobel (1973). Chemical reactions and their rate coefficients are considered along with the model atmosphere, solar fluxes, the continuity equations, and numerical details. Differences between the newmodel and Strobel's model are related to more moderate ammonia depletion relations. The height profiles of H, NH2, N2H3, N2H4, and NH3 concentrations are presented in a graph.

Prasad, S. S.↗
NASA NTRS1976

The lower ionosphere of Titan

Ionization of the atmosphere of Titan by galactic cosmic rays is a very significant process throughout the altitude range from 100 to 400 km. An approximate form of the Boltzmann equation for cosmic-ray transport has been used to obtain local ionization rates. Models of both ion and neutral chemistry have been employed to compute electron and ion density profiles for three different values of the H2/CH4 abundance ratio. The peak electron density is of the order of 1000 per cu cm. The most abundant positive ions are C2/H9(+) and C3H9(+), while the predicted densities of the negative ions H(-) and CH3(-) are very small (less than one ten-thousandth that of the positive ions). It is suggested that inclusion of the ion chemistry is important in the computation of the H and CH3 density profiles in the lower ionosphere.

Capone, L. A.↗
NASA NTRS1976

Model predictions of latitude-dependent ozone depletion due to aerospace vehicle operations

Results are presented from a two-dimensional model of the stratosphere that simulates the seasonal movement of ozone by both wind and eddy transport, and contains all the chemistry known to be important. The calculated reductions in ozone due to NO2 injection from a fleet of supersonic transports are compared with the zonally averaged results of a three-dimensional model for a similar episode of injection. The agreement is good in the northern hemisphere, but is not as good in the southern hemisphere. Both sets of calculations show a strong corridor effect in that the predicted ozone depletions are largest to the north of the flight corridor for aircraft operating in the northern hemisphere.

Borucki, W. J.↗
NASA NTRS1976

Diurnal variation of the Jovian ionosphere

The time-dependent structure of the Jovian ionosphere is examined. Diurnal variation of appreciable magnitude is revealed in the lower ionosphere. The upper ionosphere remains more or less intact at nighttime, as in the case of the earth's ionosphere. There is considerable difference in the height-integrated electrical conductivities on the day and night sides.

Tan, A.↗
NASA NTRS1975

Photochemistry of hydrocarbons in the Jovian upper atmosphere

The possibility of catalytic destruction of H by C2H2 in the Jovian upper atmosphere is investigated, and other photochemical hydrocarbon reactions are presented. It is shown that the catalytic action of C2H2 can destroy or preserve atomic hydrogen, depending on the branching ratio of an intermediate reaction and the temperature dependence of various reaction rates. A model Jovian atmosphere is constructed, and the altitude profiles of some species are plotted. It is noted that this model has a greater atomic hydrogen abundance and a lower concentration of C2H2 than previous ones, and that the H profile should be considered as an upper limit for the Jovian atmosphere.

Prasad, S. S.↗
NASA NTRS1974

The Ames two-dimensional stratosphere-mesospheric model

A two-dimensional model of the stratosphere and mesosphere has recently been developed at Ames Research Center. The model contains chemistry based on 18 species that are solved for at each step and a seasonally-varying transport model based on both winds and eddy transport. The model is described and a preliminary assessment of the impact of supersonic aircraft flights on the ozone layer is given.

Whitten, R. C.↗
NASA NTRS1973

Jovian ionospheric models

This paper reports results obtained on ionosphere formation in the Jovian upper atmosphere with special reference to some of the recently available reaction rates, and to recent models of the Jovian neutral atmosphere based on the possibility of a warmer mesopause. In the older models of the Jovian ionosphere, the major ions were H+ which were lost only by pure radiative recombination. This led to high electron densities and practically no diurnal change. In contrast, recent models have relatively much smaller electron densities, especially in lower regions, and may be susceptible to significant diurnal variation.

Capone, L. A.↗