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Callis, L. B.

Publications and source records attributed to Callis, L. B..

At least 37 records · Page 2
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NASA NTRS1981

Atmospheric carbon dioxide and chlorofluoromethanes - Combined effects on stratospheric ozone, temperature, and surface temperature

The effects of combined CO2 and CFCl3 and CF2Cl2 time-dependent scenarios on atmospheric O3 and temperature are described; the steady-state levels of O3 and surface temperature, to which the chlorofluoromethane scenario tends in the presence of twice and four time ambient CO2, are examined; and surface temperature changes, caused by the combined effects, are established. A description of the model and of the experiments is presented. Results indicate that (1) the total ozone time history is significantly different from that due to the chlorofluoromethane alone; (2) a local ozone minimum occurs in the upper stratosphere about 45 years from the present with a subsequent ozone increase, then decline; and (3) steady-state solutions indicate that tropospheric temperature and water vapor increases, associated with increased infrared opacity, cause significant changes in tropospheric ozone levels for 2 x CO2 and 4 x CO2, without the addition of chlorofluoromethanes.

Callis, L. B.↗
NASA NTRS1981

Solar UV variability - Effects on stratospheric ozone, trace constituents and thermal structure

The effect of long-term (11-year solar cycle) solar UV variability on stratospheric chemical and thermal structure has been studied using a time-dependent one-dimensional model. Previous studies have suggested substantial variations in local and total ozone, and in stratospheric thermal structure from solar minimum to solar maximum. It is shown that significant variations also occur in some of the trace constituents. Members of the HOx family and N2O exhibit the largest variations, and these changes, if detected, may provide additional means of verifying the presence of solar UV variability and its effects. Some of the species show large phase differences with the assumed solar flux variation. The role of chemical and transport time constants on the time variations of the trace species is examined. Comparisons with reported ozone and temperature data show reasonable agreement for the period 1960 to 1972.

Natarajan, M.↗
NASA NTRS1981

Stratospheric ozone and temperature perturbations - An examination of synergistic effects

Experiments have been carried out to investigate the time-dependent effects of combined releases of CO2 and chlorofluoromethanes (CFM) on stratospheric ozone and temperature. The analysis also examines the effects of steady-state variations in CFM, CO2, and solar UV flux levels on surface temperature and latitudinal temperature distribution. Results indicate that ozone depletion, due to combined effects of CO2 and CFM increases, may show a local maximum of about 6% at about the time CO2 doubles (approximately 60 yr from now). After that, the downward trend in ozone due to Cl(x) catalytic destruction is reestablished and continues, reaching approximately 15% depletion. At steady state, compensation due to CO2 increases is approximately 1% for two to four times the ambient CO2 levels.

Callis, L. B.↗
NASA NTRS1981

Study of the response of stratospheric ozone to perturbations in the solar constant and solar UV flux

A one-dimensional radiative-convective photochemical model has been used to examine the response of stratospheric and total ozone to perturbations in the solar flux. The model considers a detailed chemical reaction mechanism; vertical transport is parameterized through eddy diffusion coefficients. The temperature profile is calculated using a radiative transfer model for both time-dependent and steady-state cases. Results are discussed for the following types of perturbations: a 5% increase in the solar UV flux in the wavelength range 175-300 nm, a 5% increase in the solar constant, and an annual 6.6% variation in the solar constant associated with the variation in the earth-sun distance.

Natarajan, M.↗
NASA NTRS1979

Solar variability and ozone

Stratospheric temperature and concentration of ozone above 26 km, as measured by rocket-borne instruments, showed an increase from 1964 to 1969-70, and a decline between 1970 and 1975, closely following the solar cycle, which peaked in 1969 (+0.89 correlation at both 35 and 50 km). Similar correlations were found between the ozone density and the 10.7 cm solar radio flux (as measured by the Nimbus IV satellite), and between ozone column density and the Lyman-alpha flux, both observations being taken over the same 10 month period. A mechanism is hypothesized which would link solar flux variation with both changes in stratospheric temperature and concentration of ozone (which is produced by the photodissociation of stratospheric oxygen molecules by solar radiation in the ultraviolet wavelength region).

Callis, L. B.↗
NASA NTRS1979

Ozone and temperature trends associated with the 11-year solar cycle

Evidence is presented which suggests that trends in the ozone concentration and stratospheric temperature, reported between the early 1960's and 1976, are to a large extent due to solar ultraviolet flux variability associated with the 11-year solar cycle. Radiative-convective-photochemical simulations of ozone and temperature variations have been made with a solar ultraviolet flux variability model. Results for temperatures and ozone concentrations, when compared with published data, show good agreement.

Callis, L. B.↗
NASA NTRS1978

Solar UV variability and its effect on stratospheric thermal structure and trace constituents

Observational evidence suggests the presence of solar UV variability in the spectral range 0.175-0.310 micron during the 11-year solar cycle. The present paper reports the results of a study using a steady-state 1-D radiative-convective-photochemical model conducted to determine the response of stratospheric temperatures and O3, O(1D), O(3P), and N2O constituent distributions to UV variability. Results show that concentrations of constituents and the thermal structure may be altered significantly for the altitude interval between 20 and 55 km.

Callis, L. B.↗
NASA NTRS1978

On the coupled nature of atmospheric phenomena

The interactions that take place in the stratosphere and the troposphere which are important to the maintenance of the chemical, dynamic, and thermal state and of the middle atmosphere, and which may be important in the determination of the state of the lower atmosphere are reviewed. Examples of these interactions due to either natural or anthropogenic processes are discussed, and promising areas for future research are indicated. Specific topics include: (1) coupling between temperature and chemistry via temperature dependent rate constants; (2) the effect of latitudinal temperature variations on zonal winds; (3) the effect of clouds, surface albedo, and the lower atmosphere on stratospheric chemistry due to the scattering and reflection of solar radiation; (4) the effect of trace constituents on thermal structure and thermal balance; (5) the effect of the stratosphere on tropospheric climate; (6) the effect of solar UV variability on stratospheric chemistry and temperature; and (7) the effect of trace constituents on stratospheric dynamics.

Callis, L. B.↗
NASA NTRS1977

The effect of UV variability on stratospheric thermal structure and trace constituents

The paper examines the effect of observed UV flux variability in the spectral region of 0.175-0.3 microns on: (1) atmospheric concentrations of O3, O(1 D), OH, NO2, HNO3, and N2O; (2) stratospheric temperature structure; and (3) the calculated surface temperature. It is shown that perturbations in the number densities of the above constituents may be as large as 90 percent and that temperature deviations may range from 2 to 8 K for the altitude interval 20-40 km. These results have been determined using a 1-D radiative-convective-photochemical model.

Callis, L. B.↗
NASA NTRS1976

Sensitivity of surface temperature and atmospheric temperature to perturbations in the stratospheric concentration of ozone and nitrogen dioxide

A radiative-convective model is proposed for estimating the sensitivity of the atmospheric radiative heating rates and atmospheric and surface temperatures to perturbations in the concentration of O3 and NO2 in the stratosphere. Contribution to radiative energy transfer within the atmosphere from H2O, CO2, O3, and NO2 is considered. It is found that the net solar radiation absorbed by the earth-atmosphere system decreases with a reduction in O3; if the reduction of O3 is accompanied by an increase in NO2, there is a compensating effect due to solar absorption by NO2. The surface temperature and atmospheric temperature decrease with decreasing stratospheric O3. Another major conclusion is the strong sensitivity of surface temperature to the vertical distribution of O3 within the atmosphere. The results should be considered as reflecting the sensitivity of the proposed model rather than the sensitivity of the actual earth-atmosphere system.

Ramanathan, V.↗
NASA NTRS1972

The radiative transfer equation and environmental effects in the upper atmosphere.

A highly effective approach to the solution of the radiative transfer equation, including the effects of emission, absorption, and multiply scattered radiation, is described. The transfer equation is cast in its unsteady hyperbolic form which is amenable to several different numerical methods of solution. Comparisons of solutions with emission, absorption, and scattering of radiation, are presented to demonstrate the validity of the present approach.

Callis, L. B.↗