Burgeson, Eric M. | Engineering Papers

DOE OSTI2020

A Cast Net Thrown onto an Interface: Wrapping 3D Objects with an Interfacially Jammed Amphiphilic Sheet

Wrapping a 3D object with a 2D sheet is not uncommon, but the wrapping behavior becomes complex and interesting when the sheet is bestowed with strong interfacial activities. Amphiphilic lignin macromolecules, isolated from biomass, form a scalable thin surfactant sheet at an oil/water interface through the interfacial jamming process. The process marks three distinct stages of interfacial behavior: a) diffusive assembly, b) viscous assembly with retarded mobility, and c) flexible yet irreversibly jammed rigid sheets. The surfactant sheet wraps, traps, and promptly stabilizes both oil and water droplets in nonequilibrium morphologies upon environmental stimulus. Finally, beyond preserving exotic morphologies, the highly interfacially active surfactant sheet also participates in morphology evolution by creating a vanishing interfacial tension and driving interfacial instability around the wrapped content, leading to novel morphologies as well as many potential applications.

36 MATERIALS SCIENCE↗

DOE OSTI2019

Co-Continuous Phase Nanofiber Composites

We report on the development of a co-continuous phase composite with a polyacrylonitrile (PAN nanofiber network integrated into an acrylonitrile-butadiene-styrene (ABS) matrix that offers improved mechanical strength. Homogeneous dispersion of nanomaterials in a matrix can be challenging and typically involves mechanical mixing or chemical modification. This work overcomes this obstacle by taking an inverse approach in that a nanoscale network is synthesized then infiltrated with polymer instead of attempting to disperse the nanomaterial in the polymer. This not only enables excellent homogeneity but also allows the nanoscale phase to be continuous throughout the composite. Here, PAN is electrospun to form a random network of nanofibers having diameters of roughly 200 nm, which is then infiltrated with ABS using solution processing. By optimizing the heat treatments and ABS concentrations, the tensile strength and elastic modulus were improved by 208% and 313%, respectively, as compared to the bare PAN nanofibers. Since there has been significant previous research efforts on electrospinning polymers, many different nanofiber and polymer systems can be made into composites using the methodology established in this work. Therefore, this research offers a new route to create a co-continuous composite with the aim to replace some existing fiber reinforced composites.

Bowland, Christopher↗