Engineering topics

Bunch, T. E.

Publications and source records attributed to Bunch, T. E..

At least 37 records · Page 2

NASA NTRS1992

Observation of fullerenes (C60-C70) associated with LDEF crater number 31

The presence of fullerenes in and around the LDEF crater number 31 is reported. This crater has a high C level associated with it, and is interpreted as having been produced by the impact of a C-rich micrometeoroid. Fullerenes are large 3-D C structures, among which the species C sub 60 (MW 720) and C sub 70 (MW 840) are preeminent. Fullerenes have several UV absorption bands, hence fullerenes should be detectable using UV laser ionization time-of-flight mass spectrometry. We use a LIMA-2A instrument with pulsed UV laser (266 nm) to search for high mass C species associated with LDEF crater number 31. The mass range was 0 to 1200 amu. Low ablating laser power levels were used (less than or = 5 x 10 exp 7 W/sq. cm); 200 mass spectra were acquired and summed. We observed high mass signals near m/z 720, exhibiting 24 amu separation, which is characteristic of fullerenes. Alkali ion signals were also observed. Little or no C clusters of intermediate mass were observed. We interpret the signals around m/z 720 as fullerenes, mainly C sub 60+ with lower levels of C sub 70+. We propose that the mechanism that produces these signals is resonant multiphoton ionization (REMPI). This selective mechanism explains why low mass C cluster ions are not observed along with the fullerenes, since they have much higher ionization potentials. This finding is unexpected, since up to now the search for fullerenes in extraterrestrial materials has not been successful. We conclude that the fullerenes became associated with crater number 31 in space. Two alternative (and exciting) scenarios are being considered at this time: either the fullerenes were carried by the C-rich projectile that formed crater number 31, or the fullerenes formed upon impact with the LDEF. We show the results of experiments at the ARC Vertical Gun Facility, which may establish some constraints on the origin of the fullerenes.

Radicatidibrozolo, Filippo↗

NASA NTRS1992

LDEF impact craters formed by carbon-rich impactors: A preliminary report

Two impact craters found in Al from the Long Duration Exposure Facility (LDEF) experiment tray have residues concentrated in the bottoms, along the walls, and on top of overturned rims. Analyses indicate a 'chondritic' compositional signature (Si, S, Ca, Fe, Mg, and Ni) for the bulk residue. In one crater (number 74), round to irregular silicate grains are overlain by carbon. In addition, carbon also partially covers the crater walls, the top of the raised overturned rim, and extends outward from the crater. The second crater (number 31) also contains carbon with similar distribution in and about the crater, although the silicate residue appears to be glassy. Silver, I, K, and F (possibly some of the Ca, S, and Cl) appear to be contaminants as well as analyzed aromatic carbonaceous species associated with the raised rim and the area surrounding the crater. The origin of the impactors is assumed to be extraterrestrial. The existence of impactor residue in two craters implies impact velocities less than or equal to 6 km, based on experimental hypervelocity studies.

Bunch, T. E.↗

NASA NTRS1991

LDEF post-retrieval evaluation of exobiology interests

Cursory examination of the Long Duration Exposure Facility (LDEF) shows the existence of thousands of impact craters of which less than 1/3 exceed 0.3 mm in diameter; the largest crater is 5.5 mm. Few craters show oblique impact morphology and, surprisingly, only a low number of craters have recognizable impact debris. Study of this debris could be of interest to exobiology in terms of C content and carbonaceous materials. All craters greater that 0.3 mm have been imaged and recorded into a data base by the preliminary examination team. Various portions of the LDEF surfaces are contaminated by outgassed materials from experimenters trays, in addition to the LDEF autocontamination and impact with orbital debris not of extraterrestrial origin. Because interplanetary dust particles (IDP's) nominally impacted the LDEF at velocities greater than 3 km/s, the potential for intact survival of carbonaceous compounds is mostly unknown for hypervelocity impacts. Calculations show that for solid phthalic acid (a test impactor), molecular dissociation would not necessarily occur below 3 km/s, if all of the impact energy was directed at breaking molecular bonds, which is not the case. Hypervelocity impact experiments (LDEF analogs) were performed using the Ames Vertical Gun Facility. Grains of phthalic acid and the Murchison meteorite (grain diameter = 0.2 for both) were fired into an Al plate at 2.1 and 4.1 km/s respectively. The results of the study are presented, and it is concluded that meaningful biogenic elemental and compound information can be obtained from IDP impacts on the LDEF.

Bunch, T. E.↗

NASA NTRS1991

LDEF impact craters formed by carbon-rich impactors

Two small craters (number 74, 119 microns, and number 31, 158 microns in diameter) with depth to diameter ratios of about 0.59 and 0.8, respectively, were found in Al from the Long Duration Exposure Facility (LDEF) experiment tray A11EOOF). Both craters have residues concentrated in the crater bottoms, along the walls, and on top of the overturned rims. Low voltage scanning electron electron microscopy, Auger electron spectroscopy, time of flight secondary ion mass spectroscopy and energy dispersive x-ray spectroscopy were used to obtain high resolution imagery and elemental analysis. Analyses indicate that the impactor for both craters was carbon-rich, as the residues contain mostly C. Silicon, S, and F in low concentrations are present on the Al surface away from the craters and may be, in part, contaminants.

Bunch, T. E.↗

NASA NTRS1991

Are some chondrule rims formed by impact processes? - Observations and experiments

The ability of high-speed impacts into a parent body regolith to account for the textures and compositions observed for rims on some chondrules is presently supported by both observational and experimental data. Experimental results obtained with a light-gas gun encompass recovered-grain characteristics ranging from fragmented projectile grains mixed with melted aerogel, demonstrating that rim-like thermal and mechanical alterations of projectiles may be due to a high-velocity encounter with a low density target. Irrespective of conclusions for other types of rims, granular and opaque rim characteristics seem inconsistent with nebular condensation.

Bunch, T. E.↗

NASA NTRS1991

Imaging analysis of LDEF craters

Two small craters in Al from the Long Duration Exposure Facility (LDEF) experiment tray A11E00F (no. 74, 119 micron diameter and no. 31, 158 micron diameter) were analyzed using Auger electron spectroscopy (AES), time-of-flight secondary ion mass spectroscopy (TOF-SIMS), low voltage scanning electron microscopy (LVSEM), and SEM energy dispersive spectroscopy (EDS). High resolution images and sensitive elemental and molecular analysis were obtained with this combined approach. The result of these analyses are presented.

Radicatidibrozolo, F.↗

NASA NTRS1990

Cosmic Dust Collection Facility: Scientific objectives and programmatic relations

The science objectives are summarized for the Cosmic Dust Collection Facility (CDCF) on Space Station Freedom and these objectives are related to ongoing science programs and mission planning within NASA. The purpose is to illustrate the potential of the CDCF project within the broad context of early solar system sciences that emphasize the study of primitive objects in state-of-the-art analytical and experimental laboratories on Earth. Current knowledge about the sources of cosmic dust and their associated orbital dynamics is examined, and the results are reviewed of modern microanalytical investigations of extraterrestrial dust particles collected on Earth. Major areas of scientific inquiry and uncertainty are identified and it is shown how CDCF will contribute to their solution. General facility and instrument concepts that need to be pursued are introduced, and the major development tasks that are needed to attain the scientific objectives of the CDCF project are identified.

Hoerz, Fred↗

NASA NTRS1990

Processing of refractory meteorite inclusions (CAIs) in parent-body atmospheres

Ca-Al-rich inclusions (CAIs) in refractory meteorites are shown to have been subject to partial melting during a suitably high gas density/small scale height regime arising during gasdynamic deceleration in a temporary atmosphere around an accreting parent body. The presence of dust in such an atmosphere would have increased the pressure gradient with height, lowering the boiloff rate, and permitting dust particles to become trapped in the partially melted material. CAIs may therefore be studied as probes of a primitive atmosphere.

Podolak, Morris↗

NASA NTRS1988

Analytical electron microscopy of a hydrated interplanetary dust particle

Properties of a hydrated interplanetary dust particle (IDP), Ames-Dec86-11, were investigated using TEM and analytical electron microscopy. The particle was found to have mineralogy and chondritic composition indicating an absence of direct kinship with known carbonaceous chondrites. The available data on the Ames-Dec86-11 suggest that at least one aqueous alteration event took place in this hydrated IDP, during which fine-grained material, possibly glass, was transformed to smectite. This event appears to be unique to hydrated IDPs.

Blake, David F.↗

NASA NTRS1988

Meteorite regolithic breccias

In addition to endogenic processes such as heating and aqueous activity, meteorite parent bodies were subjected also to exogenic processing brought about by the impact of the other solar-system objects. Such impacts can produce a variety of effects, ranging from shock metamorphism of individual mineral grains to production of breccias; i.e., rocks consisting of mixtures of disparate lithic units. The present paper reviews recent studies of such breccias, which have generated significant information about the accretional growth of parent bodies, as well as their evolution, composition, stratigraphy, and geological processing.

Bunch, T. E.↗

NASA NTRS1987

Low voltage scanning electron microscopy of interplanetary dust particles

The resolution of available low-voltage SEM (LVSEM) models used in the characterization of interplanetary dust particles (IDPs) is limited by a number of factors including energy spread in the electron source, beam brightness, scanning electron detector geometry, and various lens aberrations. This paper describes an improved model of LVSEM which offers an increased resolution at low voltage. The improvements include a cold cathode FE source which has an extremely low inherent energy spread and high brightness, a second condenser lens to converge the beam and maintain an optimum aperture half-angle, and a detector optimized for low-voltage scanning-electron collection. To reduce lens aberrations, the specimen is immersed in the objective lens field. The features of several IDP samples observed using the images obtained with this LVSEM model are described.

Blake, D. F.↗

NASA NTRS1987

Analytical electron microscopy of extraterrestrial materials - Results from microtome sections of carbonaceous chondrites and interplanetary dust particles

The paper describes a method for embedding, sectioning, and observing two types of extraterrestrial materials, including hydrated interplanetary dust particles (IDPs) and carbonaceous chondrite meteorites. The technique, which produces large thin areas suitable for both high-resolution imaging and thin-film microanalysis, was applied to study the petrology of the IDP Ames-DE C86-11, the Murchison carbonaceous chondrite matrix, and the Allende dark inclusion. The technique makes it possible to maintain delicate interfaces, boundaries, and phase relationships between grains. Because phases are held in place, layer lattice silicates and other minerals with strong preferred orientations can be viewed in any orientation, including the orientation normal to their basal planes.

Blake, D. F.↗

NASA NTRS1987

A simple device for the preparation of embedded materials science specimens for ultramicrotomy

A simple hand-held grinding fixture is discussed which can produce microtome mounts of hard materials, oriented interfaces, and powders embedded in a 5/16-in plastic rod. The device has been used for the ultramicrotomy of meteorite samples, 10-50 micron interplanetary dust particles, and thin films on plastic. Results are presented for a layer lattice silicate from the Murchison carbonaceous chondrite, illustrating the resolution and structural detail that can be obtained with the method.

Blake, D. F.↗

NASA NTRS1986

Characterization of biogenic elements in interplanetary dust particles

Those particles that were designated cometary are aggregates of amorphous materials including carbon, iron-magnesium silicates, sulfides, metal and trace amounts of unusual phases. Most aggregates are carbon-rich with major and minor element abundances similar to a fine grained matrix of carbonaceous chondrites. Several particles were analyzed by a laser microprobe. The negative ionic species identified to date include carbon clusters, protonated carbon clusters, CN-, HCN-, CNO-, PO2-, PO3-, S-, S2- asnd OH-. These species are similar to those observed in cometary spectra and they support the assumption that organic materials are present. The occurance of phosphate ions suggests the presence of apatite or whitlockite. Cometary particle characteristics may indicate that the component grains represent primitive unaltered dust whose overall properties are extremely similar to altered primitive dust in carbonaceous chondrites.

Bunch, T. E.↗

NASA NTRS1986

New techniques for the detection and capture of micrometeoroids

In order to understand the origin and distribution of the biogenic elements and their compounds in the solar system, it will be necessary to study material from many classes of objects. Chemical, elemental, and isotopic measurements of returned samples of comets, asteroids, and possibly extra-solar system dust clouds would provide information on a particularly important class: the primitive objects. Extraterrestrial micron-sized particles in the vicinity of earth are one source of such materials that might otherwise be inaccessible. The Space Station appears to be an eminently suitable platform from which to collect and detect these various particles. The primary challenge, however, is to collect intact, uncontaminated particles which will be encounted at tens of kilometers per seconds. A concept for a micrometeoroid detector that could be deployed at a Space Station has been developed which uses a large area detector plate implanted with acoustic transducers. When an impact event occurs, the resulting signal is subjected to spectral analysis providing positive detection, momentum information, and angle of incidence. The primary advantage of this detector is the large area which increases the probability of measuring events.

Wolfe, J. H.↗

NASA NTRS1986

Laser microprobe characterization of C species in Interplanetary Dust Particles (IDP)

Preliminary results of a study whose aim is the characterization of carbon (C) species in microvolumes of materials by means of laser ionization mass spectrometry (LIMS) are presented. The LIMS instrument employs a pulsed UV laser to produce nearly instantaneous vaporization and ionization of materials, followed by acceleration and time-of-flight analysis of the ions produced. LIMS provides a survey technique with nearly simultaneous acquisition of mass spectra covering the entire elemental range. The main limitation of the LIMS technique at present is its limited ability to perform quantitative analysis, due in part to insufficient knowledge of the mechanism of laser-solid interaction. However, considerable effort is now being directed at making LIMS a more quantitative technique. A variety of different C samples, both natural and man made were analyzed to establish the ability of LIMS to differentiate among the various C phases. The results of preliminary analyses performed on meteoritical and interplanetary dust samples are also presented. The C standards selected for the LIMS characterization range from essentially amorphous soot to diamond, which exhibits the highest degree of ordering.

Dibrozolo, F. R.↗

NASA NTRS1986

A micrometeoroid deceleration and capture experiment: Conceptual experiment design description

The preliminary conceptual design for a cosmic dust collector is described. For the case of low Earth orbit (LEO), dust particles enter the collector through the collimator at a few volts negative potential due to charging in the ionosphere, at a velocity of 1 to 50 km/sec. The particles then pass through an electron stream and are charged to about 1 KV negative (regardless of incoming polarity). The 1 KV negatively charged particle then passes through three sensing grids coupled to charge sensitive preamps (CSP). The comparison of the two pulses provided by S(1) and S(2) are utilized by the microprocessor to determine the charge, q, on the particle (pulse amplitude) and its velocity, v (by time of flight). The third sensing grid, S(3), is kept at about 20 KV negative so that the dust particle will now be decelerated in passing from S(2) (zero potential) to S(3). S(3) is capacitively coupled to its CSP and the pulse from S(3) is utilized by the microprocessor to determine the particle's energy, E, and therefore its mass, m (again by time of flight) by comparison with the pulses from S(1) and S(2). The microprocessor can now precisely program the high-voltage switching network for the proper timing in the grounding of the successive deceleration grids. As determined by the microprocessor, each successive deceleration grid is grounded just after the dust particle passes, thus reducing the particle's energy by the amount q*100 KV at each stage. The microprocessor also determines at which stage the particle will fall below a certain critical energy where all remaining grids remain unswitched so that the particle will drift to the collector. The collector is kept at about 100V positive and is covered with gold foil to eliminate contamination and is removable for subsequent return to earth for detailed analysis.

Wolfe, J. H.↗

NASA NTRS1984

Equilibration temperatures of the ordinary chondrites - A new evaluation

The novel calibrations of the Ca-pyroxene thermometer accomplished by Kretz (1982) and Lindsley (1983) are presently applied to 24 analyzed pyroxenes from 24 H6, L6, and LL6 chondrites. Both thermometers indicate that the H group equilibrated to significantly lower temperature (820-830 C) than the L and LL groups, yielding values of 860 C (Lindsley) to 930 C (Kretz).

Olsen, E. J.↗