Engineering topics
Publications and source records attributed to Bull, Jeffrey.
High temperature ablation resistant ceramic composites have been made. These ceramics are composites of zirconium diboride and zirconium carbide with silicon carbide, hafnium diboride and hafnium carbide with silicon carbide and ceramic composites which contain mixed diborides and/or carbides of zirconium and hafnium. along with silicon carbide.
The Slender Hypersonic Aerothermodynamic Research Program (SHARP) was initiated by NASA Ames, and executed in partnership with Sandia National Laboratory and the US Air Force, to demonstrate sharp, passive leading edge designs for hypersonic vehicles, incorporating new ultra-high temperature ceramics (UHTC's). These new ceramic composites have been undergoing development, characterization and ground testing at NASA Ames for the last nine years. This paper will describe the background, flight objectives, design and pertinent flight results of SHARP, and some of the potential implications for future hypersonic vehicle designs.
The objective of this flight demonstration is to deploy a slender-body hypervelocity aerodynamic research probe (SHARP) from an orbiting platform using a tether, deorbit and fly it along its aerothermal performance constraint, and recover it intact in mid-air. To accomplish this objective, two flight demonstrations are proposed. The first flight uses a blunt-body, tethered reentry experiment vehicle (TREV) to prove out tethered deployment technology for accurate entries, a complete SHARP electronics suite, and a new soft mid-air helicopter recovery technique. The second flight takes advantage of this launch and recovery capability to demonstrate revolutionary sharp body concepts for hypervelocity vehicles, enabled by new Ultra-High Temperature Ceramics (UHTCs) recently developed by Ames Research Center. Successful demonstration of sharp body hypersonic vehicle technologies could have radical impact on space flight capabilities, including: enabling global reentry cross range capability from Station, eliminating reentry communications blackout, and allowing new highly efficient launch systems incorporating air breathing propulsion and zeroth staging.
Aluminoborosilicate powders high in alumina content were synthesized by the sol-gel process utilizing various methods of preparation. Properties and microstructural effects related to these syntheses were examined. After heating to 600 C for 2 h in flowing air, the powders were amorphous with the metal oxides comprising 87 percent of the weight and uncombusted organics the remainder. DTA of dried powders revealed a T(sub g) at approximately 835 C and an exotherm near 900 C due to crystallization. Powders derived from aluminum secbutoxide consisted of particles with a mean diameter 5 microns less than those from aluminum isopropoxide. Powders synthesized with aluminum isopropoxide produced agglomerates comprised of rod shaped particulates while powders made with the secbutoxide precursor produced irregular glassy shards. Compacts formed from these powders required different loadings for equivalent densities according to the method of synthesis.
Aluminoborosilicate (ABS) powders, high in alumina content, were synthesized by the sol-gel process utilizing four different methods of synthesis. The effect of these methods on the densification behavior of ABS powder compacts was studied. Five regions of shrinkage in the temperature range 25-1184 C were identified. In these regions, the greatest shrinkage occurred between the gel-to-glass transition temperature (T sub g approximately equal to 835 C) and the crystallization transformation temperature (T sub t approximately equal 900 C). The dominant mechanism of densification in this range was found to be viscous sintering. ABS powders were amorphous to x-rays up to T sub t at which a multiphasic structure crystallized. No 2Al2O3.B2O3 was found in these powders as predicted in the phase diagram. Above T sub t, densification was the result of competing mechanisms including grain growth and boria fluxed viscous sintering. Apparent activation energies for densification in each region varied according to the method of synthesis.
Application of sol-gel process to synthesis of aluminoborosilicate powders shows potential for control of microstructures of materials. Development of materials having enhanced processing characteristics prove advantageous in extending high-temperature endurance of fibrous refractory composite insulation made from ceramic fibers.
The performance of rigid insulations for use as thermal protection materials on reentry vehicles can be characterized by their resistance to dimensional and morphological change when exposed to an isothermal environment equivalent to that generated in entry. Improvements in these material characteristics for alumina-enhanced thermal barrier insulation by compositional modification through sol-gel processing are reported.