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Bryant, E.

Publications and source records attributed to Bryant, E..

9 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Temperature Dependence of Diffusion and Reaction at a Pd/SiC Contact

Schottky diodes of Palladium/SiC are good candidates for hydrogen and hydrocarbon gas sensors at elevated temperature. The detection sensibility of the diodes has been found heavily temperature dependent. In this work, emphasis has been put on the understanding of changes of physical and chemical properties of the Schottky diodes with variation of temperature. Schottky diodes were made by depositing ultra-thin palladium films onto silicon carbide substrates. The electrical and chemical properties of Pd/SiC Schottky contacts were studied by XPS and AES at different annealing temperatures. No significant change in the Schottky barrier height of the Pd/SiC contact was found in the temperature range of RT-400 C. However, both palladium diffused into SiC and silicon migrated into palladium thin film as well as onto surface were observed at room temperature. The formation of palladium compounds at the Pd/SiC interface was also observed. Both diffusion and reaction at the Pd/SiC interface became significant at 300 C and higher temperature. In addition, silicon oxide was found also at the interface of the Pd/SiC contact at high temperature. In this report, the mechanism of diffusion and reaction at the Pd/SiC interface will be discussed along with experimental approaches.

Shi, D.T.↗
NASA NTRS1998

"Un-annealed and Annealed Pd Ultra-Thin Film on SiC Characterized by Scanning Probe Microscopy and X-ray Photoelectron Spectroscopy"

Pd/SiC has been used as a hydrogen and a hydrocarbon gas sensor operated at high temperature. UHV (Ultra High Vacuum)-Scanning Tunneling Microscopy (STM), Atomic Force Microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS) techniques were applied to study the relationship between the morphology and chemical compositions for Pd ultra-thin films on SiC (less than 30 angstroms) at different annealing temperatures. Pd ultra-thin film on 6H-SiC was prepared by the RF sputtering method. The morphology from UHV-STM and AFM shows that the Pd thin film was well deposited on SiC substrate, and the Pd was partially aggregated to round shaped participates at an annealing temperature of 300 C. At 400 C, the amount of surface participates decreases, and some strap shape participates appear. From XPS, Pd2Si was formed on the surface after annealing at 300 C, and all Pd reacted with SiC to form Pd2Si after annealing at 400 C. The intensity of the XPS Pd peak decreases enormously at 400 C. The Pd film diffused into SiC, and the Schottky barrier height has almost no changes. The work shows the Pd sicilides/SiC have the same electronic properties with Pd/SiC, and explains why the Pd/SiC sensor still responds to hydrogen at high operating temperatures.

Lu, W. J.↗
NASA NTRS1981

Fanning - A classification algorithm for mixture landscapes applied to Landsat data of Maine forests

It is pointed out that typical landscapes include a relatively small number of 'pure' land cover types which combine in various proportions to form a myriad of mixture types. Most Landsat classifications algorithms used today require a separate user specification for each category, including mixture categories. Attention is given to a simpler approach, which would require the user to specify only the 'pure' types. Mixture pixels would be classified on the basis of the proportion of the area covered by each pure type within the pixel. The 'fanning' algorithm quantifies varying proportions of two 'pure' land cover types in selected mixture pixels. This algorithm was applied to 200,000 ha of forest land in Maine, taking into account a comparison with standard inventory information. Results compared well with a discrete categories classification of the same area.

Ungar, S. G.↗
NASA NTRS1981

Forestry applications of LANDSAT data in New Hampshire

The applications of forest clearcut maps derived from LANDSAT data are dicussed. Such maps provide harvest location information useful in general management and indicate the stage of regrowth which helps determine timber stand improvement practices. The clearcut maps are also used in fire control planning and in determining wildlife habitats.

Bryant, E.↗
NASA NTRS1980

Landsat for practical forest type mapping - A test case

Computer classified Landsat maps are compared with a recent conventional inventory of forest lands in northern Maine. Over the 196,000 hectare area mapped, estimates of the areas of softwood, mixed wood and hardwood forest obtained by a supervised classification of the Landsat data and a standard inventory based on aerial photointerpretation, probability proportional to prediction, field sampling and a standard forest measurement program are found to agree to within 5%. The cost of the Landsat maps is estimated to be $0.065/hectare. It is concluded that satellite techniques are worth developing for forest inventories, although they are not yet refined enough to be incorporated into current practical inventories.

Bryant, E.↗
NASA NTRS1979

Small forest cuttings mapped with Landsat digital data

The Cooperative Landsat Applications Research Group used computer classification of Landsat digital data to map forest cuttings (clearcuts) in northern New Hampshire. Cuttings as small as 3 hectares were identified. Several ages or conditions of clearcuts could be distinguished. Progress in two methods of duplicating classification categories from one Landsat pass to another are discussed. One method was used in making maps of areas in 1973, 1975, and 1978.

Bryant, E.↗