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Brown, Linda R.

Publications and source records attributed to Brown, Linda R..

15 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

Self- and Air-Broadened Line Shapes in the 2v3 P and R Branches of 12CH4

In this paper we report line shape parameters of 12CH4 for several hundred 2V(sub 3) transitions in the spectral regions 5891-5996 cm( exp -1) (P branch) and 6015-6115 cm(exp -1) (R branch). Air- and self-broadening coefficients were measured as a function of temperature; line mixing via off-diagonal relaxation matrix element coefficients was also obtained for 47 transition pairs. In total, nearly 1517 positions and intensities were retrieved, but many transitions were too weak for the line shape study. For this analysis, we used 25 high-resolution (0.0056 and 0.0067 cm(ex[ -1) and high signal-to-noise (S/N) spectra of high-purity 12CH4 and the same high-purity 12CH4 broadened by dry air recorded at different sample temperatures between 130 K and 295 K with the Bruker IFS 125HR Fourier transform spectrometer at JPL. Three different absorption cells were used (1) a White cell set to a path length of 13.09 m for room temperature data, (2) a single-pass 0.2038 m long coolable cell (for self-broadening) and (3) a multipass cell with 20.941 m total path coolable Herriott cell (for air-broadening). In total there were 13 spectra with pure 12CH4 (0.27-599 Torr) and 12 air-broadened spectra with total sample pressures of 80-805 Torr and volume mixing ratios (VMR) of methane between 0.18 and 1.0. An interactive multispectrum nonlinear least-squares technique was employed to fit the individual P10-P1 and R0-R10 manifolds in all the spectra simultaneously. Results obtained from the present analysis are compared to other recent measurements.

Devi, V. Malathy↗
NASA NTRS2009

The HITRAN 2008 Molecular Spectroscopic Database

This paper describes the status of the 2008 edition of the HITRAN molecular spectroscopic database. The new edition is the first official public release since the 2004 edition, although a number of crucial updates had been made available online since 2004. The HITRAN compilation consists of several components that serve as input for radiative-transfer calculation codes: individual line parameters for the microwave through visible spectra of molecules in the gas phase; absorption cross-sections for molecules having dense spectral features, i.e., spectra in which the individual lines are not resolved; individual line parameters and absorption cross sections for bands in the ultra-violet; refractive indices of aerosols, tables and files of general properties associated with the database; and database management software. The line-by-line portion of the database contains spectroscopic parameters for forty-two molecules including many of their isotopologues.

Rothman, Laurence S.↗
NASA NTRS2002

The Rovibrational Intensities of Five Absorption Bands of (12)C(16)O2 Between 5218 and 5349/cm

Absolute line intensities, band intensities, and Herman-Wallis parameters were measured for the (01(sup 1)2)(sub I) from (00(sup 0)0)(sub I) perpendicular band of (12)C(16)O2 centered at 5315/cm, along with the three nearby associated hot bands: (10(sup 0)2)(sub II) from (01(sup 1)0)(sub I) at 5248/cm, (02(sup 2))(sub I) from (01(sup 1)0)(sub I) at 5291/cm, and (10(sup 0)2)(sub I) from (01(sup 1)0)(sub I) at 5349/cm. The nearby parallel hot band (30(sup 0))(sub I) from (10(sup 0)0)(sub II) at 5218/cm was also included in this study.

Giver, Lawrence P.↗
NASA NTRS1998

Line Intensity and Position Measurements and Derived Band Parameters of the 31103-00001 C-12 O-16(2) Band and its Two Nearby Hot Bands

A set of CO2 spectra from 4500 to 4780/cm has been obtained an Ames with 1500 m path length using a Bomem DA8 FTS. This spectral region contains a number of weak bands and minor isotopic bands that have been studied at high resolution in the reflection spectrum of Venus by Mandin. Improved laboratory intensity and position measurements should assist modeling the Venus reflection spectra and improve understanding of Venus' upper atmosphere. Also, the laboratory measurements will assist DND intensity computations of weaker bands that cannot be measured, but which are nevertheless significant absorbers in Venus' hot, deep CO2, atmosphere. For example, some of the weaker bands that are members of the same polyads as the bands in this presentation lie in the nearby 2.3 microns emission window in Venus' night-side spectrum.

Giver, Lawrence P.↗
NASA NTRS1996

Theoretical Calculations of Pressure Broadening Coefficients for H2O Perturbed by Hydrogen or Helium Gas

To aid in the reduction of remote-sensing data from the outer planets, collision-broadened halfwidths are calculated for water vapor broadened by H2 and are estimated for He-broadening. The model used is a fully complex implementation of the Robert and Bonamy formalism with parabolic trajectories and all relevant terms in the interaction potential. Calculations are performed for 386 pure rotational transitions of H2O with J

remote-sensing↗
NASA NTRS1995

Intensity and Self-Broadening Measurements of the 01(exp 1)21-00(exp 0)01 CO2 Perpendicular Band at 5315/cm

The near-infrared thermal emission windows in the spectrum of the night-side of Venus have stimulated new determinations of the intensities of weak CO2 bands which are prominent absorption features in Venus spectra. Parameters for many unmeasured bands have been recomputed for the HITRAN compilation using direct numerical diagonalization (DND) [Wattson and Rothman, J.Q.S.R.T. 48, 763 (1992)]. To assess these HITRAN values, we have been measuring several of these bands on spectra which were obtained using the Kitt Peak McMath FTS and 6-meter White cell. Last year we presented preliminary intensity measurements of the 01(exp 1)21-00(exp 0)01 perpendicular band and 4 associated hot bands, Five additional McMath FTS spectra have now been obtained covering the region 3800 to 8400/cm. This permits us to finalize our intensity measurements, and to make an assessment of their uncertainties. We anticipate that these measured values will help improve further DND calculations of many weak unmeasureable bands. In addition, self-broadening parameters were determined for some lines of the 01(exp 1)21-00(exp 0)01 perpendicular band on spectra obtained with 65 and 80 torr of CO2. Because of the large spectral range, these measurements could be compared directly to self-broadening parameters of corresponding parallel. band lines measured on the same spectra. This procedure eliminates several possible sources of systematic errors that are important when attempting to determine whether or not corresponding rotational lines in different overtone-combination bands have significant differences. Our measurements thus far have found self-broadening parameters for the 01(exp 1)21-00(exp 0)01 perpendicular band to be slightly larger than similar measurements for the 30(exp 0)14-00(exp 0)01 parallel band at 6076/cm.

Giver, Lawrence P.↗
NASA NTRS1994

An Empirical Expression for the Line Widths of Ammonia

The hydrogen-broadened line widths of 116 (sup 14)NH(sub 3) ground state transitions have been measured at 0.006 cm(sup -1) resolution using a Bruker spectrometer in the 24 to 210 cm(sup -1) region. The rotational variation of the experimental widths with J(sup '),K(sup ') = 1,0 to 10,10 has been reproduced to 2.4 % using an heuristically derived expression of the form gamma = a(sub 0) + a(sub 1) J(sup ') + a (sub 2) K(sup ') + a(sub 3) J(sup ')(sup 2) + a(sub 4) J(sup ') K(sup ') where J(sup ') and K(sup ') are the lower state symmetric top quantum numbers. This function has also been applied to the measured widths of the 58 transitions of nu(sub 1) at 3 (micro)m, each broadened by N(sub 2), O(sub 2), Ar, H(sub 2), and He. The rms of the observed minus calculated widths are 5% or better for the five foreign broadeners. The values of the fitted constants suggest that for some broadeners the expression might also be written as gamma = a(sub 0) + b(sub 1) J(sup ') + b(sub 2)(J(sup ' )- K(sup ')) + b(sub 3) J(sup ')(J(sup ') - K(sup ')) .

ammonia spectroscopy planetary atmospheres hydroge↗
NASA NTRS1994

Intensity Measurements of the 01(sup 1)21-00(sup 0)01 Perpendicular CO2 band at 5315 cm (sup -1) and 4 related hot bands

The near-infrared thermal emission windows in the spectrum of the night-side of Venus have stimulated new determinations of the intensities of weak CO2 bands which are prominent absorption features in Venus spectra. We have previously measured the 31(sup 1)04-00(sup 0)01 band at 4416 cm (sup -1), which dominates a portion of the 2.2 micrometer window, using the 25-meter White absorption cell at Ames. Parameters for many of the unmeasured bands have been recomputed for the HITRAN compilation using direct numerical diagonalization. This procedure has some uncertainties, particularly for higher overtone-combination perpendicular bands, and substantial differences were noted for these bands when comparing the 1986 HITRAN tabulation with the 1992 values. To clarify this situation, we decided to measure the intensities of several of these bands; L.R.B. obtained spectra using the McMath FTS and 6 meter White cell, covering the region 3800 to 7700 cm (sup -1). A table is provided in which we compare our measured intensities and Herman-Wallis al parameters for the 01(sup 1)21-00(sup 0)01 band and 4 associated hot bands with both Hitran tabulations. It is anticipated that these measured values will be useful in further DND calculations of many very weak unmeasurable bands.

Giver, Lawrence P.↗
NASA NTRS1988

Methane line parameters from 3700 to 4136/cm

The positions and strengths of about 1900 absorption lines of methane between 3700 and 4136/cm were measured experimentally to provide a reference line list for the identification of weak CH4 features in planetary spectra. The line parameters were obtained at room temperature with accuracies of 0.0002-0.003/cm for positions and + or - 3-40 percent for strengths using spectra recorded at 0.011/cm resolution (unapodized) with a Fourier transform spectrometer at Kitt Peak National Observatory/National Solar Observatory. Individual line strengths range from 0.00002-0.013/sq cm per atm at room temperature, and the sum of the observed strengths is 1.42/sq cm per atm at 297 K. All measurements are reported in natural isotopic abundance.

Brown, Linda R.↗