Intrinsic oxygen fugacity measurements on seven chondrites, a pallasite, and a tektite and the redox state of meteorite parent bodies
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Publications and source records attributed to Brett, R..
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Measurements of the oxygen fugacity, f(O2), as a function of temperature, T, were made on an interior bulk sample of the cumulate achondrite, Angra dos Reis. Data clustered between the f(O2)-T relationship of the iron-wustite assemblage and 1.2 log atm units above iron-wustite. Interpretation of the data indicates that, throughout most of the cooling history of the meteorite, f(O2) values were defined by equilibria involving iron-bearing species at values close to the f(O2) of the assemblage iron-wustite. Measured f(O2) data are compatible with crystallization and cooling at pressures greater than 50 bars.
Sulfur abundances and metallic iron abundances in 18 Apollo 12 mare basalts were determined. No correlation between sulfur abundance and metallic iron content was detected; metallic iron abundances are not primarily caused by S loss. Sulfur abundances, directly related to the bulk composition of the rocks and especially to the TiO2 content, increase with increasing degrees of fractionation and appear to result from S concentration in the melts during fractionation. Unlike the Apollo 17 melts, the Apollo 12 melts were unsaturated with respect to sulfide. Composition appears to control S content for Apollo 17 basalts, and cumulus processes may cause Fe-FeS enrichment.
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Review of the mineral chemistry, crystallography, mosaic assemblages, and oriented inclusions of lunar rock sample 76535, and discussion of its depth of formation. Its texture, chemistry, and phase relationships are shown to indicate that it formed deep within the lunar crust. It is the first crystalline lunar rock found to date to contain evidence of a high pressure mineral assemblage formed under static conditions.
It is found that 25% on the Apollo-14 glasses have the same composition as the glasses in two samples taken from the Luna-16 column. The compositions are equivalent to feldspar basalt and anorthosite gabbro, and are similar to the feldspar basalts identified from Surveyor-7 analysis for lunar continents.
The outer portion of the moon (including the aluminum-rich crust and the source regions of mare basalts) was either accreted heterogeneously or was the product of widespread differentiation of an originally homogeneous source. Existing evidence for and against each of these two models is reviewed. It is concluded that the accretionary model presents more problems than it solves, and the model involving differentiation of an originally homogeneous moon is considered to be more plausible. A hypothesis for the formation of mare basalts is advanced.
One hundred seventy-six oxide mineral grains in the Luna 20 samples were analyzed by electron microprobe. Spinel is the most abundant oxide, occurring in troctolite fragments. Next most abundant is ilmenite, which occurs in all rock types except those containing spinel. Chromite also occurs in all rock types except those containing spinel. Minor amounts of ulvospinel, armalcolite, zirkelite, baddeleyite and an unidentified TiO2-rich phase were also found. Spinel grains are predominantly spinel-hercynite solid solutions, commonly with very minor chromite. The Fe/(Fe + Mg) ratio is generally lower than in spinel from Apollo 14 rocks. Chromites in non-mare rocks are similar to those from mare rocks. Ilmenite of mare origin is Mg-poor and Zr-rich compared to non-mare ilmenite; these elements may therefore be useful in determining the origin of ilmenite grains. Phase equilibria considerations suggest that spinel troctolite crystallized from a melt high in alumina; a likely candidate is the high-alumina basalt of Prinz et al. (1973).
It has been proposed that lunar samples were magnetized by a field created by a lunar core of molten Fe. Low abundances of siderophile elements in lunar rocks are compatible with formation of a metallic lunar core. A molten Fe core requires that the bulk of the moon was above, or close to, the melting point, a requirement which disagrees with most models of the lunar thermal regime. A core (or perhaps a layer or pockets) of molten Fe-Ni-S, at or close to the eutectic composition would act as a lunar dynamo, and be at a temperature (approximately 1000 C) consistent with some reasonable models of lunar thermal history. The existence of a Fe-Ni-S core would also partly explain the depletion in volatile elements in lunar basalts. Such a core, occupying up to 20% of the moon's radius, requires a bulk S content for the moon of only 0.3 wt %.
Electron microprobe analyses for Fe, Co, Ni, S, and P have been carried out on the metal and associated troilite, schreibersite, and rare cohenite in the Apollo 16 rake samples from Stations 1, 4, and 13. The Co/Ni ratios of most of the metal are within the limits of meteoritic metal as defined by Goldstein and Yakowitz (1971). The large abundance of schreibersite in all of the lithic types except the poikilitic rocks suggests that much of it may be of lunar origin. The near-absence of schreibersite in the poikilitic rocks may be a result of P diffusion from the metal to the surrounding silicate at low temperature. Application of the compositional data for the coexisting metal-schreibersite pairs to isotherms in the system Fe-Ni-P indicates a sequence of progressively lower temperatures of equilibration (and probably a corresponding sequence of slower cooling rates) of these phases from the devitrified glasses, to the mesostasis-rich rocks, to the diabases, to the poikilitic rocks.
A review of the recent developments in lunar science summarizing the most important lunar findings and the known restraints on the theories of lunar evolution is presented. Lunar geophysics is discussed in sections dealing with the figure of the moon, mascons, and the lunar thermal regime; recent seismic studies and magnetic results are reported. The chemical data on materials taken from lunar orbit are analyzed, and the lunar geology is discussed. Special attention is accorded the subject of minerology, reflecting the information obtained from lunar samples of both mare and nonmare origin. A tentative timetable of lunar events is proposed, and the problem of the moon's origin is briefly treated.
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A comprehensive study has been carried out of the Gosses Bluff structure in Central Australia, which is a typical cryptoexplosion structure. The study included detailed geologic mapping, and seismic reflection and refraction, gravity, aeromagnetic, and ground magnetic surveys. It is concluded that the structure is an eroded crater formed by a single nearly instantaneous shock event, and that the event can be explained only by impact.
Extensive microprobe analyses have been made of pyroxenes, plagioclases, olivines, opaque minerals, and glasses in two 0.025 g lunar samples returned from the Luna 16 mission, with the aim to characterize the Mare Fecunditatis regolith. No major differences were found between the near surface soil horizon A and horizon D at approximately 30 cm depth. Resulting characteristics of the mineral examined are presented and discussed.
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Australian Liverpool and Strang way craters as probable meteoritic impact origin form topographic and petrographic data
Lighter-than-iron elements in earth iron core, assuming formation timed chemical equilibrium with mantle
Mineralogy and petrology of Apollo 12 igneous rocks 12004, 12008, 12009 and 12022, noting ilmenite, olivine and spinel content and metal grains composition